Propiolonitrile
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Propiolonitrile
Cyanoacetylene is an organic compound with formula or . It is the simplest cyanopolyyne. Cyanoacetylene has been detected by spectroscopic methods in interstellar clouds, in the coma of comet Hale–Bopp and in the atmosphere of Saturn's moon Titan, where it sometimes forms expansive fog-like clouds. Cyanoacetylene is one of the molecules that was produced in the Miller–Urey experiment. : H-C#C-H + H-C#N -> H-C#C-C#N + H2 See also * Dicyanoacetylene, N≡C−C≡C−C≡N *Diacetylene, H−C≡C−C≡C−H * Cyanogen, N≡C−C≡N * Hydrocyanic acid, H−C≡N *Polyyne In organic chemistry, a polyyne () is any organic compound with alternating single and triple bonds; that is, a series of consecutive alkynes, with ''n'' greater than 1. These compounds are also called polyacetylenes, especially in the natural p ..., R−(C≡C)''n''−R References {{Authority control Alkyne derivatives Conjugated nitriles ...
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Organic Compound
In chemistry, organic compounds are generally any chemical compounds that contain carbon-hydrogen or carbon-carbon bonds. Due to carbon's ability to catenate (form chains with other carbon atoms), millions of organic compounds are known. The study of the properties, reactions, and syntheses of organic compounds comprise the discipline known as organic chemistry. For historical reasons, a few classes of carbon-containing compounds (e.g., carbonate salts and cyanide salts), along with a few other exceptions (e.g., carbon dioxide, hydrogen cyanide), are not classified as organic compounds and are considered inorganic. Other than those just named, little consensus exists among chemists on precisely which carbon-containing compounds are excluded, making any rigorous definition of an organic compound elusive. Although organic compounds make up only a small percentage of Earth's crust, they are of central importance because all known life is based on organic compounds. Living t ...
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Cyanopolyyne
In organic chemistry, cyanopolyynes are a family of organic compounds with the chemical formula (''n'' = 3,5,7,…) and the structural formula (''n'' = 1,2,3,…). Structurally, they are polyynes with a cyano group () covalently bonded to one of the terminal acetylene units (). A rarely seen group of molecules both due to the difficulty in production and the unstable nature of the paired groups, the cyanopolyynes have been observed as a major organic component in interstellar clouds. This is believed to be due to the hydrogen scarcity of some of these clouds. Interference with hydrogen is one of the reason for the molecule's instability due to the energetically favorable dissociation back into hydrogen cyanide and acetylene. Cyanopolyynes were first discovered in interstellar molecular clouds in 1971 using millimeter wave and microwave telescopes. Since then many higher weight cyanopolyynes such as and have been discovered, although some of these ...
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Spectroscopy
Spectroscopy is the field of study that measures and interprets the electromagnetic spectra that result from the interaction between electromagnetic radiation and matter as a function of the wavelength or frequency of the radiation. Matter waves and acoustic waves can also be considered forms of radiative energy, and recently gravitational waves have been associated with a spectral signature in the context of the Laser Interferometer Gravitational-Wave Observatory (LIGO) In simpler terms, spectroscopy is the precise study of color as generalized from visible light to all bands of the electromagnetic spectrum. Historically, spectroscopy originated as the study of the wavelength dependence of the absorption by gas phase matter of visible light dispersed by a prism. Spectroscopy, primarily in the electromagnetic spectrum, is a fundamental exploratory tool in the fields of astronomy, chemistry, materials science, and physics, allowing the composition, physical structure and e ...
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Interstellar Cloud
An interstellar cloud is generally an accumulation of gas, plasma, and dust in our and other galaxies. Put differently, an interstellar cloud is a denser-than-average region of the interstellar medium, the matter and radiation that exists in the space between the star systems in a galaxy. Depending on the density, size, and temperature of a given cloud, its hydrogen can be neutral, making an H I region; ionized, or plasma making it an H II region; or molecular, which are referred to simply as molecular clouds, or sometime dense clouds. Neutral and ionized clouds are sometimes also called ''diffuse clouds''. An interstellar cloud is formed by the gas and dust particles from a red giant in its later life. Chemical compositions The chemical composition of interstellar clouds is determined by studying electromagnetic radiation that they emanate, and we receive – from radio waves through visible light, to gamma rays on the electromagnetic spectrum – that we receive from them. ...
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Coma (cometary)
The coma is the nebulous envelope around the nucleus of a comet, formed when the comet passes close to the Sun on its highly elliptical orbit; as the comet warms, parts of it sublimate. This gives a comet a "fuzzy" appearance when viewed in telescopes and distinguishes it from stars. The word ''coma'' comes from the Greek "kome" (κόμη), which means "hair" and is the origin of the word ''comet'' itself. The coma is generally made of ice and comet dust. Water composes up to 90% of the volatiles that outflow from the nucleus when the comet is within 3-4  AU of the Sun. The H2O parent molecule is destroyed primarily through photodissociation and to a much smaller extent photoionization. The solar wind plays a minor role in the destruction of water compared to photochemistry. Larger dust particles are left along the comet's orbital path while smaller particles are pushed away from the Sun into the comet's tail by light pressure. On 11 August 2014, astronomers released stu ...
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Comet Hale–Bopp
Comet Hale–Bopp (formally designated C/1995 O1) is a comet that was one of the most widely observed of the 20th century and one of the brightest seen for many decades. Alan Hale and Thomas Bopp discovered Comet Hale–Bopp separately on July 23, 1995, before it became visible to the naked eye. It is difficult to predict the maximum brightness of new comets with any degree of certainty, but Hale–Bopp exceeded most predictions when it passed perihelion on April 1, 1997, reaching about magnitude −1.8. It was visible to the naked eye for a record 18 months, due to its massive nucleus size. This is twice as long as the Great Comet of 1811, the previous record holder. Accordingly, Hale–Bopp was dubbed the great comet of 1997. Discovery The comet was discovered independently on July 23, 1995, by two observers, Alan Hale and Thomas Bopp, both in the United States. Hale had spent many hundreds of hours searching for comets without success, and was tracking ...
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Saturn
Saturn is the sixth planet from the Sun and the second-largest in the Solar System, after Jupiter. It is a gas giant with an average radius of about nine and a half times that of Earth. It has only one-eighth the average density of Earth; however, with its larger volume, Saturn is over 95 times more massive. Saturn's interior is most likely composed of a core of iron–nickel and rock (silicon and oxygen compounds). Its core is surrounded by a deep layer of metallic hydrogen, an intermediate layer of liquid hydrogen and liquid helium, and finally, a gaseous outer layer. Saturn has a pale yellow hue due to ammonia crystals in its upper atmosphere. An electrical current within the metallic hydrogen layer is thought to give rise to Saturn's planetary magnetic field, which is weaker than Earth's, but which has a magnetic moment 580 times that of Earth due to Saturn's larger size. Saturn's magnetic field strength is around one-twentieth of Jupiter's. The outer atmosphere is g ...
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Titan (moon)
Titan is the largest moon of Saturn and the second-largest natural satellite in the Solar System. It is the only moon known to have a dense atmosphere, and is the only known object in space other than Earth on which clear evidence of stable bodies of surface liquid has been found. Titan is one of the seven gravitationally rounded moons in orbit around Saturn, and the second most distant from Saturn of those seven. Frequently described as a planet-like moon, Titan is 50% larger (in diameter) than Earth's Moon and 80% more massive. It is the second-largest moon in the Solar System after Jupiter's moon Ganymede, and is larger than the planet Mercury, but only 40% as massive. Discovered in 1655 by the Dutch astronomer Christiaan Huygens, Titan was the first known moon of Saturn, and the sixth known planetary satellite (after Earth's moon and the four Galilean moons of Jupiter). Titan orbits Saturn at 20 Saturn radii. From Titan's surface, Saturn subtends an arc of 5.09 ...
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Nature (journal)
''Nature'' is a British weekly scientific journal founded and based in London, England. As a multidisciplinary publication, ''Nature'' features peer-reviewed research from a variety of academic disciplines, mainly in science and technology. It has core editorial offices across the United States, continental Europe, and Asia under the international scientific publishing company Springer Nature. ''Nature'' was one of the world's most cited scientific journals by the Science Edition of the 2019 ''Journal Citation Reports'' (with an ascribed impact factor of 42.778), making it one of the world's most-read and most prestigious academic journals. , it claimed an online readership of about three million unique readers per month. Founded in autumn 1869, ''Nature'' was first circulated by Norman Lockyer and Alexander Macmillan as a public forum for scientific innovations. The mid-20th century facilitated an editorial expansion for the journal; ''Nature'' redoubled its efforts in exp ...
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Miller–Urey Experiment
The Miller–Urey experiment (or Miller experiment) is a famous chemistry experiment that simulated the conditions thought at the time (1952) to be present in the atmosphere of the early, prebiotic Earth, in order to test the hypothesis of the chemical origin of life under those conditions. The experiment used water (H2O), methane (CH4), ammonia (NH3), hydrogen (H2), and an electric arc (the latter simulating hypothesized lightning). At the time, it supported Alexander Oparin's and J. B. S. Haldane's hypothesis that the hypothesized conditions on the primitive Earth favored chemical reactions that synthesized more complex organic compounds from simpler inorganic precursors. One of the most famous experiments of all time, it is considered to be groundbreaking, and to be the classic experiment investigating abiogenesis. It was performed in 1952 by Stanley Miller, supervised by Harold Urey at the University of Chicago, and published the following year. After Miller's death in 20 ...
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Dicyanoacetylene
Dicyanoacetylene, also called carbon subnitride or but-2-ynedinitrile (IUPAC), is a compound of carbon and nitrogen with chemical formula . It has a linear molecular structure, (often abbreviated as ), with alternating triple and single covalent bonds. It can be viewed as acetylene with the two hydrogen atoms replaced by cyanide groups. At room temperature, dicyanoacetylene is a clear liquid. Because of its high endothermic heat of formation, it can explode to carbon powder and nitrogen gas, and it burns in oxygen with a bright blue-white flame at a temperature of 5260 K (4990 °C, 9010 °F), the hottest flame in oxygen; burnt in ozone at high pressure the flame temperature exceeds 6000 K (5730 °C, 10340 °F). Synthesis Dicyanoacetylene can be prepared by passing nitrogen gas over a sample of graphite heated to temperatures between 2673 and 3000 K. As a reagent in organic chemistry Dicyanoacetylene is a powerful dienophile because the cyanide group ...
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Diacetylene
Diacetylene (also known as butadiyne) is the organic compound with the formula C4H2. It is the simplest compound containing two triple bonds. It is first in the series of polyynes, which are of theoretical but not of practical interest. Occurrence Diacetylene has been identified in the atmosphere of Titan and in the protoplanetary nebula CRL 618 by its characteristic vibrational spectrum. It is proposed to arise by a reaction between acetylene and the ethynyl radical (C2H), which is produced when acetylene undergoes photolysis. This radical can in turn attack the triple bond in acetylene and react efficiently even at low temperatures. Diacetylene has also been detected on the Moon. Preparation This compound may be made by the dehydrohalogenation of 1,4-dichloro-2-butyne by potassium hydroxide (in alcoholic medium) at ~70°C: : ClCH2C#CCH2Cl + 2 KOH -> HC#C-C#CH + 2 KCl + 2 H2O The bis(trimethylsilyl)-protected derivative may be prepared by the Hay coupling of (trim ...
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