Thiostannates
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Thiostannates
Sulfidostannates, or thiostannates are chemical compounds containing anions composed of tin linked with sulfur. They can be considered as stannates with sulfur substituting for oxygen. Related compounds include the thiosilicates, and thiogermannates, and by varying the chalcogen: selenostannates, and tellurostannates. Oxothiostannates have oxygen in addition to sulfur. Thiostannates can be classed as chalcogenidometalates, thiometallates, chalcogenidotetrelates, thiotetrelates, and chalcogenidostannates. Tin is almost always in the +4 oxidation state in thiostannates, although a couple of mixed sulfides in the +2 state are known, Some thiostannate minerals are known. In nature the tin can be partly replaced by arsenic, germanium, antimony or indium. Many thiostannate minerals contain copper, silver or lead. In the field of mineralogy, these compound can be termed sulfostannates or sulphostannates. Different cluster anions are known: nS4sup>4–, nS3sup>2–, n2S5sup>2–, ...
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Anion
An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convention. The net charge of an ion is not zero because its total number of electrons is unequal to its total number of protons. A cation is a positively charged ion with fewer electrons than protons while an anion is a negatively charged ion with more electrons than protons. Opposite electric charges are pulled towards one another by electrostatic force, so cations and anions attract each other and readily form ionic compounds. Ions consisting of only a single atom are termed atomic or monatomic ions, while two or more atoms form molecular ions or polyatomic ions. In the case of physical ionization in a fluid (gas or liquid), "ion pairs" are created by spontaneous molecule collisions, where each generated pair consists of a free electron and ...
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Stannite
Stannite is a mineral, a sulfide of copper, iron, and tin, in the category of thiostannates. Background The chemical formula Cu2 Fe Sn S4. Zinc commonly occurs with the iron and trace germanium may be present. Stannite is used as an ore of tin, consisting of approximately 28% tin, 13% iron, 30% copper, 30% sulfur by mass. It is found in tin-bearing, hydrothermal vein deposits occurring with chalcopyrite, sphalerite, tetrahedrite, arsenopyrite, pyrite, cassiterite, and wolframite. It is also known as ''bell metal ore'' as tin is an important constituent of bell-metal. It is thought the exploitation of tin deposits in Cornwall led to an expansion in bell founding. The name comes from the Latin for tin: ''stannum''. It was first described in 1797 for an occurrence in Wheal Rock, St. Agnes, Cornwall, England. See also * Kesterite Kësterite is a sulfide mineral with a chemical formula of . In its lattice structure, zinc and iron atoms share the same lattice sites. Kesterit ...
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Canfieldite
Canfieldite is a rare silver tin sulfide mineral with formula: Ag8SnS6. The mineral typically contains variable amounts of germanium substitution in the tin site and tellurium in the sulfur site. There is a complete series between canfieldite and its germanium analogue, argyrodite. It forms black orthorhombic crystals which often appear to be cubic in form due to twinning. The most typical form is as botryoidal rounded grape-like masses. Its Mohs hardness is 2.5 and the specific gravity is 6.28. Canfieldite exhibits conchoidal fracturing and no cleavage. Canfieldite was first described in 1893 from an occurrence in Colquechaca, Potosí Department, Bolivia. It was named for Frederick Alexander Canfield (1849–1926), an American mining engineer. See also *List of minerals *List of minerals named after people This is a list of minerals named after people. The chemical composition follows name. A *Abelsonite: C31H32N4Ni – American physicist Philip Hauge Abelson (1913 ...
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Stannoidite
Stannoidite is a sulfide mineral composed of five chemical elements: copper, iron, zinc, tin and sulfur. Its name originates from Latin ''stannum'' (tin) and Greek ''eides'' (or Latin ''oïda'' meaning "like"). The mineral is found in hydrothermal Cu-Sn deposits. Stannoidite was first described in 1969 for an occurrence in the Konjo mine, Okayama prefecture, Honshu Island, Japan. See also * Stannite * Kesterite Kësterite is a sulfide mineral with a chemical formula of . In its lattice structure, zinc and iron atoms share the same lattice sites. Kesterite is the Zn-rich variety whereas the Zn-poor form is called ferrokesterite or stannite. Owing to thei ... References Sulfide minerals Orthorhombic minerals Minerals in space group 23 {{sulfide-mineral-stub ...
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Kësterite
Kësterite is a sulfide mineral with a chemical formula of . In its lattice structure, zinc and iron atoms share the same lattice sites. Kesterite is the Zn-rich variety whereas the Zn-poor form is called ferrokesterite or stannite. Owing to their similarity, kesterite is sometimes called isostannite. The synthetic form of kesterite is abbreviated as CZTS (from copper zinc tin sulfide). The name kesterite is sometimes extended to include this synthetic material and also CZTSe, which contains selenium instead of sulfur. Occurrence Kesterite was first described in 1958 in regard to an occurrence in the Kester deposit (and the associated locality) in Ynnakh Mountain, Yana basin, Yakutia, Russia, where it was discovered. It is usually found in quartz-sulfide hydrothermal veins associated with tin ore deposits. Associated minerals include arsenopyrite, stannoidite, chalcopyrite, chalcocite, sphalerite and tennantite. Stannite and kesterite occur together in the Ivigtut cryolite depo ...
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Nekrasovite
:''See Nekrasov Cossacks for another meaning'' Nekrasovite is a rare copper vanadium sulfosalt mineral with formula . It crystallizes in the isometric system and occurs as small grains in ore aggregates. It is a brown opaque metallic mineral with Mohs hardness of 4.5 and a specific gravity of 4.62. It was first described in 1984 in the Khayragatsch ore deposit of eastern Uzbekistan Uzbekistan (, ; uz, Ozbekiston, italic=yes / , ; russian: Узбекистан), officially the Republic of Uzbekistan ( uz, Ozbekiston Respublikasi, italic=yes / ; russian: Республика Узбекистан), is a doubly landlocked co ... and named for Russian mineralogist Ivan Yakovlevich Nekrasov (born 1929). ReferencesMindat data with locationsWebmineral dataMineral Data Publishing - PDF

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