Naphthalenes
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Naphthalenes
Naphthalene is an organic compound with formula . It is the simplest polycyclic aromatic hydrocarbon, and is a white crystalline solid with a characteristic odor that is detectable at concentrations as low as 0.08  ppm by mass. As an aromatic hydrocarbon, naphthalene's structure consists of a fused pair of benzene rings. It is the main ingredient of traditional mothballs. History In the early 1820s, two separate reports described a white solid with a pungent odor derived from the distillation of coal tar. In 1821, John Kidd cited these two disclosures and then described many of this substance's properties and the means of its production. He proposed the name ''naphthaline'', as it had been derived from a kind of naphtha (a broad term encompassing any volatile, flammable liquid hydrocarbon mixture, including coal tar). Naphthalene's chemical formula was determined by Michael Faraday in 1826. The structure of two fused benzene rings was proposed by Emil Erlenmeyer in 1866, a ...
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Royal Society Of Chemistry
The Royal Society of Chemistry (RSC) is a learned society and professional association in the United Kingdom with the goal of "advancing the chemistry, chemical sciences". It was formed in 1980 from the amalgamation of the Chemical Society, the Royal Institute of Chemistry, the Faraday Society, and the Society for Analytical Chemistry with a new Royal Charter and the dual role of learned society and professional body. At its inception, the Society had a combined membership of 49,000 in the world. The headquarters of the Society are at Burlington House, Piccadilly, London. It also has offices in Thomas Graham House in Cambridge (named after Thomas Graham (chemist), Thomas Graham, the first president of the Chemical Society) where ''RSC Publishing'' is based. The Society has offices in the United States, on the campuses of The University of Pennsylvania and Drexel University, at the University City Science Center in Philadelphia, Pennsylvania, in both Beijing and Shanghai, People' ...
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Carbon
Carbon () is a chemical element; it has chemical symbol, symbol C and atomic number 6. It is nonmetallic and tetravalence, tetravalent—meaning that its atoms are able to form up to four covalent bonds due to its valence shell exhibiting 4 electrons. It belongs to group 14 of the periodic table. Carbon makes up about 0.025 percent of Earth's crust. Three Isotopes of carbon, isotopes occur naturally, carbon-12, C and carbon-13, C being stable, while carbon-14, C is a radionuclide, decaying with a half-life of 5,700 years. Carbon is one of the timeline of chemical element discoveries#Pre-modern and early modern discoveries, few elements known since antiquity. Carbon is the 15th abundance of elements in Earth's crust, most abundant element in the Earth's crust, and the abundance of the chemical elements, fourth most abundant element in the universe by mass after hydrogen, helium, and oxygen. Carbon's abundance, its unique diversity of organic compounds, and its unusual abi ...
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Emil Erlenmeyer
Richard August Carl Emil Erlenmeyer (28 June 1825 – 22 January 1909), known simply as Emil Erlenmeyer, was a German chemist known for contributing to the early development of the theory of chemical structure and formulating the Erlenmeyer rule. He also designed the Erlenmeyer flask, a specialized apparatus ubiquitous in chemistry laboratories, which is named after him. Biography Early life and education Erlenmeyer was born in Wehen, Duchy of Nassau (today Taunusstein, Hesse, near Wiesbaden), in 1825, the son of a Protestant minister. He enrolled in the University of Giessen to study medicine, but after attending lectures of Justus von Liebig changed to chemistry. In the summer of 1846 he went to Heidelberg for one year, and studied physics, botany and mineralogy, returning to Giessen in 1847. After serving as assistant to H. Will and then to Carl Remigius Fresenius, Erlenmeyer decided to devote himself to pharmaceutical chemistry. For this purpose he studied in Nassau, ...
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Michael Faraday
Michael Faraday (; 22 September 1791 – 25 August 1867) was an English chemist and physicist who contributed to the study of electrochemistry and electromagnetism. His main discoveries include the principles underlying electromagnetic induction, diamagnetism, and electrolysis. Although Faraday received little formal education, as a self-made man, he was one of the most influential scientists in history. It was by his research on the magnetic field around a Electrical conductor, conductor carrying a direct current that Faraday established the concept of the electromagnetic field in physics. Faraday also established that magnetism could Faraday effect, affect rays of light and that there was an underlying relationship between the two phenomena. the 1911 ''Encyclopædia Britannica''. He similarly discovered the principles of electromagnetic induction, diamagnetism, and the Faraday's laws of electrolysis, laws of electrolysis. His inventions of electric motor, electromagnetic rotar ...
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Naphtha
Naphtha (, recorded as less common or nonstandard in all dictionaries: ) is a flammable liquid hydrocarbon mixture. Generally, it is a fraction of crude oil, but it can also be produced from natural-gas condensates, petroleum distillates, and the fractional distillation of coal tar and peat. In some industries and regions, the name ''naphtha'' refers to crude oil or refined petroleum products such as kerosene or diesel fuel. Naphtha is also known as Shellite in Australia. Etymology The word ''naphtha'' comes from Latin through Ancient Greek (), derived from Middle Persian ''naft'' ("wet", "naphtha"), the latter meaning of which was an assimilation from the Akkadian 𒉌𒆳𒊏 (see Semitic relatives such as Arabic petroleum" Syriac ''naftā'', and Hebrew , meaning petroleum). Antiquity The book of II Maccabees (2nd cent. BC) tells how a "thick water" was put on a sacrifice at the time of Nehemiah and when the sun shone it caught fire. It adds that "those aro ...
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John Kidd (chemist)
John Kidd (10 September 1775 – 7 September 1851) was an English physician, chemist and geologist who took a leading role in Oxford's "scientific awakening" in the early years of the nineteenth century. Biography Kidd was born in Westminster, the son of a naval officer, and was educated at Christ Church, Oxford. He became reader in chemistry at Oxford in 1801, and in 1803 was elected the first Aldrichian Professor of Chemistry. He then voluntarily gave courses of lectures on mineralogy and geology. These were delivered in the dark chambers under the Ashmolean Museum, where William Conybeare, William Buckland, Charles Daubeny and others gained their first lessons in geology. Kidd was a popular and instructive lecturer, and through his efforts the geological chair, first held by Buckland, was established. Kidd's two geological publications—his ''Outlines of Mineralogy'' (1809) and ''Geological Essay on the Imperfect Evidence in Support of a Theory of the Earth'' (1815)� ...
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Coal Tar
Coal tar is a thick dark liquid which is a by-product of the production of coke and coal gas from coal. It is a type of creosote. It has both medical and industrial uses. Medicinally it is a topical medication applied to skin to treat psoriasis and seborrheic dermatitis ( dandruff). It may be used in combination with ultraviolet light therapy. Industrially it is a railroad tie preservative and used in the surfacing of roads. Coal tar was listed as a known human carcinogen in the first Report on Carcinogens from the U.S. Federal Government, issued in 1980. Coal tar was discovered circa 1665 and used for medical purposes as early as the 1800s. Circa 1850, the discovery that it could be used as the main raw material for the synthesis of dyes engendered an entire industry. It is on the World Health Organization's List of Essential Medicines. Coal tar is available as a generic medication and over the counter. Side effects include skin irritation, sun sensitivity, aller ...
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Distillation
Distillation, also classical distillation, is the process of separating the component substances of a liquid mixture of two or more chemically discrete substances; the separation process is realized by way of the selective boiling of the mixture and the condensation of the vapors in a still. Distillation can operate over a wide range of pressures from 0.14 bar (e.g., ethylbenzene/ styrene) to nearly 21 bar (e.g., propylene/propane) and is capable of separating feeds with high volumetric flowrates and various components that cover a range of relative volatilities from only 1.17 ( o-xylene/ m-xylene) to 81.2 (water/ ethylene glycol). Distillation provides a convenient and time-tested solution to separate a diversity of chemicals in a continuous manner with high purity. However, distillation has an enormous environmental footprint, resulting in the consumption of approximately 25% of all industrial energy use. The key issue is that distillation operates based on phase changes, ...
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Mothball
Mothballs are small balls of chemical pesticide and deodorant, sometimes used when storing clothing and other materials susceptible to damage from silverfish, Mold (fungus), mold or moth larvae (especially clothes moths like ''Tineola bisselliella''). Composition Older mothballs consisted primarily of naphthalene, but due to naphthalene's flammability, many modern mothball formulations instead use 1,4-dichlorobenzene. The latter formulation may be somewhat less flammable, although both chemicals have the same NFPA 704 rating for flammability. The latter chemical is also variously labeled as 1,4-Dichlorobenzene, para-dichlorobenzene, p-dichlorobenzene, P-DCB, pDCB, or PDB (Palm OS), PDB, making it harder to identify unless all these names and initialisms are known to a potential purchaser. Both of these formulations have the strong, pungent, sickly-sweet odor often associated with mothballs. Both naphthalene and 1,4-dichlorobenzene undergo Sublimation (phase transition), subli ...
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Benzene
Benzene is an Organic compound, organic chemical compound with the Chemical formula#Molecular formula, molecular formula C6H6. The benzene molecule is composed of six carbon atoms joined in a planar hexagonal Ring (chemistry), ring with one hydrogen atom attached to each. Because it contains only carbon and hydrogen atoms, benzene is classed as a hydrocarbon. Benzene is a natural constituent of petroleum and is one of the elementary petrochemicals. Due to the cyclic continuous pi bonds between the carbon atoms, benzene is classed as an aromatic hydrocarbon. Benzene is a colorless and highly Combustibility and flammability, flammable liquid with a sweet smell, and is partially responsible for the aroma of gasoline. It is used primarily as a Precursor (chemistry), precursor to the manufacture of chemicals with more complex structures, such as ethylbenzene and cumene, of which billions of kilograms are produced annually. Although benzene is a major Chemical industry, industrial che ...
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Aromaticity
In organic chemistry, aromaticity is a chemical property describing the way in which a conjugated ring of unsaturated bonds, lone pairs, or empty orbitals exhibits a stabilization stronger than would be expected from conjugation alone. The earliest use of the term was in an article by August Wilhelm Hofmann in 1855. There is no general relationship between aromaticity as a chemical property and the olfactory properties of such compounds. Aromaticity can also be considered a manifestation of cyclic delocalization and of resonance. This is usually considered to be because electrons are free to cycle around circular arrangements of atoms that are alternately single- and double- bonded to one another. This commonly seen model of aromatic rings, namely the idea that benzene was formed from a six-membered carbon ring with alternating single and double bonds (cyclohexatriene), was developed by Kekulé (see History section below). Each bond may be seen as a hybrid of a single bo ...
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Parts-per Notation
In science and engineering, the parts-per notation is a set of pseudo-units to describe the small values of miscellaneous dimensionless quantities, e.g. mole fraction or mass fraction. Since these fractions are quantity-per-quantity measures, they are pure numbers with no associated units of measurement. Commonly used are * parts-per-million - ppm, * parts-per-billion - ppb, * parts-per-trillion - ppt, * parts-per-quadrillion - ppq, This notation is not part of the International System of Units - SI system and its meaning is ambiguous. Applications Parts-per notation is often used describing dilute solutions in chemistry, for instance, the relative abundance of dissolved minerals or pollutants in water. The quantity "1 ppm" can be used for a mass fraction if a water-borne pollutant is present at one-millionth of a gram per gram of sample solution. When working with aqueous solutions, it is common to assume that the density of water is 1.00 g/mL. Th ...
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