Stannite
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Stannite
Stannite is a mineral, a sulfide of copper, iron, and tin, in the category of thiostannates. Background The chemical formula Cu2 Fe Sn S4. Zinc commonly occurs with the iron and trace germanium may be present. Stannite is used as an ore of tin, consisting of approximately 28% tin, 13% iron, 30% copper, 30% sulfur by mass. It is found in tin-bearing, hydrothermal vein deposits occurring with chalcopyrite, sphalerite, tetrahedrite, arsenopyrite, pyrite, cassiterite, and wolframite. It is also known as ''bell metal ore'' as tin is an important constituent of bell-metal. It is thought the exploitation of tin deposits in Cornwall led to an expansion in bell founding. The name comes from the Latin for tin: ''stannum''. It was first described in 1797 for an occurrence in Wheal Rock, St. Agnes, Cornwall, England. See also * Kesterite Kësterite is a sulfide mineral with a chemical formula of . In its lattice structure, zinc and iron atoms share the same lattice sites. Kesterite i ...
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Thiostannates
Sulfidostannates, or thiostannates are chemical compounds containing anions composed of tin linked with sulfur. They can be considered as stannates with sulfur substituting for oxygen. Related compounds include the thiosilicates, and thiogermannates, and by varying the chalcogen: selenostannates, and tellurostannates. Oxothiostannates have oxygen in addition to sulfur. Thiostannates can be classed as chalcogenidometalates, thiometallates, chalcogenidotetrelates, thiotetrelates, and chalcogenidostannates. Tin is almost always in the +4 oxidation state in thiostannates, although a couple of mixed sulfides in the +2 state are known, Some thiostannate minerals are known. In nature the tin can be partly replaced by arsenic, germanium, antimony or indium. Many thiostannate minerals contain copper, silver or lead. In the field of mineralogy, these compound can be termed sulfostannates or sulphostannates. Different cluster anions are known: nS4sup>4–, nS3sup>2–, n2S5sup>2–, ...
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Sulfide Mineral
The sulfide minerals are a class of minerals containing sulfide (S2−) or disulfide (S22−) as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenides, the tellurides, the arsenides, the antimonides, the bismuthinides, the sulfarsenides and the sulfosalts.http://www.minerals.net/mineral/sort-met.hod/group/sulfgrp.htm Minerals.net Dana Classification, SulfidesKlein, Cornelis and Cornelius S. Hurlbut, Jr., 1986, ''Manual of Mineralogy'', Wiley, 20th ed., pp 269-293 Sulfide minerals are inorganic compounds. Minerals Common or important examples include: * Acanthite *Chalcocite *Bornite *Galena *Sphalerite * Chalcopyrite * Pyrrhotite * Millerite * Pentlandite * Covellite * Cinnabar * Realgar *Orpiment * Stibnite *Pyrite * Marcasite *Molybdenite Sulfarsenides: *Cobaltite *Arsenopyrite * Gersdorffite Sulfosalts: * Pyrargyrite * Proustite *Tetrahedrite * Tennantite * Enargite * B ...
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Sulfide Minerals
The sulfide minerals are a class of minerals containing sulfide (S2−) or disulfide (S22−) as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenides, the tellurides, the arsenides, the antimonides, the bismuthinides, the sulfarsenides and the sulfosalts.http://www.minerals.net/mineral/sort-met.hod/group/sulfgrp.htm Minerals.net Dana Classification, SulfidesKlein, Cornelis and Cornelius S. Hurlbut, Jr., 1986, ''Manual of Mineralogy'', Wiley, 20th ed., pp 269-293 Sulfide minerals are inorganic compounds. Minerals Common or important examples include: * Acanthite *Chalcocite *Bornite *Galena * Sphalerite * Chalcopyrite * Pyrrhotite * Millerite * Pentlandite * Covellite * Cinnabar * Realgar *Orpiment * Stibnite *Pyrite * Marcasite * Molybdenite Sulfarsenides: *Cobaltite *Arsenopyrite * Gersdorffite Sulfosalts: * Pyrargyrite * Proustite *Tetrahedrite * Tennantite * Enargite ...
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Kesterite
Kësterite is a sulfide mineral with a chemical formula of . In its lattice structure, zinc and iron atoms share the same lattice sites. Kesterite is the Zn-rich variety whereas the Zn-poor form is called ferrokesterite or stannite. Owing to their similarity, kesterite is sometimes called isostannite. The synthetic form of kesterite is abbreviated as CZTS (from copper zinc tin sulfide). The name kesterite is sometimes extended to include this synthetic material and also CZTSe, which contains selenium instead of sulfur. Occurrence Kesterite was first described in 1958 in regard to an occurrence in the Kester deposit (and the associated locality) in Ynnakh Mountain, Yana basin, Yakutia, Russia, where it was discovered. It is usually found in quartz-sulfide hydrothermal veins associated with tin ore deposits. Associated minerals include arsenopyrite, stannoidite, chalcopyrite, chalcocite, sphalerite and tennantite. Stannite and kesterite occur together in the Ivigtut cryolite ...
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Arsenopyrite
Arsenopyrite ( IMA symbol: Apy) is an iron arsenic sulfide (FeAsS). It is a hard ( Mohs 5.5-6) metallic, opaque, steel grey to silver white mineral with a relatively high specific gravity of 6.1. When dissolved in nitric acid, it releases elemental sulfur. When arsenopyrite is heated, it produces sulfur and arsenic vapor. With 46% arsenic content, arsenopyrite, along with orpiment, is a principal ore of arsenic. When deposits of arsenopyrite become exposed to the atmosphere, the mineral slowly converts into iron arsenates. Arsenopyrite is generally an acid-consuming sulfide mineral, unlike iron pyrite which can lead to acid mine drainage. The crystal habit, hardness, density, and garlic odour when struck are diagnostic. Arsenopyrite in older literature may be referred to as ''mispickel'', a name of German origin. Arsenopyrite also can be associated with significant amounts of gold. Consequently, it serves as an indicator of gold bearing reefs. Many arsenopyrite gold ...
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Tin Minerals
Tin is a chemical element with the symbol Sn (from la, stannum) and atomic number 50. Tin is a silvery-coloured metal. Tin is soft enough to be cut with little force and a bar of tin can be bent by hand with little effort. When bent, the so-called " tin cry" can be heard as a result of twinning in tin crystals; this trait is shared by indium, cadmium, zinc, and mercury in the solid state. Pure tin after solidifying presents a mirror-like appearance similar to most metals. In most tin alloys (such as pewter) the metal solidifies with a dull gray color. Tin is a post-transition metal in group 14 of the periodic table of elements. It is obtained chiefly from the mineral cassiterite, which contains stannic oxide, . Tin shows a chemical similarity to both of its neighbors in group 14, germanium and lead, and has two main oxidation states, +2 and the slightly more stable +4. Tin is the 49th most abundant element on Earth and has, with 10 stable isotopes, the large ...
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Iron Minerals
Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in front of oxygen (32.1% and 30.1%, respectively), forming much of Earth's outer and inner core. It is the fourth most common element in the Earth's crust. In its metallic state, iron is rare in the Earth's crust, limited mainly to deposition by meteorites. Iron ores, by contrast, are among the most abundant in the Earth's crust, although extracting usable metal from them requires kilns or furnaces capable of reaching or higher, about higher than that required to smelt copper. Humans started to master that process in Eurasia during the 2nd millennium BCE and the use of iron tools and weapons began to displace copper alloys, in some regions, only around 1200 BCE. That event is considered the transition from the Bronze Age to the Iron A ...
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Copper Minerals
Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orange color. Copper is used as a conductor of heat and electricity, as a building material, and as a constituent of various metal alloys, such as sterling silver used in jewelry, cupronickel used to make marine hardware and coins, and constantan used in strain gauges and thermocouples for temperature measurement. Copper is one of the few metals that can occur in nature in a directly usable metallic form (native metals). This led to very early human use in several regions, from circa 8000 BC. Thousands of years later, it was the first metal to be smelted from sulfide ores, circa 5000 BC; the first metal to be cast into a shape in a mold, c. 4000 BC; and the first metal to be purposely alloyed with another metal, tin, to create bronze, c ...
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England
England is a country that is part of the United Kingdom. It shares land borders with Wales to its west and Scotland to its north. The Irish Sea lies northwest and the Celtic Sea to the southwest. It is separated from continental Europe by the North Sea to the east and the English Channel to the south. The country covers five-eighths of the island of Great Britain, which lies in the North Atlantic, and includes over 100 smaller islands, such as the Isles of Scilly and the Isle of Wight. The area now called England was first inhabited by modern humans during the Upper Paleolithic period, but takes its name from the Angles, a Germanic tribe deriving its name from the Anglia peninsula, who settled during the 5th and 6th centuries. England became a unified state in the 10th century and has had a significant cultural and legal impact on the wider world since the Age of Discovery, which began during the 15th century. The English language, the Anglican Church, and Engli ...
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Latin
Latin (, or , ) is a classical language belonging to the Italic branch of the Indo-European languages. Latin was originally a dialect spoken in the lower Tiber area (then known as Latium) around present-day Rome, but through the power of the Roman Republic it became the dominant language in the Italian region and subsequently throughout the Roman Empire. Even after the fall of Western Rome, Latin remained the common language of international communication, science, scholarship and academia in Europe until well into the 18th century, when other regional vernaculars (including its own descendants, the Romance languages) supplanted it in common academic and political usage, and it eventually became a dead language in the modern linguistic definition. Latin is a highly inflected language, with three distinct genders (masculine, feminine, and neuter), six or seven noun cases (nominative, accusative, genitive, dative, ablative, and vocative), five declensions, four verb conjug ...
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Wolframite
Wolframite is an iron, manganese, and tungstate mineral with a chemical formula of that is the intermediate between ferberite ( rich) and hübnerite ( rich). Along with scheelite, the wolframite series are the most important tungsten ore minerals. Wolframite is found in quartz veins and pegmatites associated with granitic intrusives. Associated minerals include cassiterite, scheelite, bismuth, quartz, pyrite, galena, sphalerite, and arsenopyrite. This mineral was historically found in Europe in Bohemia, Saxony, and Cornwall. China reportedly has the world's largest supply of tungsten ore with about 60%. Other producers are Spain, Canada, Portugal, Russia, Australia, Thailand, South Korea, Rwanda, Bolivia, the United States, and the Democratic Republic of the Congo. Name The name "wolframite" is derived from German "''wolf rahm''", the name given to tungsten by Johan Gottschalk Wallerius in 1747. This, in turn, derives from "''Lupi spuma''", the name Georg Agricola used for th ...
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Cassiterite
Cassiterite is a tin oxide mineral, SnO2. It is generally opaque, but it is translucent in thin crystals. Its luster and multiple crystal faces produce a desirable gem. Cassiterite was the chief tin ore throughout ancient history and remains the most important source of tin today. Occurrence Most sources of cassiterite today are found in alluvial or placer deposits containing the weathering-resistant grains. The best sources of primary cassiterite are found in the tin mines of Bolivia, where it is found in crystallised hydrothermal veins. Rwanda has a nascent cassiterite mining industry. Fighting over cassiterite deposits (particularly in Walikale) is a major cause of the conflict waged in eastern parts of the Democratic Republic of the Congo. This has led to cassiterite being considered a conflict mineral. Cassiterite is a widespread minor constituent of igneous rocks. The Bolivian veins and the 4500 year old workings of Cornwall and Devon, England, are concentrated ...
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