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HgTe
Mercury telluride (HgTe) is a binary chemical compound of mercury and tellurium. It is a semi-metal related to the II-VI group of semiconductor materials. Alternative names are mercuric telluride and mercury(II) telluride. HgTe occurs in nature as the mineral form coloradoite. Physical properties All properties are at standard temperature and pressure unless stated otherwise. The lattice parameter is about 0.646 nm in the cubic crystalline form. The bulk modulus is about 42.1 GPa. The thermal expansion coefficient is about 5.2×10−6/K. Static dielectric constant 20.8, dynamic dielectric constant 15.1. Thermal conductivity is low at 2.7 W·m2/(m·K). HgTe bonds are weak leading to low hardness values. Hardness 2.7×107 kg/m2. Doping N-type doping can be achieved with elements such as boron, aluminium, gallium, or indium. Iodine and iron will also dope n-type. HgTe is naturally p-type due to mercury vacancies. P-type doping is also achieved by introducing zinc, copper, silv ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mercury Cadmium Telluride
Hg1−xCdxTe or mercury cadmium telluride (also cadmium mercury telluride, MCT, MerCad Telluride, MerCadTel, MerCaT or CMT) is a chemical compound of cadmium telluride (CdTe) and mercury telluride (HgTe) with a tunable bandgap spanning the shortwave infrared to the very long wave infrared regions. The amount of cadmium (Cd) in the alloy can be chosen so as to tune the optical absorption of the material to the desired infrared wavelength. CdTe is a semiconductor with a bandgap of approximately 1.5 electronvolts (eV) at room temperature. HgTe is a semimetal, which means that its bandgap energy is zero. Mixing these two substances allows one to obtain any bandgap between 0 and 1.5 eV. Properties Physical Hg1−xCdxTe has a zincblende structure with two interpenetrating face-centered cubic lattices offset by (1/4,1/4,1/4)ao in the primitive cell. The cations Cd and Hg are statistically mixed on the yellow sublattice while the Te anions form the grey sublattice in the image ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Topological Insulator
A topological insulator is a material whose interior behaves as an electrical insulator while its surface behaves as an electrical conductor, meaning that electrons can only move along the surface of the material. A topological insulator is an insulator for the same reason a "trivial" (ordinary) insulator is: there exists an energy gap between the valence and conduction bands of the material. But in a topological insulator, these bands are, in an informal sense, "twisted", relative to a trivial insulator. The topological insulator cannot be continuously transformed into a trivial one without untwisting the bands, which closes the band gap and creates a conducting state. Thus, due to the continuity of the underlying field, the border of a topological insulator with a trivial insulator (including vacuum, which is topologically trivial) is forced to support a conducting state. Since this results from a global property of the topological insulator's band structure, local (symmetry- ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Coloradoite
Coloradoite, also known as mercury telluride (HgTe), is a rare telluride ore associated with metallic deposit (especially gold and silver). Gold usually occurs within tellurides, such as coloradoite, as a high-finess native metal. The quest for mining led to the discovery of telluride ores which were found to be associated with metals. Tellurides are ingrown into ores containing these precious metals and are also responsible for a significant amount of these metals being produced. Coloradoite, a member of the coordination subclass of tellurides, is a covalent compound that is isostructural with sphalerite (ZnS).Povarennykh, A. S (1972). ''Crystal Chemical classification of minerals''. Vol I, pp. 120–121 Its chemical properties are highly instrumental in distinguishing it from other tellurides. It was first discovered in Colorado in 1877. Since then, other deposits have been found. Although it plays an important role in the geology of minerals, it can also be used for other purpo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mercury (element)
Mercury is a chemical element with the symbol Hg and atomic number 80. It is also known as quicksilver and was formerly named hydrargyrum ( ) from the Greek words, ''hydor'' (water) and ''argyros'' (silver). A heavy, silvery d-block A block of the periodic table is a set of elements unified by the atomic orbitals their valence electrons or vacancies lie in. The term appears to have been first used by Charles Janet. Each block is named after its characteristic orbital: s-blo ... element, mercury is the only metallic element that is known to be liquid at standard temperature and pressure; the only other element that is liquid under these conditions is the halogen bromine, though metals such as caesium, gallium, and rubidium melt just above room temperature. Mercury occurs in deposits throughout the world mostly as cinnabar (mercuric sulfide). The red pigment vermilion is obtained by Mill (grinding), grinding natural cinnabar or synthetic mercuric sulfide. Mercury is used in ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tellurium
Tellurium is a chemical element with the symbol Te and atomic number 52. It is a brittle, mildly toxic, rare, silver-white metalloid. Tellurium is chemically related to selenium and sulfur, all three of which are chalcogens. It is occasionally found in native form as elemental crystals. Tellurium is far more common in the Universe as a whole than on Earth. Its extreme rarity in the Earth's crust, comparable to that of platinum, is due partly to its formation of a volatile hydride that caused tellurium to be lost to space as a gas during the hot nebular formation of Earth.Anderson, Don L.; "Chemical Composition of the Mantle" in ''Theory of the Earth'', pp. 147-175 Tellurium-bearing compounds were first discovered in 1782 in a gold mine in Kleinschlatten, Transylvania (now Zlatna, Romania) by Austrian mineralogist Franz-Joseph Müller von Reichenstein, although it was Martin Heinrich Klaproth who named the new element in 1798 after the Latin 'earth'. Gold telluride minerals ar ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Semi-metal
A semimetal is a material with a very small overlap between the bottom of the conduction band and the top of the valence band. According to electronic band theory, solids can be classified as insulators, semiconductors, semimetals, or metals. In insulators and semiconductors the filled valence band is separated from an empty conduction band by a band gap. For insulators, the magnitude of the band gap is larger (e.g., > 4 eV) than that of a semiconductor (e.g., < 4 eV). Because of the slight overlap between the conduction and valence bands, semimetals have no band gap and a negligible at the . A metal, by contrast, has an appreciable density of states at the Fermi level because the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sphalerite
Sphalerite (sometimes spelled sphaelerite) is a sulfide mineral with the chemical formula . It is the most important ore of zinc. Sphalerite is found in a variety of deposit types, but it is primarily in Sedimentary exhalative deposits, sedimentary exhalative, Carbonate-hosted lead-zinc ore deposits, Mississippi-Valley type, and Volcanogenic massive sulfide ore deposit, volcanogenic massive sulfide deposits. It is found in association with galena, chalcopyrite, pyrite (and other sulfide mineral, sulfides), calcite, dolomite (mineral), dolomite, quartz, rhodochrosite, and fluorite. German geologist Ernst Friedrich Glocker discovered sphalerite in 1847, naming it based on the Greek word ''sphaleros'', meaning "deceiving", due to the difficulty of identifying the mineral. In addition to zinc, sphalerite is an ore of cadmium, gallium, germanium, and indium. Miners have been known to refer to sphalerite as ''zinc blende'', ''black-jack'', and ''ruby blende''. Marmatite is an opaque ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Charge Carrier
In physics, a charge carrier is a particle or quasiparticle that is free to move, carrying an electric charge, especially the particles that carry electric charges in electrical conductors. Examples are electrons, ions and holes. The term is used most commonly in solid state physics. In a conducting medium, an electric field can exert force on these free particles, causing a net motion of the particles through the medium; this is what constitutes an electric current. In conducting media, particles serve to carry charge: *In many metals, the charge carriers are electrons. One or two of the valence electrons from each atom are able to move about freely within the crystal structure of the metal. The free electrons are referred to as conduction electrons, and the cloud of free electrons is called a Fermi gas. Many metals have electron and hole bands. In some, the majority carriers are holes. *In electrolytes, such as salt water, the charge carriers are ions, which are atoms or molecul ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electric Current
An electric current is a stream of charged particles, such as electrons or ions, moving through an electrical conductor or space. It is measured as the net rate of flow of electric charge through a surface or into a control volume. The moving particles are called charge carriers, which may be one of several types of particles, depending on the conductor. In electric circuits the charge carriers are often electrons moving through a wire. In semiconductors they can be electrons or holes. In an electrolyte the charge carriers are ions, while in plasma, an ionized gas, they are ions and electrons. The SI unit of electric current is the ampere, or ''amp'', which is the flow of electric charge across a surface at the rate of one coulomb per second. The ampere (symbol: A) is an SI base unit. Electric current is measured using a device called an ammeter. Electric currents create magnetic fields, which are used in motors, generators, inductors, and transformers. In ordinary con ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Surface State
Surface states are electronic states found at the surface of materials. They are formed due to the sharp transition from solid material that ends with a surface and are found only at the atom layers closest to the surface. The termination of a material with a surface leads to a change of the electronic band structure from the bulk material to the vacuum. In the weakened potential at the surface, new electronic states can be formed, so called surface states. Origin at condensed matter interfaces As stated by Bloch's theorem, eigenstates of the single-electron Schrödinger equation with a perfectly periodic potential, a crystal, are Bloch waves : \begin \Psi_ &=\mathrm^u_(\boldsymbol). \end Here u_(\boldsymbol) is a function with the same periodicity as the crystal, ''n'' is the band index and k is the wave number. The allowed wave numbers for a given potential are found by applying the usual Born–von Karman cyclic boundary conditions. The termination of a crystal, i.e. the f ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cadmium Telluride
Cadmium telluride (CdTe) is a stable crystalline compound formed from cadmium and tellurium. It is mainly used as the semiconducting material in cadmium telluride photovoltaics and an infrared optical window. It is usually sandwiched with cadmium sulfide to form a p–n junction solar PV cell. Applications CdTe is used to make thin film solar cells, accounting for about 8% of all solar cells installed in 2011. They are among the lowest-cost types of solar cell, although a comparison of total installed cost depends on installation size and many other factors, and has changed rapidly from year to year. The CdTe solar cell market is dominated by First Solar. In 2011, around 2 GWp of CdTe solar cells were produced; For more details and discussion see cadmium telluride photovoltaics. CdTe can be alloyed with mercury to make a versatile infrared detector material (HgCdTe). CdTe alloyed with a small amount of zinc makes an excellent solid-state X-ray and gamma ray detector ( Cd ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Enthalpy Of Formation
Enthalpy , a property of a thermodynamic system, is the sum of the system's internal energy and the product of its pressure and volume. It is a state function used in many measurements in chemical, biological, and physical systems at a constant pressure, which is conveniently provided by the large ambient atmosphere. The pressure–volume term expresses the work required to establish the system's physical dimensions, i.e. to make room for it by displacing its surroundings. The pressure-volume term is very small for solids and liquids at common conditions, and fairly small for gases. Therefore, enthalpy is a stand-in for energy in chemical systems; bond, lattice, solvation and other "energies" in chemistry are actually enthalpy differences. As a state function, enthalpy depends only on the final configuration of internal energy, pressure, and volume, not on the path taken to achieve it. In the International System of Units (SI), the unit of measurement for enthalpy is the joule. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
