Polybutadiene acrylonitrile (PBAN)

copolymer In polymer chemistry, a copolymer is a polymer derived from more than one species of monomer. The polymerization of monomers into copolymers is called copolymerization. Copolymers obtained from the copolymerization of two monomer species are some ...

, also noted as

polybutadiene Polybutadiene utadiene rubber BRis a synthetic rubber. Polybutadiene rubber is a polymer formed from the polymerization of the monomer 1,3-butadiene. Polybutadiene has a high resistance to wear and is used especially in the manufacture of tir ...

—

acrylic acid Acrylic acid (IUPAC: propenoic acid) is an organic compound with the formula CH2=CHCOOH. It is the simplest unsaturated carboxylic acid, consisting of a vinyl group connected directly to a carboxylic acid terminus. This colorless liquid has a ...

—

acrylonitrile Acrylonitrile is an organic compound with the formula and the structure . It is a colorless, volatile liquid although commercial samples can be yellow due to impurities. It has a pungent odor of garlic or onions. In terms of its molecular ...

terpolymer In polymer chemistry, a copolymer is a polymer derived from more than one species of monomer. The polymerization of monomers into copolymers is called copolymerization. Copolymers obtained from the copolymerization of two monomer species are some ...

is a copolymer compound used most frequently as a rocket propellant fuel mixed with

ammonium perchlorate Ammonium perchlorate ("AP") is an inorganic compound with the formula NH4 ClO4. It is a colorless or white solid that is soluble in water. It is a powerful oxidizer. Combined with a fuel, it can be used as a rocket propellant called ammonium pe ...

oxidizer. It was the binder formulation widely used on the 1960s–1970s big boosters (e.g.,

Titan III Titan was a family of United States expendable rockets used between 1959 and 2005. The Titan I and Titan II were part of the US Air Force's intercontinental ballistic missile (ICBM) fleet until 1987. The space launch vehicle versions contribute ...

and Space Shuttle SRBs). Polybutadiene acrylonitrile is also sometimes used by amateurs due to simplicity, very low cost, and lower toxicity than the more common

hydroxyl-terminated polybutadiene Hydroxyl-terminated polybutadiene (HTPB) is an oligomer of butadiene terminated at each end with a hydroxyl functional group. It reacts with isocyanates to form polyurethane polymers. HTPB is a translucent liquid with a color similar to wax paper a ...

(HTPB). HTPB uses

isocyanate In organic chemistry, isocyanate is the functional group with the formula . Organic compounds that contain an isocyanate group are referred to as isocyanates. An organic compound with two isocyanate groups is known as a diisocyanate. Diisocyan ...

s for curing, which have a relatively quick curing time; however, they are also generally toxic. PBAN based

propellants A propellant (or propellent) is a mass that is expelled or expanded in such a way as to create a thrust or other motive force in accordance with Newton's third law of motion, and "propel" a vehicle, projectile, or fluid payload. In vehicles, the e ...

also have a slightly higher performance than HTPB based propellants. PBAN is normally cured with the addition of an

epoxy Epoxy is the family of basic components or cured end products of epoxy resins. Epoxy resins, also known as polyepoxides, are a class of reactive prepolymers and polymers which contain epoxide groups. The epoxide functional group is also coll ...

resin, taking several days at elevated temperatures to cure.

Usages

PBAN was to be used in the

Constellation program The Constellation program (abbreviated CxP) was a crewed spaceflight program developed by NASA, the space agency of the United States, from 2005 to 2009. The major goals of the program were "completion of the International Space Station" and a " ...

, later canceled, as this

was to be used in the first stage of the Ares I rocket in five segments. However future versions of Ares I were discussed using liquid propellants as a potential alternative. PBAN is currently used in the solid rocket boosters on the SLS rocket.

References

Rocket fuels Acrylate polymers Copolymers Plastics {{rocket-stub