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Orthovanadate
In chemistry, a vanadate is an anionic coordination complex of vanadium. Often vanadate refers to oxoanions of vanadium, most of which exist in its highest oxidation state of +5. The complexes and are referred to as hexacyanovanadate(III) and nonachlorodivanadate(III), respectively. A simple vanadate ion is the tetrahedral orthovanadate anion, (which is also called vanadate(V)), which is present in e.g. sodium orthovanadate and in solutions of in strong base ( pH > 13). Conventionally this ion is represented with a single double bond, however this is a resonance form as the ion is a regular tetrahedron with four equivalent oxygen atoms. Additionally a range of polyoxovanadate ions exist which include discrete ions and "infinite" polymeric ions. There are also vanadates, such as rhodium vanadate, , which has a statistical rutile structure where the and ions randomly occupy the positions in the rutile lattice, that do not contain a lattice of cations and balancing ...
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Sodium Orthovanadate
Sodium orthovanadate is the inorganic compound with the chemical formula . It forms a dihydrate . Sodium orthovanadate is a salt of the oxyanion. It is a colorless, water-soluble solid. Synthesis and structure Sodium orthovanadate is produced by dissolving vanadium(V) oxide in a solution of sodium hydroxide: : The salt features tetrahedral anion centers linked to octahedral cation sites. Condensation equilibria Like many oxometalates, orthovanadate is subject to a number of reactions, which have been analyzed by 51V NMR studies. At high pH, ions exist in equilibrium with . At lower pH's, condensation ensues to give various polyoxovanadates. Ultimately, decavanadate is formed. Biochemistry Vanadates exhibit a variety of biological activities, in part because they serve as structural mimics of phosphates. It acts as a competitive inhibitor of ATPases, alkaline and acid phosphatases, and protein-phosphotyrosine phosphatases, and its inhibitory effects can be reversed by diluti ...
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Orthovanadate Anion
In chemistry, a vanadate is an anionic coordination complex of vanadium. Often vanadate refers to oxoanions of vanadium, most of which exist in its highest oxidation state of +5. The complexes and are referred to as hexacyanovanadate(III) and nonachlorodivanadate(III), respectively. A simple vanadate ion is the tetrahedral orthovanadate anion, (which is also called vanadate(V)), which is present in e.g. sodium orthovanadate and in solutions of in strong base ( pH > 13). Conventionally this ion is represented with a single double bond, however this is a resonance form as the ion is a regular tetrahedron with four equivalent oxygen atoms. Additionally a range of polyoxovanadate ions exist which include discrete ions and "infinite" polymeric ions. There are also vanadates, such as rhodium vanadate, , which has a statistical rutile structure where the and ions randomly occupy the positions in the rutile lattice, that do not contain a lattice of cations and balancing ...
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Vanadium
Vanadium is a chemical element with the symbol V and atomic number 23. It is a hard, silvery-grey, malleable transition metal. The elemental metal is rarely found in nature, but once isolated artificially, the formation of an oxide layer ( passivation) somewhat stabilizes the free metal against further oxidation. Spanish scientist Andrés Manuel del Río discovered compounds of vanadium in 1801 in Mexico by analyzing a new lead-bearing mineral he called "brown lead". Though he initially presumed its qualities were due to the presence of a new element, he was later erroneously convinced by French chemist Hippolyte Victor Collet-Descotils that the element was just chromium. Then in 1830, Nils Gabriel Sefström generated chlorides of vanadium, thus proving there was a new element, and named it "vanadium" after the Scandinavian goddess of beauty and fertility, Vanadís (Freyja). The name was based on the wide range of colors found in vanadium compounds. Del Rio's lead mineral was ...
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Tungstate
In chemistry, a tungstate is a compound that contains an oxyanion of tungsten or is a mixed oxide containing tungsten. The simplest tungstate ion is , "orthotungstate". Many other tungstates belong to a large group of polyatomic ions that are termed polyoxometalates, ("POMs"), and specifically termed isopolyoxometalates as they contain, along with oxygen and maybe hydrogen, only one other element. Almost all useful tungsten ores are tungstates. Structures Orthotungstates feature tetrahedral W(VI) centres with short W–O distances of 1.79  Å. Structurally, they resemble sulfates. Six-coordinate, octahedral tungsten dominates in the polyoxotungstates. In these compounds, the W–O distances are elongated. Some examples of tungstate ions: * (hydrogentungstate) * polymeric ions of various structures in , and Wells A.F. (1984) ''Structural Inorganic Chemistry'' 5th edition Oxford Science Publications * (paratungstate A) * (tungstate Y)Jon A. McCleverty, N. G. Connelly,Nom ...
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Vanadates
Vanadates can refer to: * Ammonium vanadate (other) Ammonium vanadate may refer to: * Ammonium metavanadate (ammonium trioxovanadate(V)), NH4VO3 * Ammonium orthovanadate (ammonium tetraoxovanadate(V)), (NH4)3VO4, a compound related to Ammonium metavanadate * Ammonium hexavanadate, (NH4)2V6O16, a ... * Sodium vanadate (other) {{disambig ...
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Journal Of Inorganic Biochemistry
The ''Journal of Inorganic Biochemistry'' is a monthly peer-reviewed scientific journal covering research on the inorganic aspects of biochemistry, such as metalloenzymes and metallobiomolecules. The journal was established in 1971 as ''Bioinorganic Chemistry'', obtaining its current name in 1979. Since 1996, the editor-in-chief has been John H. Dawson ( University of South Carolina). According to the ''Journal Citation Reports'', the journal has a 2020 impact factor The impact factor (IF) or journal impact factor (JIF) of an academic journal is a scientometric index calculated by Clarivate that reflects the yearly mean number of citations of articles published in the last two years in a given journal, as i ... of 4.155, ranking it 7th out of 44 journals in the category "Chemistry, Inorganic and Nuclear". References External links * Biochemistry journals Elsevier academic journals Monthly journals Publications established in 1971 Inorganic chemistry journals Eng ...
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Journal Of Biological Chemistry
The ''Journal of Biological Chemistry'' (''JBC'') is a weekly peer-reviewed scientific journal that was established in 1905., jbc.org Since 1925, it is published by the American Society for Biochemistry and Molecular Biology. It covers research in areas of biochemistry and molecular biology. The editor is Alex Toker. As of January 2021, the journal is fully open access. In press articles are available free on its website immediately after acceptance. Editors The following individuals have served as editors of the journal: * 1906–1909: John Jacob Abel and Christian Archibald Herter * 1909–1910: Christian Archibald Herter * 1910–1914: Alfred Newton Richards * 1914–1925: Donald D. Van Slyke * 1925–1936: Stanley R. Benedict. After Benedict died, John T. Edsall served as temporary editor until the next editor was appointed. * 1937–1958: Rudolph J. Anderson * 1958–1967: John T. Edsall * 1968–1971: William Howard Stein * 1971–2011: Herbert Tabor * 2011–2015: ...
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The Vascular System
''The'' () is a grammatical article in English, denoting persons or things that are already or about to be mentioned, under discussion, implied or otherwise presumed familiar to listeners, readers, or speakers. It is the definite article in English. ''The'' is the most frequently used word in the English language; studies and analyses of texts have found it to account for seven percent of all printed English-language words. It is derived from gendered articles in Old English which combined in Middle English and now has a single form used with nouns of any gender. The word can be used with both singular and plural nouns, and with a noun that starts with any letter. This is different from many other languages, which have different forms of the definite article for different genders or numbers. Pronunciation In most dialects, "the" is pronounced as (with the voiced dental fricative followed by a schwa) when followed by a consonant sound, and as (homophone of the archaic pr ...
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SERCA
SERCA, or sarco/endoplasmic reticulum Ca2+-ATPase, or SR Ca2+-ATPase, is a calcium ATPase-type P-ATPase. Its major function is to transport calcium from the cytosol into the sarcoplasmic reticulum. Function SERCA is a P-type ATPase. It resides in the sarcoplasmic reticulum (SR) within myocytes. It is a Ca2+ ATPase that transfers Ca2+ from the cytosol of the cell to the lumen of the SR. This uses energy from ATP hydrolysis during muscle relaxation. There are 3 major domains on the cytoplasmic face of SERCA: the phosphorylation and nucleotide-binding domains, which form the catalytic site, and the actuator domain, which is involved in the transmission of major conformational changes. In addition to its calcium-transporting functions, SERCA1 generates heat in brown adipose tissue and in skeletal muscles. Along with the heat it naturally produces due to its inefficiency in pumping ions, when it binds to a regulator called sarcolipin it stops pumping and functions solely as an AT ...
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Plasma Membrane Ca2+ ATPase
Plasma or plasm may refer to: Science * Plasma (physics), one of the four fundamental states of matter * Plasma (mineral), a green translucent silica mineral * Quark–gluon plasma, a state of matter in quantum chromodynamics Biology * Blood plasma, the yellow-colored liquid component of blood, in which blood cells are suspended * Cytoplasm, a jelly-like substance that fills cells, suspends and protects organelles * Germ plasm, a zone in the cytoplasm determining germ cells * Germplasm, describes a collection of genetic resources for an organism * Milk plasma or whey, the liquid remaining after milk has been curdled and strained * Nucleoplasm, a highly viscous liquid that surrounds the chromosomes and nucleoli * Plasma cell, white blood cells that secrete large volumes of antibodies * Protoplasm, the entire living substance inside the cell membrane or cell wall Technology * Plasma (engine), a real-time 3D game engine from Cyan Worlds * Plasma display, a flat-panel electronic visu ...
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Na+/K+-ATPase
NA, N.A., Na, nA or n/a may refer to: Chemistry and physics * Sodium, symbol Na, a chemical element * Avogadro constant (''N''A) * Nucleophilic addition, a type of reaction in organic chemistry * Numerical aperture, a number that characterizes a range of angles in an optical system * nA, the symbol for nanoampere * Naturally aspirated engine Biology and medicine * Na (tree) or ''Mesua ferrea'', a species of tree native to Sri Lanka * Neuroacanthocytosis, a neurological condition * ''Nomina Anatomica'', a former international standard for human anatomical nomenclature * Noradrenaline, a hormone * Nucleic acid analogue, compounds analogous to naturally occurring RNA and DNA Places Current * Namibia (ISO country code) * Naples (car number plate code: NA), Italy * North America, a continent * North Africa, a subcontinent Historical * Netherlands Antilles (former international vehicle registration code: NA) * Na (Chinese state), a small state of the Chinese Zhou dynasty from ...
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ATPase
ATPases (, Adenosine 5'-TriPhosphatase, adenylpyrophosphatase, ATP monophosphatase, triphosphatase, SV40 T-antigen, ATP hydrolase, complex V (mitochondrial electron transport), (Ca2+ + Mg2+)-ATPase, HCO3−-ATPase, adenosine triphosphatase) are a class of enzymes that catalyze the decomposition of ATP into ADP and a free phosphate ion or the inverse reaction. This dephosphorylation reaction releases energy, which the enzyme (in most cases) harnesses to drive other chemical reactions that would not otherwise occur. This process is widely used in all known forms of life. Some such enzymes are integral membrane proteins (anchored within biological membranes), and move solutes across the membrane, typically against their concentration gradient. These are called transmembrane ATPases. Functions Transmembrane ATPases import metabolites necessary for cell metabolism and export toxins, wastes, and solutes that can hinder cellular processes. An important example is the sodium-potass ...
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