Delafossite
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Delafossite
Delafossite is a copper iron oxide mineral with formula CuFeO2 or Cu1+Fe3+O2. It is a member of the delafossite mineral group, which has the general formula ABO2, a group characterized by sheets of linearly coordinated A cations stacked between edge-shared octahedral layers (BO6). Delafossite, along with other minerals of the ABO2 group, is known for its wide range of electrical properties, its conductivity varying from insulating to metallic. Delafossite is usually a secondary mineral that crystallizes in association with oxidized copper and rarely occurs as a primary mineral. Composition The chemical formula for delafossite is CuFeO2, which was first determined through chemical analysis of the pure mineral by G. S. Bohart. The ratio he determined was very close to Cu:Fe:O=1:1:2, with slightly more iron than copper. Rogers. attributed this fact to a small amount of hematite in the sample. In order to determine the composition of delafossite Rogers used the Ziervogel process. The ...
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Oxide Mineral
The oxide mineral class includes those minerals in which the oxide anion (O2−) is bonded to one or more metal alloys. The hydroxide-bearing minerals are typically included in the oxide class. The minerals with complex anion groups such as the silicates, sulfates, carbonates and phosphates are classed separately. Simple oxides: *XO **Periclase group ***Periclase ***Manganosite **Zincite group ***Zincite *** Bromellite ***Tenorite ***Litharge * **Cuprite **Ice * **Hematite group ***Corundum ***Hematite ***Ilmenite * **Rutile group ***Rutile ***Pyrolusite ***Cassiterite **Baddeleyite **Uraninite **Thorianite * **Spinel group ***Spinel ***Gahnite ***Magnetite ***Franklinite ***Chromite **Chrysoberyl **Columbite *Hydroxide subgroup: **Brucite **Manganite ** Romanèchite **Goethite group: ***Diaspore ***Goethite Nickel–Strunz Classification -04- Oxides IMA-CNMNC proposes a new hierarchical scheme (Mills et al., 2009). This list uses it to modify ...
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Oxide Minerals
The oxide mineral class includes those minerals in which the oxide anion (O2−) is bonded to one or more metal alloys. The hydroxide-bearing minerals are typically included in the oxide class. The minerals with complex anion groups such as the silicates, sulfates, carbonates and phosphates are classed separately. Simple oxides: *XO **Periclase group ***Periclase ***Manganosite **Zincite group ***Zincite *** Bromellite ***Tenorite ***Litharge * **Cuprite **Ice * **Hematite group ***Corundum ***Hematite ***Ilmenite * **Rutile group ***Rutile ***Pyrolusite *** Cassiterite ** Baddeleyite **Uraninite **Thorianite * **Spinel group ***Spinel ***Gahnite ***Magnetite ***Franklinite *** Chromite **Chrysoberyl **Columbite *Hydroxide subgroup: **Brucite **Manganite ** Romanèchite **Goethite group: ***Diaspore ***Goethite Nickel–Strunz Classification -04- Oxides IMA-CNMNC proposes a new hierarchical scheme (Mills et al., 2009). This list uses it to mod ...
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Cuprite
Cuprite is an oxide mineral composed of copper(I) oxide Cu2O, and is a minor ore of copper. Its dark crystals with red internal reflections are in the isometric system hexoctahedral class, appearing as cubic, octahedral, or dodecahedral forms, or in combinations. Penetration twins frequently occur. In spite of its nice color it is rarely used for jewelry because of its low Mohs hardness of 3.5 to 4. It has a relatively high specific gravity of 6.1, imperfect cleavage and is brittle to conchoidal fracture. The luster is sub-metallic to brilliant adamantine. The "chalcotrichite" (from variety typically shows greatly elongated (parallel to 01 capillary or needle like crystals forms. It is a secondary mineral which forms in the oxidized zone of copper sulfide deposits. It frequently occurs in association with native copper, azurite, chrysocolla, malachite, tenorite and a variety of iron oxide minerals.Hurlbut, Cornelius S.; Klein, Cornelis, 1985, ''Manual of Mineralogy,'' 20th ed. ...
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Siberia
Siberia ( ; rus, Сибирь, r=Sibir', p=sʲɪˈbʲirʲ, a=Ru-Сибирь.ogg) is an extensive geographical region, constituting all of North Asia, from the Ural Mountains in the west to the Pacific Ocean in the east. It has been a part of Russia since the latter half of the 16th century, after the Russians conquered lands east of the Ural Mountains. Siberia is vast and sparsely populated, covering an area of over , but home to merely one-fifth of Russia's population. Novosibirsk, Krasnoyarsk and Omsk are the largest cities in the region. Because Siberia is a geographic and historic region and not a political entity, there is no single precise definition of its territorial borders. Traditionally, Siberia extends eastwards from the Ural Mountains to the Pacific Ocean, and includes most of the drainage basin of the Arctic Ocean. The river Yenisey divides Siberia into two parts, Western and Eastern. Siberia stretches southwards from the Arctic Ocean to the hills of north-ce ...
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Charles Friedel
Charles Friedel (; 12 March 1832 – 20 April 1899) was a French chemist and Mineralogy, mineralogist. Life A native of Strasbourg, France, he was a student of Louis Pasteur at the University of Paris, Sorbonne. In 1876, he became a professor of chemistry and mineralogy at the Sorbonne. Friedel developed the Friedel–Crafts reaction, Friedel-Crafts alkylation and acylation reactions with James Crafts in 1877, and attempted to make synthetic diamonds. His son Georges Friedel (1865–1933) also became a renowned mineralogist. Lineage * Friedel's wife's father was the engineer, Charles Combes.Charles Combes
, quercy.net, accessed April 2010 The Friedel family is a rich lineage of French scientists: ** Georges Friedel (1865–1933), French crystallographer and mineralogist; son of Charles ** Edmond Friedel (1895–1972), French Polytechnician and min ...
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X-ray Diffraction
X-ray crystallography is the experimental science determining the atomic and molecular structure of a crystal, in which the crystalline structure causes a beam of incident X-rays to diffract into many specific directions. By measuring the angles and intensities of these diffracted beams, a crystallographer can produce a three-dimensional picture of the density of electrons within the crystal. From this electron density, the mean positions of the atoms in the crystal can be determined, as well as their chemical bonds, their crystallographic disorder, and various other information. Since many materials can form crystals—such as salts, metals, minerals, semiconductors, as well as various inorganic, organic, and biological molecules—X-ray crystallography has been fundamental in the development of many scientific fields. In its first decades of use, this method determined the size of atoms, the lengths and types of chemical bonds, and the atomic-scale differences among various mat ...
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Lithium Batteries
Lithium battery may refer to: * Lithium metal battery, a non-rechargeable battery with lithium as an anode ** Rechargeable lithium metal battery, a rechargeable counterpart to the lithium metal battery * Lithium-ion battery, a rechargeable battery in which lithium ions move from the negative electrode to the positive electrode during discharge and back when charging ** Thin-film lithium-ion battery, a solid-state lithium-ion battery constructed as a thin-film ** Aqueous lithium-ion battery ** Lithium-ion flow battery ** Lithium ion manganese oxide battery * Lithium polymer battery * Lithium–sulfur battery * Lithium-titanate battery * Lithium–air battery * Lithium iron phosphate battery * Nickel–lithium battery * Lithium–silicon battery * Lithium vanadium phosphate battery * Lithium hybrid organic battery See also *List of battery types *Lithium batteries in China *High capacity oceanographic lithium battery pack *Glass battery, which may use a lithium metal electrode *Sub ...
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Photoelectrochemical
Photoelectrochemical processes are processes in photoelectrochemistry; they usually involve transforming light into other forms of energy. These processes apply to photochemistry, optically pumped lasers, sensitized solar cells, luminescence, and photochromism. Electron excitation Electron excitation is the movement of an electron to a higher energy state. This can either be done by photoexcitation (PE), where the original electron absorbs the photon and gains all the photon's energy or by electrical excitation (EE), where the original electron absorbs the energy of another, energetic electron. Within a semiconductor crystal lattice, thermal excitation is a process where lattice vibrations provide enough energy to move electrons to a higher energy band. When an excited electron falls back to a lower energy state again, it is called electron relaxation. This can be done by radiation of a photon or giving the energy to a third spectator particle as well. In physics there is a sp ...
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Photocathode
A photocathode is a surface engineered to convert light (photons) into electrons using the photoelectric effect. Photocathodes are important in accelerator physics where they are utilised in a photoinjector to generate high brightness electron beams. Electron beams generated with photocathodes are commonly used for free electron lasers and for ultrafast electron diffraction. Photocathodes are also commonly used as the negatively charged electrode in a light detection device such as a photomultiplier or phototube. Important Properties Quantum Efficiency (QE) Quantum efficiency is a unitless number that measures the sensitivity of the photocathode to light. It is the ratio of the number of electrons emitted to the number of incident photons.Rao, T., & Dowell, D. H. (2013). ''An engineering guide to photoinjectors''. CreateSpace Independent Publishing. This property depends on the wavelength of light being used to illuminate the photocathode. For many applications, QE is th ...
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Aqueous
An aqueous solution is a solution in which the solvent is water. It is mostly shown in chemical equations by appending (aq) to the relevant chemical formula. For example, a solution of table salt, or sodium chloride (NaCl), in water would be represented as . The word ''aqueous'' (which comes from ''aqua'') means pertaining to, related to, similar to, or dissolved in, water. As water is an excellent solvent and is also naturally abundant, it is a ubiquitous solvent in chemistry. Since water is frequently used as the solvent in experiments, the word solution refers to an aqueous solution, unless the solvent is specified. A ''non-aqueous solution'' is a solution in which the solvent is a liquid, but is not water. (See also Solvent and Inorganic nonaqueous solvent.) Characteristics Substances that are ''hydrophobic'' ('water-fearing') do not dissolve well in water, whereas those that are ''hydrophilic'' ('water-friendly') do. An example of a hydrophilic substance is sodium chlori ...
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Zinc Oxide
Zinc oxide is an inorganic compound with the formula . It is a white powder that is insoluble in water. ZnO is used as an additive in numerous materials and products including cosmetics, food supplements, rubbers, plastics, ceramics, glass, cement, lubricants, paints, ointments, adhesives, sealants, pigments, foods, batteries, ferrites, fire retardants, and first-aid tapes. Although it occurs naturally as the mineral zincite, most zinc oxide is produced synthetically. ZnO is a wide-band gap semiconductor of the II-VI semiconductor group. The native doping of the semiconductor due to oxygen vacancies or zinc interstitials is n-type. Other favorable properties include good transparency, high electron mobility, wide band gap, and strong room-temperature luminescence. Those properties make ZnO valuable for a variety of emerging applications: transparent electrodes in liquid crystal displays, energy-saving or heat-protecting windows, and electronics as thin-film transistors and lig ...
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Indium Tin Oxide
Indium tin oxide (ITO) is a ternary composition of indium, tin and oxygen in varying proportions. Depending on the oxygen content, it can be described as either a ceramic or an alloy. Indium tin oxide is typically encountered as an oxygen-saturated composition with a formulation of 74% In, 18% Sn, and 8% O by weight. Oxygen-saturated compositions are so typical that unsaturated compositions are termed ''oxygen-deficient ITO''. It is transparent and colorless in thin layers, while in bulk form it is yellowish to gray. In the infrared region of the spectrum it acts as a metal-like mirror. Indium tin oxide is one of the most widely used transparent conducting oxides because of its electrical conductivity and optical transparency, the ease with which it can be deposited as a thin film, and its chemical resistance to moisture. As with all transparent conducting films, a compromise must be made between conductivity and transparency, since increasing the thickness and increasing the concent ...
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