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Erbium Compounds
Erbium compounds are compounds containing the element erbium (Er). These compounds are usually dominated by erbium in the +3 oxidation state, although the +2, +1 and 0Yttrium and all lanthanides except Ce and Pm have been observed in the oxidation state 0 in bis(1,3,5-tri-t-butylbenzene) complexes, see and oxidation states have also been reported. Oxides Erbium(III) oxide (also known as erbia) is the only known oxide of erbium, first isolated by Carl Gustaf Mosander in 1843, and first obtained in pure form in 1905 by Georges Urbain and Charles James. It has a cubic structure resembling the bixbyite motif. The Er3+ centers are octahedral. The formation of erbium oxide is accomplished by burning erbium metal. Erbium oxide is insoluble in water and soluble in mineral acids. Halides Erbium(III) fluoride is a pinkish powder that can be produced by reacting erbium(III) nitrate and ammonium fluoride. It can be used to make infrared light-transmitting materials and up-conve ...
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Erbium
Erbium is a chemical element with the symbol Er and atomic number 68. A silvery-white solid metal when artificially isolated, natural erbium is always found in chemical combination with other elements. It is a lanthanide, a rare-earth element The rare-earth elements (REE), also called the rare-earth metals or (in context) rare-earth oxides or sometimes the lanthanides (yttrium and scandium are usually included as rare earths), are a set of 17 nearly-indistinguishable lustrous silve ..., originally found in the gadolinite mine in Ytterby, Sweden, which is the source of the element's name. Erbium's principal uses involve its pink-colored Er3+ ions, which have optical fluorescent properties particularly useful in certain laser applications. Erbium-doped glasses or crystals can be used as optical amplification media, where Er3+ ions are optically pumped at around 980 or and then radiate light at in stimulated emission. This process results in an unusually mechanically simple la ...
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Monoclinic
In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic system. They form a parallelogram prism. Hence two pairs of vectors are perpendicular (meet at right angles), while the third pair makes an angle other than 90°. Bravais lattices Two monoclinic Bravais lattices exist: the primitive monoclinic and the base-centered monoclinic. For the base-centered monoclinic lattice, the primitive cell has the shape of an oblique rhombic prism;See , row mC, column Primitive, where the cell parameters are given as a1 = a2, α = β it can be constructed because the two-dimensional centered rectangular base layer can also be described with primitive rhombic axes. Note that the length a of the primitive cell below equals \frac \sqrt of the conventional cell above. Crystal classes The table below org ...
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Erbium Hexaboride
Erbium hexaboride (ErB6) is a rare-earth hexaboride compound containing the element erbium, which has a calcium hexaboride crystal structure. It is one of the fundamental compounds formed in reactions between erbium and boron. The compound is isostructural with all other reported rare-earth hexaboride compounds including lanthanum hexaboride, samarium hexaboride, and cerium hexaboride. Due to the isostructural nature of the rare-earth hexaborides and the strong interaction of boron octahedra within the crystal, these compounds show a high degree of lattice matching which suggests the possibility of doping by substituting one rare earth metal within the crystal with another. Until recently, it had been hypothesized that erbium hexaboride was unstable due to the small size of the Er3+ cation within the crystal structure when compared to the ionic radii of other rare-earth elements that form known rare-earth hexaboride compounds. It has now been demonstrated, however, that new nan ...
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Rocket Engine Nozzle
A rocket engine nozzle is a propelling nozzle (usually of the de Laval type) used in a rocket engine to expand and accelerate combustion products to high supersonic velocities. Simply: propellants pressurized by either pumps or high pressure ullage gas to anywhere between two to several hundred atmospheres are injected into a combustion chamber to burn, and the combustion chamber leads into a nozzle which converts the energy contained in high pressure, high temperature combustion products into kinetic energy by accelerating the gas to high velocity and near-ambient pressure. History Simple bell-shaped nozzles were developed in the 1500s. The de Laval nozzle was originally developed in the 19th century by Gustaf de Laval for use in steam turbines. It was first used in an early rocket engine developed by Robert Goddard, one of the fathers of modern rocketry. It has since been used in almost all rocket engines, including Walter Thiel's implementation, which made possible German ...
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Gas Turbines
A gas turbine, also called a combustion turbine, is a type of continuous flow internal combustion engine. The main parts common to all gas turbine engines form the power-producing part (known as the gas generator or core) and are, in the direction of flow: * a rotating gas compressor * a combustor * a compressor-driving turbine. Additional components have to be added to the gas generator to suit its application. Common to all is an air inlet but with different configurations to suit the requirements of marine use, land use or flight at speeds varying from stationary to supersonic. A propelling nozzle is added to produce thrust for flight. An extra turbine is added to drive a propeller (turboprop) or ducted fan (turbofan) to reduce fuel consumption (by increasing propulsive efficiency) at subsonic flight speeds. An extra turbine is also required to drive a helicopter rotor or land-vehicle transmission (turboshaft), marine propeller or electrical generator (power turbine). Greater ...
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Turbine Blade
A turbine blade is a radial aerofoil mounted in the rim of a turbine disc and which produces a tangential force which rotates a turbine rotor. Each turbine disc has many blades. As such they are used in gas turbine engines and steam turbines. The blades are responsible for extracting energy from the high temperature, high pressure gas produced by the combustor. The turbine blades are often the limiting component of gas turbines. To survive in this difficult environment, turbine blades often use exotic materials like superalloys and many different methods of cooling that can be categorized as internal and external cooling, and thermal barrier coatings. Blade fatigue is a maj ...
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Semiconductor
A semiconductor is a material which has an electrical resistivity and conductivity, electrical conductivity value falling between that of a electrical conductor, conductor, such as copper, and an insulator (electricity), insulator, such as glass. Its electrical resistivity and conductivity, resistivity falls as its temperature rises; metals behave in the opposite way. Its conducting properties may be altered in useful ways by introducing impurities ("doping (semiconductor), doping") into the crystal structure. When two differently doped regions exist in the same crystal, a semiconductor junction is created. The behavior of charge carriers, which include electrons, ions, and electron holes, at these junctions is the basis of diodes, transistors, and most modern electronics. Some examples of semiconductors are silicon, germanium, gallium arsenide, and elements near the so-called "metalloid staircase" on the periodic table. After silicon, gallium arsenide is the second-most common s ...
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Taylor & Francis
Taylor & Francis Group is an international company originating in England that publishes books and academic journals. Its parts include Taylor & Francis, Routledge, F1000 (publisher), F1000 Research or Dovepress. It is a division of Informa, Informa plc, a United Kingdom–based publisher and conference company. Overview The company was founded in 1852 when William Francis (chemist), William Francis joined Richard Taylor (editor), Richard Taylor in his publishing business. Taylor had founded his company in 1798. Their subjects covered agriculture, chemistry, education, engineering, geography, law, mathematics, medicine, and social sciences. Francis's son, Richard Taunton Francis (1883–1930), was sole partner in the firm from 1917 to 1930. In 1965, Taylor & Francis launched Wykeham Publications and began book publishing. T&F acquired Hemisphere Publishing in 1988, and the company was renamed Taylor & Francis Group to reflect the growing number of Imprint (trade name), imp ...
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Boride
A boride is a compound between boron and a less electronegative element, for example silicon boride (SiB3 and SiB6). The borides are a very large group of compounds that are generally high melting and are covalent more than ionic in nature. Some borides exhibit very useful physical properties. The term boride is also loosely applied to compounds such as B12As2 (N.B. Arsenic has an electronegativity higher than boron) that is often referred to as icosahedral boride. Ranges of compounds The borides can be classified loosely as boron rich or metal rich, for example the compound YB66 at one extreme through to Nd2Fe14B at the other. The generally accepted definition is that if the ratio of boron atoms to metal atoms is 4:1 or more, the compound is boron rich; if it is less, then it is metal rich. Boron rich borides (B:M 4:1 or more) The main group metals, lanthanides and actinides form a wide variety of boron-rich borides, with metal:boron ratios up to YB66. The properties of this g ...
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Erbium Tetraboride
Erbium tetraboride is a boride of the lanthanide metal erbium. It is hard and has a high melting point. Industrial applications of erbium boride include use in semiconductors, the blades of gas turbines, and the nozzles A nozzle is a device designed to control the direction or characteristics of a fluid flow (specially to increase velocity) as it exits (or enters) an enclosed chamber or pipe. A nozzle is often a pipe or tube of varying cross sectional area, a ... of rocket engines. References Borides Erbium compounds {{inorganic-compound-stub ...
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Iodine
Iodine is a chemical element with the symbol I and atomic number 53. The heaviest of the stable halogens, it exists as a semi-lustrous, non-metallic solid at standard conditions that melts to form a deep violet liquid at , and boils to a violet gas at . The element was discovered by the French chemist Bernard Courtois in 1811 and was named two years later by Joseph Louis Gay-Lussac, after the Ancient Greek 'violet-coloured'. Iodine occurs in many oxidation states, including iodide (I−), iodate (), and the various periodate anions. It is the least abundant of the stable halogens, being the sixty-first most abundant element. As the heaviest essential mineral nutrient, iodine is required for the synthesis of thyroid hormones. Iodine deficiency affects about two billion people and is the leading preventable cause of intellectual disabilities. The dominant producers of iodine today are Chile and Japan. Due to its high atomic number and ease of attachment to organic compound ...
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Erbium(III) Iodide
Erbium(III) iodide is an iodide of lanthanide metal erbium Erbium is a chemical element with the symbol Er and atomic number 68. A silvery-white solid metal when artificially isolated, natural erbium is always found in chemical combination with other elements. It is a lanthanide, a rare-earth element, or .... The compound is insoluble in water and is white to slightly pink in appearance. The chemical can be produced by the reaction of elemental iodine and finely divided erbium by the following equation: 2Er + 3I_2\longrightarrow 2ErI_3 References Erbium compounds Iodides Lanthanide halides {{inorganic-compound-stub ...
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