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Levich Constant
A Levich constant (B) is often used in order to simplify the Levich equation. Furthermore, B is readily extracted from rotating disk electrode experimental data. The B can be defined as: B= (0.620) n F A D^\fracv^\fracC where * ''n'' is the number of moles of electrons transferred in the half reaction (number) * ''F'' is the Faraday constant (C/mol) * ''A'' is the electrode area (cm2) * ''D'' is the diffusion coefficient (see Fick's law of diffusion) (cm2/s) * ''v'' is the kinematic viscosity (cm2/s) * ''C'' is the analyte An analyte, component (in clinical chemistry), or chemical species is a substance or chemical constituent that is of interest in an analytical procedure. The purest substances are referred to as analytes, such as 24 karat gold, NaCl, water, etc. ... concentration (mol/cm3) References Electrochemical equations Electrochemistry {{electrochem-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Levich Equation
The Levich equation models the diffusion and solution flow conditions around a rotating disk electrode (RDE). It is named after Veniamin Grigorievich Levich who first developed an RDE as a tool for electrochemical research. It can be used to predict the current observed at an RDE, in particular, the Levich equation gives the height of the sigmoidal wave observed in rotating disk voltammetry. The sigmoidal wave height is often called the Levich current. Equation The Levich equation is written as: :I_L = (0.620) n F A D^\frac \omega^\fracv^\fracC where ''I''L is the Levich current (A), ''n'' is the number of moles of electrons transferred in the half reaction (number), ''F'' is the Faraday constant (C/mol), ''A'' is the electrode area (cm2), ''D'' is the diffusion coefficient (see Fick's law of diffusion) (cm2/s), ''ω'' is the angular rotation rate of the electrode (rad/s), ''v'' is the kinematic viscosity (cm2/s), ''C'' is the analyte An analyte, component (in clinical chemi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rotating Disk Electrode
A rotating disk electrode (RDE) is a working electrode used in three electrode systems for hydrodynamic voltammetry.Bard, A.J.; Faulkner, L.R. Electrochemical Methods: Fundamentals and Applications. New York: John Wiley & Sons, 2nd Edition, 2000. The electrode rotates during experiments inducing a flux of analyte to the electrode. These working electrodes are used in electrochemical studies when investigating reaction mechanisms related to redox chemistry, among other chemical phenomena. The more complex rotating ring-disk electrode can be used as a rotating disk electrode if the ring is left inactive during the experiment. Structure The electrode includes a conductive disk embedded in an inert non-conductive polymer or resin that can be attached to an electric motor that has very fine control of the electrode's rotation rate. The disk, like any working electrode, is generally made of a noble metal or glassy carbon, however any conductive material can be used based on specifi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrons
The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have no known components or substructure. The electron's mass is approximately 1/1836 that of the proton. Quantum mechanical properties of the electron include an intrinsic angular momentum ( spin) of a half-integer value, expressed in units of the reduced Planck constant, . Being fermions, no two electrons can occupy the same quantum state, in accordance with the Pauli exclusion principle. Like all elementary particles, electrons exhibit properties of both particles and waves: They can collide with other particles and can be diffracted like light. The wave properties of electrons are easier to observe with experiments than those of other particles like neutrons and protons because electrons have a lower mass and hence a longer de Broglie wav ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Half Reaction
A half reaction (or half-cell reaction) is either the oxidation or reduction reaction component of a redox reaction. A half reaction is obtained by considering the change in oxidation states of individual substances involved in the redox reaction. Often, the concept of half reactions is used to describe what occurs in an electrochemical cell, such as a Galvanic cell battery. Half reactions can be written to describe both the metal undergoing oxidation (known as the anode) and the metal undergoing reduction (known as the cathode). Half reactions are often used as a method of balancing redox reactions. For oxidation-reduction reactions in acidic conditions, after balancing the atoms and oxidation numbers, one will need to add H+ ions to balance the hydrogen ions in the half reaction. For oxidation-reduction reactions in basic conditions, after balancing the atoms and oxidation numbers, first treat it as an acidic solution and then add OH− ions to balance the H+ ions in the half rea ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Faraday Constant
In physical chemistry, the Faraday constant, denoted by the symbol and sometimes stylized as ℱ, is the electric charge per mole of elementary charges. It is named after the English scientist Michael Faraday. Since the 2019 redefinition of SI base units, which took effect on 20 May 2019, the Faraday constant has the exactly defined value given by the product of the elementary charge ''e'' and Avogadro constant ''N''A: : : :. Derivation The Faraday constant can be thought of as the conversion factor between the mole (used in chemistry) and the coulomb (used in physics and in practical electrical measurements), and is therefore of particular use in electrochemistry. Because 1 mole contains exactly entities, and 1 coulomb contains exactly elementary charges, the Faraday constant is given by the quotient of these two quantities: :. One common use of the Faraday constant is in electrolysis calculations. One can divide the amount of charge (the current integrated over time) ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fick's Law Of Diffusion
Fick's laws of diffusion describe diffusion and were derived by Adolf Fick in 1855. They can be used to solve for the diffusion coefficient, . Fick's first law can be used to derive his second law which in turn is identical to the diffusion equation. A diffusion process that obeys Fick's laws is called normal or Fickian diffusion; otherwise, it is called anomalous diffusion or non-Fickian diffusion. History In 1855, physiologist Adolf Fick first reported* * his now well-known laws governing the transport of mass through diffusive means. Fick's work was inspired by the earlier experiments of Thomas Graham, which fell short of proposing the fundamental laws for which Fick would become famous. Fick's law is analogous to the relationships discovered at the same epoch by other eminent scientists: Darcy's law (hydraulic flow), Ohm's law (charge transport), and Fourier's Law (heat transport). Fick's experiments (modeled on Graham's) dealt with measuring the concentrations and ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Kinematic Viscosity
The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water. Viscosity quantifies the internal frictional force between adjacent layers of fluid that are in relative motion. For instance, when a viscous fluid is forced through a tube, it flows more quickly near the tube's axis than near its walls. Experiments show that some stress (such as a pressure difference between the two ends of the tube) is needed to sustain the flow. This is because a force is required to overcome the friction between the layers of the fluid which are in relative motion. For a tube with a constant rate of flow, the strength of the compensating force is proportional to the fluid's viscosity. In general, viscosity depends on a fluid's state, such as its temperature, pressure, and rate of deformation. However, the dependence on some of these properties is n ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Analyte
An analyte, component (in clinical chemistry), or chemical species is a substance or chemical constituent that is of interest in an analytical procedure. The purest substances are referred to as analytes, such as 24 karat gold, NaCl, water, etc. In reality, no substance has been found to be 100% pure in its quality, so a substance that is found to be most pure (for some metals, 99% after electrolysis) is called an analyte. See also *Analytical chemistry *Immunoassay *Magnetic immunoassay Magnetic immunoassay (MIA) is a type of diagnostic immunoassay using magnetic beads as labels in lieu of conventional enzymes (ELISA), radioisotopes (RIA) or fluorescent moieties ( fluorescent immunoassays) to detect a specified analyte. MIA involv ... References Analytical chemistry {{Analytical-chemistry-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrochemical Equations
Electrochemistry is the branch of physical chemistry concerned with the relationship between electrical potential difference, as a measurable and quantitative phenomenon, and identifiable chemical change, with the potential difference as an outcome of a particular chemical change, or vice versa. These reactions involve electrons moving via an electronically-conducting phase (typically an external electrical circuit, but not necessarily, as in electroless plating) between electrodes separated by an ionically conducting and electronically insulating electrolyte (or ionic species in a solution). When a chemical reaction is driven by an electrical potential difference, as in electrolysis, or if a potential difference results from a chemical reaction as in an electric battery or fuel cell, it is called an ''electrochemical'' reaction. Unlike in other chemical reactions, in electrochemical reactions electrons are not transferred directly between atoms, ions, or molecules, but via the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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