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List Of Chemical Compounds With Unusual Names
IUPAC nomenclature, Chemical nomenclature, replete as it is with chemical compound, compounds with complex names, is a wikt:repository, repository for some names that may be considered unusual. A browse through the ''Physical Constants of Organic Compounds'' in the ''CRC Handbook of Chemistry and Physics'' (a fundamental resource) will reveal not just the whimsical work of chemists, but the sometimes peculiar compound names that occur as the consequence of simple Contrast (linguistics), juxtaposition. Some names derive legitimately from their chemical makeup, from the geographic region where they may be found, the plant or animal species from which they are isolated or the name of the discoverer. Some are given intentionally unusual trivial names based on their structure, a notable property or at the whim of those who first isolate them. However, many trivial names predate formal naming conventions. Trivial names can also be ambiguous or carry different meanings in different indust ...
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IUPAC Nomenclature
A chemical nomenclature is a set of rules to generate systematic names for chemical compounds. The nomenclature used most frequently worldwide is the one created and developed by the International Union of Pure and Applied Chemistry (IUPAC). The IUPAC's rules for naming organic and inorganic compounds are contained in two publications, known as the ''Blue Book''. . and the '' Red Book'',. respectively. A third publication, known as the '' Green Book'',. recommends the use of symbols for physical quantities (in association with the IUPAP), while a fourth, the ''Gold Book'',''Compendium of Chemical Terminology, IMPACT Recommendations (2nd Ed.)'', Oxford:Blackwell Scientific Publications. (1997) defines many technical terms used in chemistry. Similar compendia exist for biochemistry''Biochemical Nomenclature and Related Documents'', London: Portland Press, 1992. (the ''White Book'', in association with the IUBMB), analytical chemistry (the '' Orange Book''), macromolecular chemistr ...
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Basketane
Basketane is a polycyclic alkane with the chemical formula C10H12. The name is taken from its structural similarity to a basket shape. Basketane was first synthesized in 1966, independently by Masamune and Dauben and Whalen. A patent application published in 1988 used basketane, which is a hydrocarbon, as a source material in doping thin diamond layers because of the molecule's high vapor pressure, carbon ring structure, and fewer hydrogen-to-carbon bond ratio. Chemical nomenclature In the year 1989 and before the synthesis of basketane, historic chemists were intrigued by the structural make-up of molecules, specifically those in objects seen in everyday life. Using supramolecular chemistry, molecules such as cubane and basketane were named according to their corresponding shape and historically revealed certain characteristics and personal motives of chemists at that time. Naming these uniquely shaped molecules were also done considering chemical nomenclature such as adding " ...
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Fenestrane
A fenestrane in organic chemistry is a type of chemical compound with a central quaternary carbon atom which serves as a common vertex for four fused carbocycles. They can be regarded as spiro compounds twice over. Because of their inherent strain and instability, fenestranes are of theoretical interest to chemists. The name—proposed in 1972 by Vlasios Georgian and Martin Saltzman—is derived from the Latin word for window, ''fenestra''. Georgian had intended that "fenestrane" solely referred to .4.4.4enestrane, whose skeletal structure looks like windows, and Kenneth B. Wiberg called that specific structure "windowpane". The term ''fenestrane'' has since become generalized to refer to the whole class of molecules that have various other ring-sizes. Georgian recommended ''rosettane'' for the class, based on the structural appearance as a rosette of flowers. Nomenclature and structure Structures within this class of chemicals can be named according to the number of atoms in ...
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Dodecahedron
In geometry, a dodecahedron (Greek , from ''dōdeka'' "twelve" + ''hédra'' "base", "seat" or "face") or duodecahedron is any polyhedron with twelve flat faces. The most familiar dodecahedron is the regular dodecahedron with regular pentagons as faces, which is a Platonic solid. There are also three regular star dodecahedra, which are constructed as stellations of the convex form. All of these have icosahedral symmetry, order 120. Some dodecahedra have the same combinatorial structure as the regular dodecahedron (in terms of the graph formed by its vertices and edges), but their pentagonal faces are not regular: The pyritohedron, a common crystal form in pyrite, has pyritohedral symmetry, while the tetartoid has tetrahedral symmetry. The rhombic dodecahedron can be seen as a limiting case of the pyritohedron, and it has octahedral symmetry. The elongated dodecahedron and trapezo-rhombic dodecahedron variations, along with the rhombic dodecahedra, are space-filling. There ...
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Platonic Hydrocarbon
In organic chemistry, a Platonic hydrocarbon is a hydrocarbon (molecule) whose structure matches one of the five Platonic solids, with carbon atoms replacing its vertices, carbon–carbon bonds replacing its edges, and hydrogen atoms as needed. Not all Platonic solids have molecular hydrocarbon counterparts; those that do are the tetrahedron (tetrahedrane), the cube (cubane), and the dodecahedron (dodecahedrane). Tetrahedrane Tetrahedrane (C4H4) is a hypothetical compound. It has not yet been synthesized without substituents, but it is predicted to be kinetically stable in spite of its angle strain. Some stable derivatives, including tetra( ''tert''-butyl)tetrahedrane (a hydrocarbon) and tetra(trimethylsilyl)tetrahedrane, have been produced. Cubane Cubane (C8H8) has been synthesized. Although it has high angle strain, cubane is kinetically stable, due to a lack of readily available decomposition paths. Octahedrane Angle strain would make an octahedron highly unstable due to ...
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Dodecahedrane
Dodecahedrane is a chemical compound, a hydrocarbon with formula , whose carbon atoms are arranged as the vertices (corners) of a regular dodecahedron. Each carbon is bound to three neighbouring carbon atoms and to a hydrogen atom. This compound is one of the three possible Platonic hydrocarbons, the other two being cubane and tetrahedrane. Dodecahedrane does not occur in nature and has no significant uses. It was synthesized by Leo Paquette in 1982, primarily for the "aesthetically pleasing symmetry of the dodecahedral framework". For many years, dodecahedrane was the simplest real carbon-based molecule with full icosahedral symmetry. Buckminsterfullerene (), discovered in 1985, also has the same symmetry, but has three times as many carbons and 50% more atoms overall. The synthesis of the C20 fullerene in 2000, from brominated dodecahedrane, may have demoted to second place. Structure The angle between the C-C bonds in each carbon atom is 108°, which is the angle between a ...
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Carbon
Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent In chemistry, the valence (US spelling) or valency (British spelling) of an element is the measure of its combining capacity with other atoms when it forms chemical compounds or molecules. Description The combining capacity, or affinity of an ...—its atom making four electrons available to form covalent bond, covalent chemical bonds. It belongs to group 14 of the periodic table. Carbon makes up only about 0.025 percent of Earth's crust. Three Isotopes of carbon, isotopes occur naturally, Carbon-12, C and Carbon-13, C being stable, while Carbon-14, C is a radionuclide, decaying with a half-life of about 5,730 years. Carbon is one of the Timeline of chemical element discoveries#Ancient discoveries, few elements known since antiquity. Carbon is the 15th Abundance of elements in Earth's crust, most abundant element in the Earth's crust, and the Abundance of the c ...
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Hydrocarbon
In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or exemplified by the odors of gasoline and lighter fluid. They occur in a diverse range of molecular structures and phases: they can be gases (such as methane and propane), liquids (such as hexane and benzene), low melting solids (such as paraffin wax and naphthalene) or polymers (such as polyethylene and polystyrene). In the fossil fuel industries, ''hydrocarbon'' refers to the naturally occurring petroleum, natural gas and coal, and to their hydrocarbon derivatives and purified forms. Combustion of hydrocarbons is the main source of the world's energy. Petroleum is the dominant raw-material source for organic commodity chemicals such as solvents and polymers. Most anthropogenic (human-generated) emissions of greenhouse gases are carbon di ...
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Cuban
Cuban may refer to: * Something of, from, or related to Cuba, a country in the Caribbean * Cubans, people from Cuba, or of Cuban descent ** Cuban exile, a person who left Cuba for political reasons, or a descendant thereof * Cuban citizen, a person who is part of the Cuban population, see Demographics of Cuba * Cuban Spanish, the dialect of Cuba * Cuban Americans, citizens of the United States who are of Cuban descent * Cuban cigar, often referred to as "Cubans" * Cuban culture * Cuban cuisine ** Cuban sandwich * Cuban-eight, a type of aerobatic maneuver People with the surname * Brian Cuban (born 1961), American lawyer and activist * Mark Cuban (born 1958), American entrepreneur See also * Cuban Missile Crisis * List of Cubans * * Cuban Boys, a British music act * Kuban (other) * Cubane Cubane () is a synthetic hydrocarbon compound that consists of eight carbon atoms arranged at the corners of a cube, with one hydrogen atom attached to each carbon atom. A solid cryst ...
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Cubane
Cubane () is a synthetic hydrocarbon compound that consists of eight carbon atoms arranged at the corners of a cube, with one hydrogen atom attached to each carbon atom. A solid crystalline substance, cubane is one of the Platonic hydrocarbons and a member of the prismanes. It was first synthesized in 1964 by Philip Eaton and Thomas Cole. Before this work, Eaton believed that cubane would be impossible to synthesize due to the "required 90 degree bond angles". The cubic shape requires the carbon atoms to adopt an unusually sharp 90° bonding angle, which would be highly strained as compared to the 109.45° angle of a tetrahedral carbon. Once formed, cubane is quite kinetically stable, due to a lack of readily available decomposition paths. It is the simplest hydrocarbon with octahedral symmetry. Having high potential energy but kinetic stability makes cubane and its derivative compounds useful for controlled energy storage. For example, octanitrocubane and heptanitrocubane have ...
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