The expansion ratio of a
liquefied and
cryogenic substance is the
volume
Volume is a measure of occupied three-dimensional space. It is often quantified numerically using SI derived units (such as the cubic metre and litre) or by various imperial or US customary units (such as the gallon, quart, cubic inch). Th ...
of a given amount of that substance in
liquid form compared to the volume of the same amount of substance in
gaseous
Gas is one of the four fundamental states of matter (the others being solid, liquid, and plasma).
A pure gas may be made up of individual atoms (e.g. a noble gas like neon), elemental molecules made from one type of atom (e.g. oxygen), ...
form, at room temperature and normal
atmospheric pressure
Atmospheric pressure, also known as barometric pressure (after the barometer), is the pressure within the atmosphere of Earth. The standard atmosphere (symbol: atm) is a unit of pressure defined as , which is equivalent to 1013.25 millibars, ...
.
If a sufficient amount of liquid is
vaporized
Vaporization (or vaporisation) of an element or compound is a phase transition from the liquid phase to vapor. There are two types of vaporization: evaporation and boiling. Evaporation is a surface phenomenon, whereas boiling is a bulk phenom ...
within a closed container, it produces pressures that can rupture the
pressure vessel. Hence the use of
pressure relief valve
A relief valve or pressure relief valve (PRV) is a type of safety valve used to control or limit the pressure in a system; pressure might otherwise build up and create a process upset, instrument or equipment failure, or fire. The pressure is re ...
s and vent valves are important.
The expansion ratio of
liquefied and
cryogenic from the
boiling point to ambient is:
*
nitrogen
Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at se ...
– 1 to 696
*
liquid helium
Liquid helium is a physical state of helium at very low temperatures at standard atmospheric pressures. Liquid helium may show superfluidity.
At standard pressure, the chemical element helium exists in a liquid form only at the extremely low temp ...
– 1 to 745
*
argon
Argon is a chemical element with the symbol Ar and atomic number 18. It is in group 18 of the periodic table and is a noble gas. Argon is the third-most abundant gas in Earth's atmosphere, at 0.934% (9340 ppmv). It is more than twice as ...
– 1 to 842
*
liquid hydrogen
Liquid hydrogen (LH2 or LH2) is the liquid state of the element hydrogen. Hydrogen is found naturally in the molecular H2 form.
To exist as a liquid, H2 must be cooled below its critical point of 33 K. However, for it to be in a fully l ...
– 1 to 850
*
liquid oxygen
Liquid oxygen—abbreviated LOx, LOX or Lox in the aerospace, submarine and gas industries—is the liquid form of molecular oxygen. It was used as the oxidizer in the first liquid-fueled rocket invented in 1926 by Robert H. Goddard, an app ...
– 1 to 860
*
neon – Neon has the highest expansion ratio with 1 to 1445.
See also
*
Liquid-to-gas ratio An important parameter in wet scrubbing systems is the rate of liquid flow. It is common in wet scrubber terminology to express the liquid flow as a function of the gas flow rate that is being treated. This is commonly called the liquid-to-gas rati ...
*
Boiling liquid expanding vapor explosion
A boiling liquid expanding vapor explosion (BLEVE, ) is an explosion caused by the rupture of a vessel containing a pressurized liquid that has reached temperature above its boiling point. Because the boiling point of a liquid rises wi ...
*
Thermal expansion
Thermal expansion is the tendency of matter to change its shape, area, volume, and density in response to a change in temperature, usually not including phase transitions.
Temperature is a monotonic function of the average molecular kinetic ...
References
External links
cryogenic-gas-hazards
{{physical-chemistry-stub
Cryogenics