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Hittorf
Johann Wilhelm Hittorf (27 March 1824 – 28 November 1914) was a German physicist who was born in Bonn and died in Münster, Germany. Hittorf was the first to compute the electricity-carrying capacity of charged atoms and molecules (ions), an important factor in understanding electrochemical reactions. He formulated ion transport numbers and the first method for their measurements. He observed tubes with energy rays extending from a negative electrode. These rays produced a fluorescence when they hit the glass walls of the tubes. In 1876 the effect was named "cathode rays" by Eugen Goldstein. Hittorf's early investigations were on the allotropes of phosphorus and selenium. Between 1853 and 1859 his most important work was on ion movement caused by electric current. In 1853 Hittorf pointed out that some ions traveled more rapidly than others. This observation led to the concept of transport number, the fraction of the electric current carried by each ionic species. He measured ...
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Allotropes Of Phosphorus
Elemental phosphorus can exist in several allotropes, the most common of which are white and red solids. Solid violet and black allotropes are also known. Gaseous phosphorus exists as diphosphorus and atomic phosphorus. White phosphorus White phosphorus, yellow phosphorus or simply tetraphosphorus () exists as molecules made up of four atoms in a tetrahedral structure. The tetrahedral arrangement results in ring strain and instability. The molecule is described as consisting of six single P–P bonds. Two crystalline forms are known. The α form is defined as the standard state of the element, but is actually metastable under standard conditions. It has a body-centered cubic crystal structure, and transforms reversibly into the β form at 195.2 K. The β form is believed to have a hexagonal crystal structure. White phosphorus is a translucent waxy solid that quickly becomes yellow when exposed to light. For this reason it is also called yellow phosphorus. It glows greenish in t ...
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Ion Transport Number
In chemistry, ion transport number, also called the transference number, is the fraction of the total electric current carried in an electrolyte by a given ionic species : :t_i = \frac Differences in transport number arise from differences in electrical mobility. For example, in an aqueous solution of sodium chloride, less than half of the current is carried by the positively charged sodium ions (cations) and more than half is carried by the negatively charged chloride ions (anions) because the chloride ions are able to move faster, i.e., chloride ions have higher mobility than sodium ions. The sum of the transport numbers for all of the ions in solution always equals unity: :\sum_i t_i = 1 The concept and measurement of transport number were introduced by Johann Wilhelm Hittorf in the year 1853. Liquid junction potential can arise from ions in a solution having different ion transport numbers. At zero concentration, the limiting ion transport numbers may be expressed in terms ...
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Transport Number
In chemistry, ion transport number, also called the transference number, is the fraction of the total electric current carried in an electrolyte by a given ionic species : :t_i = \frac Differences in transport number arise from differences in electrical mobility. For example, in an aqueous solution of sodium chloride, less than half of the current is carried by the positively charged sodium ions (cations) and more than half is carried by the negatively charged chloride ions (anions) because the chloride ions are able to move faster, i.e., chloride ions have higher mobility than sodium ions. The sum of the transport numbers for all of the ions in solution always equals unity: :\sum_i t_i = 1 The concept and measurement of transport number were introduced by Johann Wilhelm Hittorf in the year 1853. Liquid junction potential can arise from ions in a solution having different ion transport numbers. At zero concentration, the limiting ion transport numbers may be expressed in t ...
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Ion Transport Number
In chemistry, ion transport number, also called the transference number, is the fraction of the total electric current carried in an electrolyte by a given ionic species : :t_i = \frac Differences in transport number arise from differences in electrical mobility. For example, in an aqueous solution of sodium chloride, less than half of the current is carried by the positively charged sodium ions (cations) and more than half is carried by the negatively charged chloride ions (anions) because the chloride ions are able to move faster, i.e., chloride ions have higher mobility than sodium ions. The sum of the transport numbers for all of the ions in solution always equals unity: :\sum_i t_i = 1 The concept and measurement of transport number were introduced by Johann Wilhelm Hittorf in the year 1853. Liquid junction potential can arise from ions in a solution having different ion transport numbers. At zero concentration, the limiting ion transport numbers may be expressed in terms ...
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Cathode Ray
Cathode rays or electron beam (e-beam) are streams of electrons observed in discharge tubes. If an evacuated glass tube is equipped with two electrodes and a voltage is applied, glass behind the positive electrode is observed to glow, due to electrons emitted from the cathode (the electrode connected to the negative terminal of the voltage supply). They were first observed in 1859 by German physicist Julius Plücker and Johann Wilhelm Hittorf, and were named in 1876 by Eugen Goldstein ''Kathodenstrahlen'', or cathode rays. In 1897, British physicist J. J. Thomson showed that cathode rays were composed of a previously unknown negatively charged particle, which was later named the ''electron''. Cathode-ray tubes (CRTs) use a focused beam of electrons deflected by electric or magnetic fields to render an image on a screen. Description Cathode rays are so named because they are emitted by the negative electrode, or cathode, in a vacuum tube. To release electrons into the tube, th ...
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Phosphorus
Phosphorus is a chemical element with the symbol P and atomic number 15. Elemental phosphorus exists in two major forms, white phosphorus and red phosphorus, but because it is highly reactive, phosphorus is never found as a free element on Earth. It has a concentration in the Earth's crust of about one gram per kilogram (compare copper at about 0.06 grams). In minerals, phosphorus generally occurs as phosphate. Elemental phosphorus was first isolated as white phosphorus in 1669. White phosphorus emits a faint glow when exposed to oxygen – hence the name, taken from Greek mythology, meaning 'light-bearer' (Latin ), referring to the " Morning Star", the planet Venus. The term '' phosphorescence'', meaning glow after illumination, derives from this property of phosphorus, although the word has since been used for a different physical process that produces a glow. The glow of phosphorus is caused by oxidation of the white (but not red) phosphorus — a process now called chem ...
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Cathode Ray Tube
A cathode-ray tube (CRT) is a vacuum tube containing one or more electron guns, which emit electron beams that are manipulated to display images on a phosphorescent screen. The images may represent electrical waveforms ( oscilloscope), pictures (television set, computer monitor), radar targets, or other phenomena. A CRT on a television set is commonly called a picture tube. CRTs have also been used as memory devices, in which case the screen is not intended to be visible to an observer. The term ''cathode ray'' was used to describe electron beams when they were first discovered, before it was understood that what was emitted from the cathode was a beam of electrons. In CRT television sets and computer monitors, the entire front area of the tube is scanned repeatedly and systematically in a fixed pattern called a raster. In color devices, an image is produced by controlling the intensity of each of three electron beams, one for each additive primary color (red, green, and bl ...
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German Physicist
This is a list of Germans, German physicists. A * Ernst Abbe * Max Abraham * Gerhard Abstreiter * Michael Adelbulner * Martin Aeschlimann * Georg von Arco * Manfred von Ardenne * Peter Armbruster * Leo Arons * Markus Aspelmeyer * Felix Auerbach * Bruno Augenstein B * Ernst Emil Alexander Back * Karl Baedeker (scientist), Karl Baedeker * Erich Bagge * Marc Baldus * Valentine Bargmann * Heinrich Barkhausen * Henry H. Barschall * Heinz Barwich * Ernst G. Bauer * Karl Bechert * Friedrich Beck * Guido Beck * Richard Becker (physicist), Richard Becker * Karl Heinz Beckurts * Georg Bednorz * August Beer * Wilhelm von Beetz * Martin Beneke * Johann Benzenberg * Berend Wilhelm Feddersen * Arnold Berliner * Arthur Berson * Adolf Bestelmeyer * Hans Bethe * Sigfried Bethke * Albert Betz * Hans-Dieter Betz * Paul Alfred Biefeld * Ikaros Bigi * Josef Bille * Heinz Billing * Gerd Binnig * Marcus Birkenkrahe * Paul Richard Heinrich Blasius * Klaus Blaum * Immanuel Bloch * Detlef Blöc ...
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Crookes–Hittorf Tube
A Crookes tube (also Crookes–Hittorf tube) is an early experimental electrical discharge tube, with partial vacuum, invented by English physicist William Crookes and others around 1869-1875, in which cathode rays, streams of electrons, were discovered. Developed from the earlier Geissler tube, the Crookes tube consists of a partially evacuated glass bulb of various shapes, with two metal electrodes, the cathode and the anode, one at either end. When a high voltage is applied between the electrodes, cathode rays (electrons) are projected in straight lines from the cathode. It was used by Crookes, Johann Hittorf, Julius Plücker, Eugen Goldstein, Heinrich Hertz, Philipp Lenard, Kristian Birkeland and others to discover the properties of cathode rays, culminating in J.J. Thomson's 1897 identification of cathode rays as negatively charged particles, which were later named ''electrons''. Crookes tubes are now used only for demonstrating cathode rays. Wilhelm Röntgen discovered ...
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Eugen Goldstein
Eugen Goldstein (; 5 September 1850 – 25 December 1930) was a German physicist. He was an early investigator of discharge tubes, the discoverer of anode rays or canal rays, later identified as positive ions in the gas phase including the hydrogen ion. He was the great uncle of the violinists Mikhail Goldstein and Boris Goldstein. Life Goldstein was born in 1850 at Gleiwitz Upper Silesia, now known as Gliwice, Poland, to a Jewish family. He studied at Breslau and later, under Helmholtz, in Berlin. Goldstein worked at the Berlin Observatory from 1878 to 1890 but spent most of his career at the Potsdam Observatory, where he became head of the astrophysical section in 1927. He died in 1930 and was buried in the Weißensee Cemetery in Berlin. Work In the mid-nineteenth century, Julius Plücker investigated the light emitted in discharge tubes (Crookes tubes) and the influence of magnetic fields on the glow. Later, in 1869, Johann Wilhelm Hittorf studied discharge ...
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Vacuum Tube
A vacuum tube, electron tube, valve (British usage), or tube (North America), is a device that controls electric current flow in a high vacuum between electrodes to which an electric voltage, potential difference has been applied. The type known as a thermionic tube or thermionic valve utilizes thermionic emission of electrons from a hot cathode for fundamental electronic functions such as signal amplifier, amplification and current rectifier, rectification. Non-thermionic types such as a vacuum phototube, however, achieve electron emission through the photoelectric effect, and are used for such purposes as the detection of light intensities. In both types, the electrons are accelerated from the cathode to the anode by the electric field in the tube. The simplest vacuum tube, the diode (i.e. Fleming valve), invented in 1904 by John Ambrose Fleming, contains only a heated electron-emitting cathode and an anode. Electrons can only flow in one direction through the device—fro ...
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Hughes Medal
The Hughes Medal is awarded by the Royal Society of London "in recognition of an original discovery in the physical sciences, particularly electricity and magnetism or their applications". Named after David E. Hughes, the medal is awarded with a gift of £1000. The medal was first awarded in 1902 to J. J. Thomson "for his numerous contributions to electric science, especially in reference to the phenomena of electric discharge in gases", and has since been awarded over one-hundred times. Unlike other Royal Society medals, the Hughes Medal has never been awarded to the same individual more than once. The medal has on occasion been awarded to multiple people at a time; in 1938 it was won by John Cockcroft and Ernest Walton "for their discovery that nuclei could be disintegrated by artificially produced bombarding particles", in 1981 by Peter Higgs and Tom Kibble "for their international contributions about the spontaneous breaking of fundamental symmetries in elementary-particle ...
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