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Expansion Ratio
The expansion ratio of a liquefied and cryogenic substance is the volume of a given amount of that substance in liquid form compared to the volume of the same amount of substance in gaseous form, at room temperature and normal atmospheric pressure. If a sufficient amount of liquid is vaporized within a closed container, it produces pressures that can rupture the pressure vessel. Hence the use of pressure relief valves and vent valves are important. The expansion ratio of liquefied and cryogenic from the boiling point to ambient is: *nitrogen – 1 to 696 * liquid helium – 1 to 745 *argon – 1 to 842 *liquid hydrogen – 1 to 850 * liquid oxygen – 1 to 860 *neon Neon is a chemical element; it has symbol Ne and atomic number 10. It is the second noble gas in the periodic table. Neon is a colorless, odorless, inert monatomic gas under standard conditions, with approximately two-thirds the density of ... – Neon has the highest expansion ratio with 1 to 1445. See a ...
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Liquification
In materials science, liquefaction is a process that generates a liquid from a solid or a gas or that generates a non-liquid phase which behaves in accordance with fluid dynamics. It occurs both naturally and artificially. As an example of the latter, a "major commercial application of liquefaction is the liquefaction of air to allow separation of the constituents, such as oxygen, nitrogen, and the noble gases." Another is the conversion of solid coal into a liquid form usable as a substitute for liquid fuels. In geology, soil liquefaction refers to the process by which water-saturated, unconsolidated sediments are transformed into a substance that acts like a liquid, often in an earthquake. Soil liquefaction was blamed for building collapses in the city of Palu, Indonesia in October 2018. In a related phenomenon, liquefaction of bulk materials in cargo ships may cause a dangerous shift in the load. In physics and chemistry, the phase transitions from solid and melting.htm ...
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Liquid Nitrogen
Liquid nitrogen (LN2) is nitrogen in a liquid state at cryogenics, low temperature. Liquid nitrogen has a boiling point of about . It is produced industrially by fractional distillation of liquid air. It is a colorless, mobile liquid whose viscosity is about one-tenth that of acetone (i.e. roughly one-thirtieth that of water at room temperature). Liquid nitrogen is widely used as a coolant. Physical properties The diatomic character of the N2 molecule is retained after liquefaction. The weak van der Waals interaction between the N2 molecules results in little interatomic attraction. This is the cause of nitrogen's unusually low boiling point. The temperature of liquid nitrogen can readily be reduced to its freezing point by placing it in a vacuum chamber pumped by a vacuum pump. Liquid nitrogen's efficiency as a coolant is limited by the fact that it boils immediately on contact with a warmer object, enveloping the object in an insulating layer of nitrogen gas bubbles. Thi ...
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Boiling Liquid Expanding Vapor Explosion
A boiling liquid expanding vapor explosion (BLEVE, ) is an explosion caused by the rupture of a Pressure vessel, vessel containing a Compressed fluid, pressurized liquid that has attained a temperature sufficiently higher than its boiling point at atmospheric pressure. Because the boiling point of a liquid rises with pressure, the contents of the pressurized vessel can remain a liquid as long as the vessel is intact. If the vessel's integrity is compromised, the loss of pressure drops the boiling point, which can cause a portion of the liquid to Boiling, boil and form a cloud of rapidly expanding vapor. BLEVEs are manifestations of explosive boiling. If the vapor is Combustibility and flammability, flammable (as is the case with compounds such as hydrocarbons and alcohol (chemistry), alcohols) and comes in contact with an ignition source, further damage can be caused by the ensuing explosion and fireball. However, BLEVEs do not necessarily involve fire. Name On 24 April 1957 ...
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Liquid-to-gas Ratio
An important parameter in wet scrubbing systems is the rate of liquid flow. It is common in wet scrubber terminology to express the liquid flow as a function of the gas flow rate that is being treated. This is commonly called the liquid-to-gas ratio (L/G ratio) and uses the units of gallons per 1,000 actual cubic feet or litres per cubic metre (L/m3). Expressing the amount of liquid used as a ratio enables systems of different sizes to be readily compared. For particulate removal, the liquid-to-gas ratio is a function of the mechanical design of the system; while for gas absorption this ratio gives an indication of the difficulty of removing a pollutant. Most wet scrubbers used for particulate control operate with liquid-to-gas ratios in the range of 4 to 20 gallons per 1,000 actual cubic foot (0.5 to 3 litres per actual cubic metre). Depending on scrubber design, a minimum volume of liquid is required to "wet" the scrubber internals and create sufficient collection targets. After ...
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Neon
Neon is a chemical element; it has symbol Ne and atomic number 10. It is the second noble gas in the periodic table. Neon is a colorless, odorless, inert monatomic gas under standard conditions, with approximately two-thirds the density of air. Neon was discovered in 1898 alongside krypton and xenon, identified as one of the three remaining rare inert elements in dry air after the removal of nitrogen, oxygen, argon, and carbon dioxide. Its discovery was marked by the distinctive bright red emission spectrum it exhibited, leading to its immediate recognition as a new element. The name ''neon'' originates from the Greek word , a neuter singular form of (), meaning 'new'. Neon is a chemically inert gas; although neon compounds do exist, they are primarily ionic molecules or fragile molecules held together by van der Waals forces. The synthesis of most neon in the cosmos resulted from the nuclear fusion within stars of oxygen and helium through the alpha-capture proce ...
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Liquid Oxygen
Liquid oxygen, sometimes abbreviated as LOX or LOXygen, is a clear cyan liquid form of dioxygen . It was used as the oxidizer in the first liquid-fueled rocket invented in 1926 by Robert H. Goddard, an application which is ongoing. Physical properties Liquid oxygen has a clear cyan color and is strongly paramagnetic: it can be suspended between the poles of a powerful horseshoe magnet. Liquid oxygen has a density of , slightly denser than liquid water, and is cryogenic with a freezing point of and a boiling point of at . Liquid oxygen has an expansion ratio of 1:861 and because of this, it is used in some commercial and military aircraft as a transportable source of breathing oxygen. Because of its cryogenic nature, liquid oxygen can cause the materials it touches to become extremely brittle. Liquid oxygen is also a very powerful oxidizing agent: organic materials will burn rapidly and energetically in liquid oxygen. Further, if soaked in liquid oxygen, some materials su ...
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Liquid Hydrogen
Liquid hydrogen () is the liquid state of the element hydrogen. Hydrogen is found naturally in the molecule, molecular H2 form. To exist as a liquid, H2 must be cooled below its critical point (thermodynamics), critical point of 33 Kelvins, K. However, for it to be in a fully liquid state at atmospheric pressure, H2 needs to be cooled to .IPTS-1968
iupac.org, accessed 2020-01-01
A common method of obtaining liquid hydrogen involves a compressor resembling a jet engine in both appearance and principle. Liquid hydrogen is typically used as a concentrated form of hydrogen storage. Storing it as liquid takes less space than storing it as a gas at normal temperature and pressure. However, the liquid density is very low compared to other common fuels. Once liquefied, it can be maintained as a liquid for some time in the ...
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Argon
Argon is a chemical element; it has symbol Ar and atomic number 18. It is in group 18 of the periodic table and is a noble gas. Argon is the third most abundant gas in Earth's atmosphere, at 0.934% (9340 ppmv). It is more than twice as abundant as water vapor (which averages about 4000 ppmv, but varies greatly), 23 times as abundant as carbon dioxide (400 ppmv), and more than 500 times as abundant as neon (18 ppmv). Argon is the most abundant noble gas in Earth's crust, comprising 0.00015% of the crust. Nearly all argon in Earth's atmosphere is radiogenic argon-40, derived from the decay of potassium-40 in Earth's crust. In the universe, argon-36 is by far the most common argon isotope, as it is the most easily produced by stellar nucleosynthesis in supernovas. The name "argon" is derived from the Greek word , neuter singular form of meaning 'lazy' or 'inactive', as a reference to the fact that the element undergoes almost no chemical reactions. The complete oc ...
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Liquid Helium
Liquid helium is a physical state of helium at very low temperatures at standard atmospheric pressures. Liquid helium may show superfluidity. At standard pressure, the chemical element helium exists in a liquid form only at the extremely low temperature of . Its boiling point and critical point depend on the isotope of helium present: the common isotope helium-4 or the rare isotope helium-3. These are the only two stable isotopes of helium. See the table below for the values of these physical quantities. The density of liquid helium-4 at its boiling point and a pressure of one atmosphere (101.3 kilopascals) is about , or about one-eighth the density of liquid water. Liquefaction Helium was first liquefied on July 10, 1908, by the Dutch physicist Heike Kamerlingh Onnes at the University of Leiden in the Netherlands. At that time, helium-3 was unknown because the mass spectrometer had not yet been invented. In more recent decades, liquid helium has been used as a cryogenic refriger ...
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Boiling Point
The boiling point of a substance is the temperature at which the vapor pressure of a liquid equals the pressure surrounding the liquid and the liquid changes into a vapor. The boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum, i.e., under a lower pressure, has a lower boiling point than when that liquid is at atmospheric pressure. Because of this, water boils at 100°C (or with scientific precision: ) under standard pressure at sea level, but at at altitude. For a given pressure, different liquids will boiling, boil at different temperatures. The normal boiling point (also called the atmospheric boiling point or the atmospheric pressure boiling point) of a liquid is the special case in which the vapor pressure of the liquid equals the defined atmospheric pressure at sea level, one Atmosphere (unit), atmosphere. At that temperature, the vapor pressure of the liquid becomes sufficient to overcome atmospheric pre ...
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Cryogenic
In physics, cryogenics is the production and behaviour of materials at very low temperatures. The 13th International Institute of Refrigeration's (IIR) International Congress of Refrigeration (held in Washington, DC in 1971) endorsed a universal definition of "cryogenics" and "cryogenic" by accepting a threshold of to distinguish these terms from conventional refrigeration. This is a logical dividing line, since the normal boiling points of the so-called permanent gases (such as helium, hydrogen, neon, nitrogen, oxygen, and normal air) lie below 120 K, while the Freon refrigerants, hydrocarbons, and other common refrigerants have boiling points above 120 K. Discovery of superconducting materials with critical temperatures significantly above the boiling point of nitrogen has provided new interest in reliable, low-cost methods of producing high-temperature cryogenic refrigeration. The term "high temperature cryogenic" describes temperatures ranging from above the ...
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Liquification
In materials science, liquefaction is a process that generates a liquid from a solid or a gas or that generates a non-liquid phase which behaves in accordance with fluid dynamics. It occurs both naturally and artificially. As an example of the latter, a "major commercial application of liquefaction is the liquefaction of air to allow separation of the constituents, such as oxygen, nitrogen, and the noble gases." Another is the conversion of solid coal into a liquid form usable as a substitute for liquid fuels. In geology, soil liquefaction refers to the process by which water-saturated, unconsolidated sediments are transformed into a substance that acts like a liquid, often in an earthquake. Soil liquefaction was blamed for building collapses in the city of Palu, Indonesia in October 2018. In a related phenomenon, liquefaction of bulk materials in cargo ships may cause a dangerous shift in the load. In physics and chemistry, the phase transitions from solid and melting.htm ...
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