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Compatibility (geochemistry)
Compatibility is a term used by geochemists to describe how elements partition themselves in the solid and melt within Earth's mantle. In geochemistry, compatibility is a measure of how readily a particular trace element substitutes for a major element within a mineral. Compatibility of an ion is controlled by two things: its valence and its ionic radius. Both must approximate those of the major element for the trace element to be compatible in the mineral. For instance, olivine (an abundant mineral in the upper mantle) has the chemical formula . Nickel, with very similar chemical behaviour to iron and magnesium, substitutes readily for them and hence is very compatible in the mantle. Compatibility controls the partitioning of different elements during melting. The compatibility of an element in a rock is a weighted average of its compatibility in each of the minerals present. By contrast, an incompatible element is one that is least stable within its crystal structure. I ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Earth's Mantle
Earth's mantle is a layer of silicate mineral, silicate rock between the Earth's crust, crust and the Earth's outer core, outer core. It has a mass of and makes up 67% of the mass of Earth. It has a thickness of making up about 46% of Earth's radius and 84% of Earth's volume. It is predominantly solid but, on geologic time scales, it behaves as a viscosity, viscous fluid, sometimes described as having the consistency of caramel. Partial melting of the mantle at mid-ocean ridges produces oceanic crust, and partial melting of the mantle at subduction zones produces continental crust. Structure Rheology Earth's upper mantle is divided into two major rheology, rheological layers: the rigid lithosphere comprising the uppermost mantle (the lithospheric mantle), and the more ductile asthenosphere, separated by the Lithosphere-Asthenosphere boundary, lithosphere-asthenosphere boundary. Lithosphere underlying ocean crust has a thickness of around , whereas lithosphere underlying cont ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Magma
Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma (sometimes colloquially but incorrectly referred to as ''lava'') is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natural satellites. Besides molten rock, magma may also contain suspended crystals and volcanic gas, gas bubbles. Magma is produced by melting of the mantle (geology), mantle or the Crust (geology), crust in various tectonics, tectonic settings, which on Earth include subduction zones, continental rift (geology), rift zones, mid-ocean ridges and Hotspot (geology), hotspots. Mantle and crustal melts migrate upwards through the crust where they are thought to be stored in magma chambers or trans-crustal crystal mush, crystal-rich mush zones. During magma's storage in the crust, its composition may be modified by Fractional crystallization (geology), fractional crystallization, contaminati ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Incompatible Element
In petrology and geochemistry, an incompatible element is one that is unsuitable in size and/or charge to the cation sites of the minerals in which it is included. It is defined by a partition coefficient between rock-forming minerals and melt being much smaller than 1. During the fractional crystallization of magma and magma generation by the partial melting of the Earth's mantle and crust, elements that have difficulty in entering cation sites of the minerals are concentrated in the melt phase of the magma (liquid phase). Two groups of incompatible elements that have difficulty entering the solid phase are known by acronyms. One group includes elements having large ionic radius, such as potassium, rubidium, caesium, strontium, and barium (called LILE, or large-ion lithophile elements), and the other group includes elements of large ionic valences (or high electrical charges), such as zirconium, niobium, hafnium, rare-earth elements (REE), thorium, uranium and ta ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Distribution Constant
The distribution constant (or partition ratio) (KD) is the equilibrium constant for the distribution of an analyte in two immiscible solvents.i is the concentration of A remaining after extracting Vaq millilitre The litre ( Commonwealth spelling) or liter ( American spelling) (SI symbols L and l, other symbol used: ℓ) is a metric unit of volume. It is equal to 1 cubic decimetre (dm3), 1000 cubic centimetres (cm3) or 0.001 cubic metres (m3). A cu ...s of solution with the original concentration of sub>0 with ''i'' portions of the organic solvent, each with a volume of Vorg). References {{chromatography Chromatography ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Equilibrium Constant
The equilibrium constant of a chemical reaction is the value of its reaction quotient at chemical equilibrium, a state approached by a dynamic chemical system after sufficient time has elapsed at which its composition has no measurable tendency towards further change. For a given set of reaction conditions, the equilibrium constant is independent of the initial analytical concentrations of the reactant and product species in the mixture. Thus, given the initial composition of a system, known equilibrium constant values can be used to determine the Chemical equilibrium#Composition of a mixture, composition of the system at equilibrium. However, reaction parameters like temperature, solvent, and ionic strength may all influence the value of the equilibrium constant. A knowledge of equilibrium constants is essential for the understanding of many chemical systems, as well as the biochemical processes such as oxygen transport by hemoglobin in blood and acid–base homeostasis in the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fractionation
Fractionation is a separation process in which a certain quantity of a mixture (of gasses, solids, liquids, enzymes, or isotopes, or a suspension) is divided during a phase transition, into a number of smaller quantities (fractions) in which the composition varies according to a gradient. Fractions are collected based on differences in a specific property of the individual components. A common trait in fractionations is the need to find an optimum between the amount of fractions collected and the desired purity in each fraction. Fractionation makes it possible to isolate more than two components in a mixture in a single run. This property sets it apart from other separation techniques. Fractionation is widely employed in many branches of science and technology. Mixtures of liquids and gasses are separated by fractional distillation by difference in boiling point. Fractionation of components also takes place in column chromatography by a difference in affinity between statio ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Elemental Abundances
An elemental is a mythic supernatural being that is described in occult and alchemical works from around the time of the European Renaissance, and particularly elaborated in the 16th century works of Paracelsus. According to Paracelsus and his subsequent followers, there are four categories of elementals, which are gnomes, undines, sylphs, and salamanders. These correspond to the four Empedoclean elements of antiquity: earth, water, air, and fire, respectively. Terms employed for beings associated with alchemical elements vary by source and gloss. History The Paracelsian concept of elementals draws from several much older traditions in mythology and religion. Common threads can be found in folklore, animism, and anthropomorphism. Examples of creatures such as the Pygmy were taken from Greek mythology. The elements of earth, water, air, and fire, were classed as the fundamental building blocks of nature. This system prevailed in the Classical world and was highly influent ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Partition Coefficient
In the physical sciences, a partition coefficient (''P'') or distribution coefficient (''D'') is the ratio of concentrations of a chemical compound, compound in a mixture of two immiscible solvents at partition equilibrium, equilibrium. This ratio is therefore a comparison of the solubilities of the solute in these two liquids. The partition coefficient generally refers to the concentration ratio of ionization, un-ionized species of compound, whereas the distribution coefficient refers to the concentration ratio of all species of the compound (ionized plus un-ionized). In the chemistry, chemical and pharmaceutical sciences, both phases usually are solvents. Most commonly, one of the solvents is water, while the second is hydrophobic, such as 1-octanol. Hence the partition coefficient measures how hydrophilic ("water-loving") or hydrophobic ("water-fearing") a chemical substance is. Partition coefficients are useful in estimating the distribution (pharmacology), distribution of dru ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Titanium
Titanium is a chemical element; it has symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in sea water, aqua regia, and chlorine. Titanium was discovered in Cornwall, Great Britain, by William Gregor in 1791 and was named by Martin Heinrich Klaproth after the Titans of Greek mythology. The element occurs within a number of minerals, principally rutile and ilmenite, which are widely distributed in the Earth's crust and lithosphere; it is found in almost all living things, as well as bodies of water, rocks, and soils. The metal is extracted from its principal mineral ores by the Kroll and Hunter processes. The most common compound, titanium dioxide (TiO2), is a popular photocatalyst and is used in the manufacture of white pigments. Other compounds include titanium tetrachloride (TiCl4), a component of smoke screens and cata ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lanthanum
Lanthanum is a chemical element; it has symbol La and atomic number 57. It is a soft, ductile, silvery-white metal that tarnishes slowly when exposed to air. It is the eponym of the lanthanide series, a group of 15 similar elements between lanthanum and lutetium in the periodic table, of which lanthanum is the first and the prototype. Lanthanum is traditionally counted among the rare earth elements. Like most other rare earth elements, its usual oxidation state is +3, although some compounds are known with an oxidation state of +2. Lanthanum has no biological role in humans but is used by some bacteria. It is not particularly toxic to humans but does show some antimicrobial activity. Lanthanum usually occurs together with cerium and the other rare earth elements. Lanthanum was first found by the Swedish chemist Carl Gustaf Mosander in 1839 as an impurity in cerium nitrate – hence the name ''lanthanum'', from the ancient Greek (), meaning 'to lie hidden'. Although ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Uranium
Uranium is a chemical element; it has chemical symbol, symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium radioactive decay, radioactively decays, usually by emitting an alpha particle. The half-life of this decay varies between 159,200 and 4.5 billion years for different isotopes of uranium, isotopes, making them useful for dating the age of the Earth. The most common isotopes in natural uranium are uranium-238 (which has 146 neutrons and accounts for over 99% of uranium on Earth) and uranium-235 (which has 143 neutrons). Uranium has the highest atomic weight of the primordial nuclide, primordially occurring elements. Its density is about 70% higher than that of lead and slightly lower than that of gold or tungsten. It occurs naturally in low concentrations of a few Parts-per notation#Parts-per expressions, parts per million in soil, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
