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Sessile Drop Technique
image:Contact angle.svg, 400px, Fig 1: An illustration of the sessile drop technique with a liquid droplet partially wetting a solid substrate. is the contact angle, and represent the solid–gas, gas–liquid, and liquid–solid interfaces, respectively. In materials science, the sessile drop technique is a method used for the characterization of solid surface energy, surface energies, and in some cases, aspects of liquid surface energies. The main premise of the method is that by placing a droplet of liquid with a known surface energy and contact angle, the surface energy of the solid substrate can be calculated. The liquid used for such experiments is referred to as the probe liquid, and the use of several different probe liquids is required. Probe liquid The surface energy is measured in units of Joules per area, which is equivalent in the case of liquids to surface tension, measured in Newtons per meter. The overall surface tension/energy of a liquid can be acquired thr ...
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Contact Angle
The contact angle is the angle, conventionally measured through the liquid, where a liquid–vapor interface meets a solid surface. It quantifies the wettability of a solid surface by a liquid via the Young equation. A given system of solid, liquid, and vapor at a given temperature and pressure has a unique equilibrium contact angle. However, in practice a dynamic phenomenon of contact angle hysteresis is often observed, ranging from the advancing (maximal) contact angle to the receding (minimal) contact angle. The equilibrium contact is within those values, and can be calculated from them. The equilibrium contact angle reflects the relative strength of the liquid, solid, and vapour molecular interaction. The contact angle depends upon the medium above the free surface of the liquid, and the nature of the liquid and solid in contact. It is independent of the inclination of solid to the liquid surface. It changes with surface tension and hence with the temperature and purity of ...
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Hydrogen Bonding
In chemistry, a hydrogen bond (or H-bond) is a primarily electrostatic force of attraction between a hydrogen (H) atom which is covalently bound to a more electronegative "donor" atom or group (Dn), and another electronegative atom bearing a lone pair of electrons—the hydrogen bond acceptor (Ac). Such an interacting system is generally denoted , where the solid line denotes a polar covalent bond, and the dotted or dashed line indicates the hydrogen bond. The most frequent donor and acceptor atoms are the second-row elements nitrogen (N), oxygen (O), and fluorine (F). Hydrogen bonds can be intermolecular (occurring between separate molecules) or intramolecular (occurring among parts of the same molecule). The energy of a hydrogen bond depends on the geometry, the environment, and the nature of the specific donor and acceptor atoms and can vary between 1 and 40 kcal/mol. This makes them somewhat stronger than a van der Waals interaction, and weaker than fully covalent o ...
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Polymers
A polymer (; Greek '' poly-'', "many" + '' -mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic and natural polymers play essential and ubiquitous roles in everyday life. Polymers range from familiar synthetic plastics such as polystyrene to natural biopolymers such as DNA and proteins that are fundamental to biological structure and function. Polymers, both natural and synthetic, are created via polymerization of many small molecules, known as monomers. Their consequently large molecular mass, relative to small molecule compounds, produces unique physical properties including toughness, high elasticity, viscoelasticity, and a tendency to form amorphous and semicrystalline structures rather than crystals. The term "polymer" derives from the Greek word πολύς (''polus'', meaning "many, much") and μέρος (''meros' ...
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Plasma Cleaning
Plasma cleaning is the removal of impurities and contaminants from surfaces through the use of an energetic plasma or dielectric barrier discharge (DBD) plasma created from gaseous species. Gases such as argon and oxygen, as well as mixtures such as air and hydrogen/nitrogen are used. The plasma is created by using high frequency voltages (typically kHz to >MHz) to ionise the low pressure gas (typically around 1/1000 atmospheric pressure), although atmospheric pressure plasmas are now also common. Methods In plasma, gas atoms are excited to higher energy states and also ionized. As the atoms and molecules 'relax' to their normal, lower energy states they release a photon of light, this results in the characteristic “glow” or light associated with plasma. Different gases give different colors. For example, oxygen plasma emits a light blue color. A plasma’s activated species include atoms, molecules, ions, electrons, free radicals, metastables, and photons in the short wave ...
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Corona Treatment
Corona treatment (sometimes referred to as air plasma) is a surface modification technique that uses a low temperature corona discharge plasma to impart changes in the properties of a surface. The corona plasma is generated by the application of high voltage to an electrode that has a sharp tip. The plasma forms at the tip. A linear array of electrodes is often used to create a curtain of corona plasma. Materials such as plastics, cloth, or paper may be passed through the corona plasma curtain in order to change the surface energy of the material. All materials have an inherent surface energy. Surface treatment systems are available for virtually any surface format including dimensional objects, sheets and roll goods that are handled in a web format. Corona treatment is a widely used surface treatment method in the plastic film, extrusion, and converting industries. History The corona treatment was invented by the Danish engineer Verner Eisby in 1951. Eisby had been asked by o ...
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Heat Treatment
Heat treating (or heat treatment) is a group of industrial process, industrial, thermal and metalworking, metalworking processes used to alter the physical property, physical, and sometimes chemical property, chemical, properties of a material. The most common application is metallurgy, metallurgical. Heat treatments are also used in the manufacture of many other materials, such as glass. Heat treatment involves the use of heating or chilling, normally to extreme temperatures, to achieve the desired result such as hardening or softening of a material. Heat treatment techniques include annealing (metallurgy), annealing, case hardening, precipitation strengthening, tempering (metallurgy), tempering, carburizing, normalizing and quenching. Although the term ''heat treatment'' applies only to processes where the heating and cooling are done for the specific purpose of altering properties intentionally, heating and cooling often occur incidentally during other manufacturing processes s ...
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William Zisman
Dr. William Albert Zisman (1905–1986)Dr. William A. Zisman: A Retrospective, Labstracts, July 6, 2009, p3 was an American chemist and geophysicist. Life and career He was born in Albany, NY and spent his youth in Providence, RI up to the age of 14 when his family moved to Washington, DC. He earned his BS and MS degrees in physics from Massachusetts Institute of Technology. He began his career working as a research assistant to Nobel Prize winner P. W. Bridgman at Harvard University. He earned his PhD while at Harvard in 1932 and continued on as a post-doc studying high pressure problems relating to the Earth's core. During this point in his career he began to follow in the footsteps of Langmuir, Rideal, and Harkins. Research funds were limited during the Great Depression and so Zisman returned to Washington, DC and held various administrative jobs for government agencies that were born during the New Deal era. Zisman returned to science in 1938 when he quit his job in Washing ...
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Contact Angle Goniometer
A goniometer is an instrument that either measures an angle or allows an object to be rotated to a precise angular position. The term goniometry derives from two Greek words, γωνία (''gōnía'') 'angle' and μέτρον (''métron'') ' measure'. The first known description of a goniometer, based on the astrolabe, was by Gemma Frisius in 1538. Applications Surveying Prior to the invention of the theodolite, the goniometer was used in surveying. The application of triangulation to geodesy was described in the second (1533) edition of ''Cosmograficus liber'' by Petri Appiani as a 16-page appendix by Frisius entitled ''Libellus de locorum describendorum ratione''. Communications The Bellini–Tosi direction finder was a type of radio direction finder that was widely used from World War I to World War II. It used the signals from two crossed antennas, or four individual antennas simulating two crossed ones, to re-create the radio signal in a small area between two loo ...
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Wetting
Wetting is the ability of a liquid to maintain contact with a solid surface, resulting from intermolecular interactions when the two are brought together. This happens in presence of a gaseous phase or another liquid phase not miscible with the first one. The degree of wetting (wettability) is determined by a force balance between adhesive and cohesive forces. Wetting is important in the bonding or adherence of two materials. Wetting and the surface forces that control wetting are also responsible for other related effects, including capillary effects. There are two types of wetting: non-reactive wetting and reactive wetting. Wetting deals with three phases of matter: gas, liquid, and solid. It is now a center of attention in nanotechnology and nanoscience studies due to the advent of many nanomaterials in the past two decades (e.g. graphene, Carbon nano tube, carbon nanotube, boron nitride nanomesh). Explanation Adhesive forces between a liquid and solid cause a liqu ...
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Polytetrafluoroethylene
Polytetrafluoroethylene (PTFE) is a synthetic fluoropolymer of tetrafluoroethylene that has numerous applications. It is one of the best-known and widely applied PFAS. The commonly known brand name of PTFE-based composition is Teflon by Chemours, a spin-off from DuPont, which originally discovered the compound in 1938. Polytetrafluoroethylene is a fluorocarbon solid, as it is a high- molecular-weight polymer consisting wholly of carbon and fluorine. PTFE is hydrophobic: neither water nor water-containing substances wet PTFE, as fluorocarbons exhibit only small London dispersion forces due to the low electric polarizability of fluorine. PTFE has one of the lowest coefficients of friction of any solid. Polytetrafluoroethylene is used as a non-stick coating for pans and other cookware. It is non-reactive, partly because of the strength of carbon–fluorine bonds, so it is often used in containers and pipework for reactive and corrosive chemicals. Where used as a lubricant ...
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Alkane
In organic chemistry, an alkane, or paraffin (a historical trivial name that also has other meanings), is an acyclic saturated hydrocarbon. In other words, an alkane consists of hydrogen and carbon atoms arranged in a tree structure in which all the carbon–carbon bonds are single. Alkanes have the general chemical formula . The alkanes range in complexity from the simplest case of methane (), where ''n'' = 1 (sometimes called the parent molecule), to arbitrarily large and complex molecules, like pentacontane () or 6-ethyl-2-methyl-5-(1-methylethyl) octane, an isomer of tetradecane (). The International Union of Pure and Applied Chemistry (IUPAC) defines alkanes as "acyclic branched or unbranched hydrocarbons having the general formula , and therefore consisting entirely of hydrogen atoms and saturated carbon atoms". However, some sources use the term to denote ''any'' saturated hydrocarbon, including those that are either monocyclic (i.e. the cycloalkanes ...
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