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Polybutadiene Acrylonitrile
Polybutadiene acrylonitrile (PBAN) copolymer, also noted as polybutadiene—acrylic acid—acrylonitrile terpolymer is a copolymer compound used most frequently as a rocket propellant fuel mixed with ammonium perchlorate oxidizer. It was the binder formulation widely used on the 1960s–1970s big booster rocket, boosters (e.g., Titan III and Space Shuttle Solid Rocket Booster, Space Shuttle SRBs). Polybutadiene acrylonitrile is also sometimes used by amateurs due to simplicity, very low cost, and lower toxicity than the more common hydroxyl-terminated polybutadiene (HTPB). HTPB uses isocyanates for curing, which have a relatively quick curing time; however, they are also generally toxic. PBAN based propellants also have a slightly higher performance than HTPB based propellants. PBAN is normally cured with the addition of an epoxy resin, taking several days at elevated temperatures to cure. Usages PBAN was to be used in the Constellation program, later canceled, as this co ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Copolymer
In polymer chemistry, a copolymer is a polymer derived from more than one species of monomer. The polymerization of monomers into copolymers is called copolymerization. Copolymers obtained from the copolymerization of two monomer species are sometimes called ''bipolymers''. Those obtained from three and four monomers are called ''terpolymers'' and ''quaterpolymers'', respectively. Copolymers can be characterized by a variety of techniques such as NMR spectroscopy and size-exclusion chromatography to determine the molecular size, weight, properties, and composition of the material. Commercial copolymers include acrylonitrile butadiene styrene (ABS), styrene/butadiene co-polymer (SBR), nitrile rubber, styrene-acrylonitrile, styrene-isoprene-styrene (SIS) and ethylene-vinyl acetate, all of which are formed by chain-growth polymerization. Another production mechanism is step-growth polymerization, which is used to produce the nylon-12/6/66 copolymer of nylon 12, nylon 6 and nylon ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Isocyanate
In organic chemistry, isocyanate is the functional group with the formula . Organic compounds that contain an isocyanate group are referred to as isocyanates. An organic compound with two isocyanate groups is known as a diisocyanate. Diisocyanates are manufactured for the production of polyurethanes, a class of polymers. Isocyanates should not be confused with cyanate esters and isocyanides, very different families of compounds. The cyanate (cyanate ester) functional group () is arranged differently from the isocyanate group (). Isocyanides have the connectivity , lacking the oxygen of the cyanate groups. Structure and bonding In terms of bonding, isocyanates are closely related to carbon dioxide (CO2) and carbodiimides (C(NR)2). The C−N=C=O unit that defines isocyanates is planar, and the N=C=O linkage is nearly linear. In phenyl isocyanate, the C=N and C=O distances are respectively 1.195 and 1.173 Å. The C-N=C angle is 134.9° and the N=C=O angle is 173.1°. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Acrylate Polymers
An acrylate polymer (also known as acrylic or polyacrylate) is any of a group of polymers prepared from acrylate monomers. These plastics are noted for their transparency, resistance to breakage, and elasticity. Acrylate polymer is commonly used in cosmetics, such as nail polish, as an adhesive. History The first synthesis of acrylic polymer was reported by G.W.A Kahlbaum in 1880. Acrylic elastomers Acrylic elastomer is a general term for a type of synthetic rubber whose primary component is acrylic acid alkylester (ethyl or butyl ester). Acrylic elastomer possesses characteristics of heat and oil resistance, with the ability to withstand temperatures of 170–180 °C. It is used primarily for producing oil seals and packaging related to automobiles. Acrylic elastomer can generally be characterized as one of two types. "Old" types include ACM (copolymer of acrylic acid ester and 2-chloroethyl vinyl ether) containing chlorine and ANM (copolymer of acrylic acid ester and ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rocket Fuels
Rocket propellant is the reaction mass of a rocket. This reaction mass is ejected at the highest achievable velocity from a rocket engine to produce thrust. The energy required can either come from the propellants themselves, as with a chemical rocket, or from an external source, as with ion engines. Overview Rockets create thrust by expelling mass rear-ward, at high velocity. The thrust produced can be calculated by multiplying the mass flow rate of the propellants by their exhaust velocity relative to the rocket (specific impulse). A rocket can be thought of as being accelerated by the pressure of the combusting gases against the combustion chamber and nozzle, not by "pushing" against the air behind or below it. Rocket engines perform best in outer space because of the lack of air pressure on the outside of the engine. In space it is also possible to fit a longer nozzle without suffering from flow separation. Most chemical propellants release energy through redox chemistry, m ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Space Launch System
The Space Launch System (SLS) is an American super heavy-lift expendable launch vehicle developed by NASA. As of 2022, SLS has the highest payload capacity of any rocket in operational service, as well as the greatest liftoff thrust of any rocket in operation. As the primary launch vehicle of the Artemis moon landing program, SLS is designed to launch the crewed Orion spacecraft on a trans-lunar trajectory. The first uncrewed launch, Artemis 1, took place on 16 November 2022. Development of SLS began in 2011, as a replacement for the retired Space Shuttle as well as the cancelled Ares I and Ares V launch vehicles. As a Shuttle-derived vehicle, the Space Launch System reuses hardware from the Space Shuttle program, including the Space Shuttle Solid Rocket Booster, solid rocket boosters and RS-25, RS-25 first stage engines. An original flight date of late 2016 was delayed by nearly 6 years. The SLS program has Space Launch System#Criticism, attracted criticism for such de ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Constellation Program
The Constellation program (abbreviated CxP) was a crewed spaceflight program developed by NASA, the space agency of the United States, from 2005 to 2009. The major goals of the program were "completion of the International Space Station" and a "return to the Moon no later than 2020" with a crewed flight to the planet Mars as the ultimate goal. The program's logo reflected the three stages of the program: the Earth (ISS), the Moon, and finally Mars—while the Mars goal also found expression in the name given to the program's booster rockets: Ares (the Greek equivalent of the Roman god Mars). The technological aims of the program included the regaining of significant astronaut experience beyond low Earth orbit and the development of technologies necessary to enable sustained human presence on other planetary bodies. Constellation began in response to the goals laid out in the Vision for Space Exploration under NASA Administrator Sean O'Keefe and President George W. Bush. O'Keef ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Epoxy
Epoxy is the family of basic components or cured end products of epoxy resins. Epoxy resins, also known as polyepoxides, are a class of reactive prepolymers and polymers which contain epoxide groups. The epoxide functional group is also collectively called ''epoxy''. The IUPAC name for an epoxide group is an oxirane. Epoxy resins may be reacted (cross-linked) either with themselves through catalytic homopolymerisation, or with a wide range of co-reactants including polyfunctional amines, acids (and acid anhydrides), phenols, alcohols and thiols (usually called mercaptans). These co-reactants are often referred to as hardeners or curatives, and the cross-linking reaction is commonly referred to as curing. Reaction of polyepoxides with themselves or with polyfunctional hardeners forms a thermosetting polymer, often with favorable mechanical properties and high thermal and chemical resistance. Epoxy has a wide range of applications, including metal coatings, composites, use in ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Propellants
A propellant (or propellent) is a mass that is expelled or expanded in such a way as to create a thrust or other motive force in accordance with Newton's third law of motion, and "propel" a vehicle, projectile, or fluid payload. In vehicles, the engine that expels the propellant is called a reaction engine. Although technically a propellant is the reaction mass used to create thrust, the term "propellant" is often used to describe a substance which is contains both the reaction mass and the fuel that holds the energy used to accelerate the reaction mass. For example, the term "propellant" is often used in chemical rocket design to describe a combined fuel/propellant, although the propellants should not be confused with the fuel that is used by an engine to produce the energy that expels the propellant. Even though the byproducts of substances used as fuel are also often used as a reaction mass to create the thrust, such as with a chemical rocket engine, propellant and fuel are two ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydroxyl-terminated Polybutadiene
Hydroxyl-terminated polybutadiene (HTPB) is an oligomer of butadiene terminated at each end with a hydroxyl functional group. It reacts with isocyanates to form polyurethane polymers. HTPB is a translucent liquid with a color similar to wax paper and a viscosity similar to corn syrup. The properties vary because HTPB is a mixture rather than a pure compound, and it is manufactured to meet customers' specific requirements. A typical HTPB is R-45HTLO. This product consists of oligomeric units typically containing 40–50 butadiene molecules bonded together, with each end of the chain terminated with a hydroxyl Hgroup: R-45HTLO has a functionality of 2.4-2.6, which means that there is (approximately) one additional hydroxyl group located along the chain for every two oligomeric units. This provides side-to-side linkage for a stronger cured product. HTPB is usually cured by an addition reaction with di- or poly-isocyanate compounds. Uses Materials Production Polyurethanes prepare ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Polybutadiene
Polybutadiene utadiene rubber BRis a synthetic rubber. Polybutadiene rubber is a polymer formed from the polymerization of the monomer 1,3-butadiene. Polybutadiene has a high resistance to wear and is used especially in the manufacture of tires, which consumes about 70% of the production. Another 25% is used as an additive to improve the toughness (impact resistance) of plastics such as polystyrene and acrylonitrile butadiene styrene (ABS). Polybutadiene rubber accounted for about a quarter of total global consumption of synthetic rubbers in 2012. It is also used to manufacture golf balls, various elastic objects and to coat or encapsulate electronic assemblies, offering high electrical resistivity. The IUPAC refers to polybutadiene as poly (buta-1,3-diene). Buna rubber is a term used to describe an early generation of synthetic polybutadiene rubber produced in Germany by Bayer using sodium as a catalyst. History The Russian chemist Sergei Vasilyevich Lebedev was the f ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Space Shuttle Solid Rocket Booster
The Space Shuttle Solid Rocket Booster (SRB) was the first solid-propellant rocket to be used for primary propulsion on a vehicle used for human spaceflight. A pair of these provided 85% of the Space Shuttle's thrust at liftoff and for the first two minutes of ascent. After burnout, they were jettisoned and parachuted into the Atlantic Ocean where they were recovered, examined, refurbished, and reused. The Space Shuttle SRBs were the most powerful solid rocket motors to ever launch humans. The Space Launch System (SLS) SRBs, adapted from the shuttle, surpassed it as the most powerful solid rocket motors ever flown, after the launch of the Artemis-1 mission. Each Space Shuttle SRB provided a maximum thrust, roughly double the most powerful single-combustion chamber liquid-propellant rocket engine ever flown, the Rocketdyne F-1. With a combined mass of about , they comprised over half the mass of the Shuttle stack at liftoff. The motor segments of the SRBs were manufactured by ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Titan III
Titan was a family of United States expendable rockets used between 1959 and 2005. The Titan I and Titan II were part of the US Air Force's intercontinental ballistic missile (ICBM) fleet until 1987. The space launch vehicle versions contributed the majority of the 368 Titan launches, including all the Project Gemini crewed flights of the mid-1960s. Titan vehicles were also used to lift US military payloads as well as civilian agency reconnaissance satellites and to send interplanetary scientific probes throughout the Solar System. Titan I missile The HGM-25A Titan I, built by the Martin Company, was the first version of the Titan family of rockets. It began as a backup ICBM project in case the SM-65 Atlas was delayed. It was a two-stage rocket operational from early 1962 to mid-1965 whose LR-87 booster engine was powered by RP-1 (kerosene) and liquid oxygen (LOX). The ground guidance for the Titan was the UNIVAC ATHENA computer, designed by Seymour Cray, based in a harden ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
