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Rotating Disk Electrode
A rotating disk electrode (RDE) is a working electrode used in three electrode systems for hydrodynamic voltammetry.Bard, A.J.; Faulkner, L.R. Electrochemical Methods: Fundamentals and Applications. New York: John Wiley & Sons, 2nd Edition, 2000. The electrode rotates during experiments inducing a flux of analyte to the electrode. These working electrodes are used in electrochemical studies when investigating reaction mechanisms related to redox chemistry, among other chemical phenomena. The more complex rotating ring-disk electrode can be used as a rotating disk electrode if the ring is left inactive during the experiment. Structure The electrode includes a conductive disk embedded in an inert non-conductive polymer or resin that can be attached to an electric motor that has very fine control of the electrode's rotation rate. The disk, like any working electrode, is generally made of a noble metal or glassy carbon, however any conductive material can be used based on specifi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Working Electrode
The working electrode is the electrode in an electrochemical system on which the reaction of interest is occurring. The working electrode is often used in conjunction with an auxiliary electrode, and a reference electrode in a three electrode system. Depending on whether the reaction on the electrode is a reduction or an oxidation, the working electrode is called cathodic or anodic, respectively. Common working electrodes can consist of materials ranging from inert metals such as gold, silver or platinum, to inert carbon such as glassy carbon, boron doped diamond or pyrolytic carbon, and mercury drop and film electrodes. Chemically modified electrodes are employed for the analysis of both organic and inorganic samples. Special types * Ultramicroelectrode (UME) * Rotating disk electrode (RDE) * Rotating ring-disk electrode (RRDE) * Hanging mercury drop electrode (HMDE) * Dropping mercury electrode (DME) See also * Auxiliary electrode * Electrochemical cell * Electrochemistry ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Angular Velocity
In physics, angular velocity or rotational velocity ( or ), also known as angular frequency vector,(UP1) is a pseudovector representation of how fast the angular position or orientation of an object changes with time (i.e. how quickly an object rotates or revolves relative to a point or axis). The magnitude of the pseudovector represents the ''angular speed'', the rate at which the object rotates or revolves, and its direction is normal to the instantaneous plane of rotation or angular displacement. The orientation of angular velocity is conventionally specified by the right-hand rule.(EM1) There are two types of angular velocity. * Orbital angular velocity refers to how fast a point object revolves about a fixed origin, i.e. the time rate of change of its angular position relative to the origin. * Spin angular velocity refers to how fast a rigid body rotates with respect to its center of rotation and is independent of the choice of origin, in contrast to orbital angular ve ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Liquid Metal Electrode
A liquid metal electrode is an electrode that uses a liquid metal, such as mercury, Galinstan, and NaK. They can be used in electrocapillarity, voltammetry, and impedance measurements. Dropping mercury electrode The dropping mercury electrode (DME) is a working electrode made of mercury and used in polarography. Experiments run with mercury electrodes are referred to as forms of polarography even if the experiments are identical or very similar to a corresponding voltammetry experiment which uses solid working electrodes. Like other working electrodes these electrodes are used in electrochemical studies using three electrode systems when investigating reaction mechanisms related to redox chemistry among other chemical phenomena. Structure A flow of mercury passes through an insulating capillary producing a droplet which grows from the end of the capillary in a reproducible way. Each droplet grows until it reaches a diameter of about a millimeter and releases. The released dro ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Levich Equation
The Levich equation models the diffusion and solution flow conditions around a rotating disk electrode (RDE). It is named after Veniamin Grigorievich Levich who first developed an RDE as a tool for electrochemical research. It can be used to predict the current observed at an RDE, in particular, the Levich equation gives the height of the sigmoidal wave observed in rotating disk voltammetry. The sigmoidal wave height is often called the Levich current. Equation The Levich equation is written as: :I_L = (0.620) n F A D^\frac \omega^\fracv^\fracC where ''I''L is the Levich current (A), ''n'' is the number of moles of electrons transferred in the half reaction (number), ''F'' is the Faraday constant (C/mol), ''A'' is the electrode area (cm2), ''D'' is the diffusion coefficient (see Fick's law of diffusion) (cm2/s), ''ω'' is the angular rotation rate of the electrode (rad/s), ''v'' is the kinematic viscosity (cm2/s), ''C'' is the analyte An analyte, component (in clinical chemi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Linear Sweep Voltammetry
Linear sweep voltammetry is a voltammetric method where the current at a working electrode is measured while the potential between the working electrode and a reference electrode is swept linearly in time. Oxidation or reduction of species is registered as a peak or trough in the current signal at the potential at which the species begins to be oxidized or reduced. Experimental method The experimental setup for linear sweep voltammetry utilizes a potentiostat and a three-electrode setup to deliver a potential to a solution and monitor its change in current. The three-electrode setup consists of a working electrode, an auxiliary electrode, and a reference electrode. The potentiostat delivers the potentials through the three-electrode setup. A potential, E, is delivered through the working electrode. The slope of the potential vs. time graph is called the scan rate and can range from mV/s to 1,000,000 V/s. The working electrode is one of the electrodes at which the oxidation/ ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pt And BDD Electrodes, Dopamine RDE Scans
PT, Pt, or pt may refer to: Arts and entertainment * ''P.T.'' (video game), acronym for ''Playable Teaser'', a short video game released to promote the cancelled video game ''Silent Hills'' * Porcupine Tree, a British progressive rock group In business Businesses * Capital Cargo International Airlines (IATA airline designator PT) * West Air Sweden (IATA airline designator PT) * Putnam Transit, a bus system that serves Putnam County, New York * Portugal Telecom, the largest telecommunications service provider in Portugal * ''Piteå-Tidningen'', a Swedish local newspaper Business terminology * Part-time job * Perseroan Terbatas, the Indonesian name for a limited liability company Political parties * ''Partido dos Trabalhadores'' (Brazil) (Workers' Party), a Brazilian political party * ''Parti des travailleurs'' (France) (Workers' Party), a defunct French political party * ''Partido dos Trabalhadores'' (Guinea-Bissau) (Workers' Party), a Bissau-Guinean political par ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cyclic Voltammetry
Cyclic voltammetry (CV) is a type of potentiodynamic electrochemical measurement. In a cyclic voltammetry experiment, the working electrode potential is ramped linearly versus time. Unlike in linear sweep voltammetry, after the set potential is reached in a CV experiment, the working electrode's potential is ramped in the opposite direction to return to the initial potential. These cycles of ramps in potential may be repeated as many times as needed. The current at the working electrode is plotted versus the applied voltage (that is, the working electrode's potential) to give the cyclic voltammogram trace. Cyclic voltammetry is generally used to study the electrochemical properties of an analyte in solution or of a molecule that is adsorbed onto the electrode. Experimental method In cyclic voltammetry (CV), the electrode potential ramps linearly versus time in cyclical phases (Figure 2). The rate of voltage change over time during each of these phases is known as the experiment ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Laminar Flow
In fluid dynamics, laminar flow is characterized by fluid particles following smooth paths in layers, with each layer moving smoothly past the adjacent layers with little or no mixing. At low velocities, the fluid tends to flow without lateral mixing, and adjacent layers slide past one another like playing cards. There are no cross-currents perpendicular to the direction of flow, nor eddies or swirls of fluids. In laminar flow, the motion of the particles of the fluid is very orderly with particles close to a solid surface moving in straight lines parallel to that surface. Laminar flow is a flow regime characterized by high momentum diffusion and low momentum convection. When a fluid is flowing through a closed channel such as a pipe or between two flat plates, either of two types of flow may occur depending on the velocity and viscosity of the fluid: laminar flow or turbulent flow. Laminar flow occurs at lower velocities, below a threshold at which the flow becomes turbulent. Th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Centrifugal Force
In Newtonian mechanics, the centrifugal force is an inertial force (also called a "fictitious" or "pseudo" force) that appears to act on all objects when viewed in a rotating frame of reference. It is directed away from an axis which is parallel to the axis of rotation and passing through the coordinate system's origin. If the axis of rotation passes through the coordinate system's origin, the centrifugal force is directed radially outwards from that axis. The magnitude of centrifugal force ''F'' on an object of mass ''m'' at the distance ''r'' from the origin of a frame of reference rotating with angular velocity is: F = m\omega^2 r The concept of centrifugal force can be applied in rotating devices, such as centrifuges, centrifugal pumps, centrifugal governors, and centrifugal clutches, and in centrifugal railways, planetary orbits and banked curves, when they are analyzed in a rotating coordinate system. Confusingly, the term has sometimes also been used for the reactiv ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Boundary Layer
In physics and fluid mechanics, a boundary layer is the thin layer of fluid in the immediate vicinity of a bounding surface formed by the fluid flowing along the surface. The fluid's interaction with the wall induces a no-slip boundary condition (zero velocity at the wall). The flow velocity then monotonically increases above the surface until it returns to the bulk flow velocity. The thin layer consisting of fluid whose velocity has not yet returned to the bulk flow velocity is called the velocity boundary layer. The air next to a human is heated resulting in gravity-induced convective airflow, airflow which results in both a velocity and thermal boundary layer. A breeze disrupts the boundary layer, and hair and clothing protect it, making the human feel cooler or warmer. On an aircraft wing, the velocity boundary layer is the part of the flow close to the wing, where viscous forces distort the surrounding non-viscous flow. In the Earth's atmosphere, the atmospheric boun ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rotation
Rotation, or spin, is the circular movement of an object around a '' central axis''. A two-dimensional rotating object has only one possible central axis and can rotate in either a clockwise or counterclockwise direction. A three-dimensional object has an infinite number of possible central axes and rotational directions. If the rotation axis passes internally through the body's own center of mass, then the body is said to be ''autorotating'' or '' spinning'', and the surface intersection of the axis can be called a ''pole''. A rotation around a completely external axis, e.g. the planet Earth around the Sun, is called ''revolving'' or ''orbiting'', typically when it is produced by gravity, and the ends of the rotation axis can be called the ''orbital poles''. Mathematics Mathematically, a rotation is a rigid body movement which, unlike a translation, keeps a point fixed. This definition applies to rotations within both two and three dimensions (in a plane and in space, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrodynamic Voltammetry
Hydrodynamic voltammetry is a form of voltammetry in which the analyte solution flows relative to a working electrode. In many voltammetry techniques, the solution is intentionally left still to allow diffusion controlled mass transfer. When a solution is made to flow, through stirring or some other physical mechanism, it is very important to the technique to achieve a very controlled flux or mass transfer in order to obtain predictable results. These methods are types of electrochemical studies which use potentiostats to investigate reaction mechanisms related to redox chemistry among other chemical phenomenon.Douglas A. Skoog, F. James Holler, Timothy A. Nieman Principles of Instrumental Analysis. Harcourt Brace College Publishers, 1998 . Structure Most experiments involve a three electrode setup but the setup configuration varies widely. All cell configurations create a laminar flow of solution across the working electrode(s) producing a steady-state current determined by s ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
