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Potassium Picrate
{{chembox , Verifiedfields = changed , Watchedfields = changed , verifiedrevid = 428744204 , ImageFile =Potassium picrate.svg , ImageSize = , PIN = Potassium 2,4,6-trinitrophenoxide , OtherNames = Potassium 2,4,6-trinitrophenolate; Picric acid, potassium salt , Section1={{Chembox Identifiers , CASNo_Ref = {{cascite, correct, ?? , CASNo = 573-83-1 , EINECS = 209-361-0 , UNII_Ref = {{fdacite, correct, FDA , UNII = I7I1601L00 , PubChem = 68454 , ChemSpiderID_Ref = {{chemspidercite, changed, chemspider , ChemSpiderID = 61732 , SMILES = c1c(cc(c(c1 +=O) - - +=O) - +=O) - +, InChI = 1/C6H3N3O7.K/c10-6-4(8(13)14)1-3(7(11)12)2-5(6)9(15)16;/h1-2,10H;/q;+1/p-1 , InChIKey = RBGOCSKFMWMTRZ-REWHXWOFAJ , StdInChI_Ref = {{stdinchicite, changed, chemspider , StdInChI = 1S/C6H3N3O7.K/c10-6-4(8(13)14)1-3(7(11)12)2-5(6)9(15)16;/h1-2,10H;/q;+1/p-1 , StdInChIKey_Ref = {{stdinchicite, changed, chemspider , StdInChIKey = RBGOCSKFMWMTRZ-UHFFFAOYSA-M , Section2={{Chembox Properties , ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Picrate
A picrate is a salt containing the anion (O2N)3C6H2O− or an ester derivative of the picrate anion. These salts are often produced by reactions of picric acid (2,4,6-trinitrophenol). The picrate ion is intensely yellow, although many of its salts are brown or orange-red. Explosives Many picrates are explosives, for example ammonium picrate (known as Dunnite). Some are used as primary explosives, namely lead picrate or potassium picrate which find their use as primers for cartridge ammunition. Picrates of some metals tend to be significantly more sensitive to impact, friction and shock than picric acid itself. As a result, storage of picric acid (or mixtures containing it) in metal containers is strongly discouraged due to the high risk of accidental explosion. Other uses Ferrous picrate is used in some applications as a diesel fuel additive to achieve better mileage. Sodium picrate is used as an etchant in metallography to differ preeutectoid ferrite in hypoeutectoid stee ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Propellant
A propellant (or propellent) is a mass that is expelled or expanded in such a way as to create a thrust or other motive force in accordance with Newton's third law of motion, and "propel" a vehicle, projectile, or fluid payload. In vehicles, the engine that expels the propellant is called a reaction engine. Although technically a propellant is the reaction mass used to create thrust, the term "propellant" is often used to describe a substance which is contains both the reaction mass and the fuel that holds the energy used to accelerate the reaction mass. For example, the term "propellant" is often used in chemical rocket design to describe a combined fuel/propellant, although the propellants should not be confused with the fuel that is used by an engine to produce the energy that expels the propellant. Even though the byproducts of substances used as fuel are also often used as a reaction mass to create the thrust, such as with a chemical rocket engine, propellant and fuel are two ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lead Picrate
Lead picrate is an organic picrate salt. It is a sensitive and highly explosive compound that is typically found as a hydrate. Dry lead picrate is incredibly dangerous and cannot be handled without explosive decomposition occurring. History Lead picrate was first discovered in the early 1900s. It was investigated by numerous militaries during the First World War as a potential primary explosive, most notably Germany for using it in blasting caps. Preparation Numerous lead precursors can be used to create lead picrate. Two of the simplest examples of lead picrate synthesis are the addition of lead(II) oxide or lead carbonate Lead(II) carbonate is the chemical compound with the chemical formula . It is a white solid with several practical uses, despite its toxicity. It occurs naturally as the mineral cerussite. Structure Like all metal carbonates, lead(II) carbonate a ... with picric acid. References Picrates Lead(II) compounds {{explosive-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Picric Acid
Picric acid is an organic compound with the formula (O2N)3C6H2OH. Its IUPAC name is 2,4,6-trinitrophenol (TNP). The name "picric" comes from el, πικρός (''pikros''), meaning "bitter", due to its bitter taste. It is one of the most acidic phenols. Like other strongly nitrated organic compounds, picric acid is an explosive, which is its primary use. It has also been used as medicine (antiseptic, burn treatments) and as a dye. History Picric acid was probably first mentioned in the alchemical writings of Johann Rudolf Glauber. Initially, it was made by nitrating substances such as animal horn, silk, indigo, and natural resin, the synthesis from indigo first being performed by Peter Woulfe during 1771. The German chemist Justus von Liebig had named picric acid (rendered in French as ). Picric acid was given that name by the French chemist Jean-Baptiste Dumas in 1841. Its synthesis from phenol, and the correct determination of its formula, were accomplished during 1841. I ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dunnite
Dunnite, also known as Explosive D or systematically as ammonium picrate, is an explosive developed in 1906 by US Army Major Beverly W. Dunn, who later served as the chief inspector of the Bureau of Transportation Explosives. Ammonium picrate is a salt formed by reacting picric acid and ammonia. It is chemically related to the more stable explosive trinitrotoluene (TNT). History It was the first explosive used in an aerial bombing operation in military history, performed by Italian pilots in Libya in 1911. It was used extensively by the United States Navy during World War I. Though Dunnite was generally considered an insensitive substance, by 1911 the United States Army had abandoned its use in favor of other alternatives. The Navy, however, used it in armor-piercing artillery shells and projectiles, and in coastal defense. Dunnite typically did not detonate on striking heavy armor. Rather, the encasing shell would penetrate the armor, after which the charge would be triggere ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Surfactant
Surfactants are chemical compounds that decrease the surface tension between two liquids, between a gas and a liquid, or interfacial tension between a liquid and a solid. Surfactants may act as detergents, wetting agents, emulsifiers, foaming agents, or dispersants. The word "surfactant" is a blend of ''surface-active agent'', coined . Agents that increase surface tension are "surface active" in the literal sense but are not called surfactants as their effect is opposite to the common meaning. A common example of surface tension increase is salting out: by adding an inorganic salt to an aqueous solution of a weakly polar substance, the substance will precipitate. The substance may itself be a surfactant – this is one of the reasons why many surfactants are ineffective in sea water. Composition and structure Surfactants are usually organic compounds that are amphiphilic, meaning each molecule contains both a hydrophilic "water-seeking" group (the ''head''), and a hydro ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ammonium Picrate
Dunnite, also known as Explosive D or systematically as ammonium picrate, is an explosive developed in 1906 by US Army Major Beverly W. Dunn, who later served as the chief inspector of the Bureau of Transportation Explosives. Ammonium picrate is a salt formed by reacting picric acid and ammonia. It is chemically related to the more stable explosive trinitrotoluene (TNT). History It was the first explosive used in an aerial bombing operation in military history, performed by Italian pilots in Libya in 1911. It was used extensively by the United States Navy during World War I. Though Dunnite was generally considered an insensitive substance, by 1911 the United States Army had abandoned its use in favor of other alternatives. The Navy, however, used it in armor-piercing artillery shells and projectiles, and in coastal defense. Dunnite typically did not detonate on striking heavy armor. Rather, the encasing shell would penetrate the armor, after which the charge would be trigge ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Detonate
Detonation () is a type of combustion involving a supersonic exothermic front accelerating through a medium that eventually drives a shock front propagating directly in front of it. Detonations propagate supersonically through shock waves with speeds in the range of 1 km/sec and differ from deflagrations which have subsonic flame speeds in the range of 1 m/sec. Detonations occur in both conventional solid and liquid explosives, as well as in reactive gases. The velocity of detonation in solid and liquid explosives is much higher than that in gaseous ones, which allows the wave system to be observed with greater detail (higher resolution). A very wide variety of fuels may occur as gases (e.g. hydrogen), droplet fogs, or dust suspensions. In addition to dioxygen, oxidants can include halogen compounds, ozone, hydrogen peroxide and oxides of nitrogen. Gaseous detonations are often associated with a mixture of fuel and oxidant in a composition somewhat below conventional flammabilit ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Deflagration
Deflagration (Lat: ''de + flagrare'', "to burn down") is subsonic combustion in which a pre-mixed flame propagates through a mixture of fuel and oxidizer. Deflagrations can only occur in pre-mixed fuels. Most fires found in daily life are diffusion flames. Deflagrations with flame speeds in the range of 1 m/sec differ from detonations which propagate supersonically through shock waves with speeds in the range of 1 km/sec. Applications Deflagrations are often used in engineering applications when the goal is to move an object such as a bullet in a firearm, or a piston in an internal combustion engine with the force of the expanding gas. Deflagration systems and products can also be used in mining, demolition and stone quarrying via gas pressure blasting as a beneficial alternative to high explosives. Flame physics The underlying flame physics can be understood with the help of an idealized model consisting of a uniform one-dimensional tube of unburnt and burned gaseous fuel, sep ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lead Picrate
Lead picrate is an organic picrate salt. It is a sensitive and highly explosive compound that is typically found as a hydrate. Dry lead picrate is incredibly dangerous and cannot be handled without explosive decomposition occurring. History Lead picrate was first discovered in the early 1900s. It was investigated by numerous militaries during the First World War as a potential primary explosive, most notably Germany for using it in blasting caps. Preparation Numerous lead precursors can be used to create lead picrate. Two of the simplest examples of lead picrate synthesis are the addition of lead(II) oxide or lead carbonate Lead(II) carbonate is the chemical compound with the chemical formula . It is a white solid with several practical uses, despite its toxicity. It occurs naturally as the mineral cerussite. Structure Like all metal carbonates, lead(II) carbonate a ... with picric acid. References Picrates Lead(II) compounds {{explosive-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Explosive Primer
A detonator, frequently a blasting cap, is a device used to trigger an explosive device. Detonators can be chemically, mechanically, or electrically initiated, the last two being the most common. The commercial use of explosives uses electrical detonators or the capped fuse which is a length of safety fuse to which an ordinary detonator has been joined. Many detonators' primary explosive is a material called ASA compound. This compound is formed from lead azide, lead styphnate and aluminium and is pressed into place above the base charge, usually TNT or tetryl in military detonators and PETN in commercial detonators. Other materials such as DDNP (diazo dinitro phenol) are also used as the primary charge to reduce the amount of lead emitted into the atmosphere by mining and quarrying operations. Old detonators used mercury fulminate as the primary, often mixed with potassium chlorate to yield better performance. A blasting cap is a small sensitive primary explosive device ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
