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Bond Hardening
Bond hardening is a process of creating a new chemical bond by strong laser fields—an effect opposite to bond softening. However, it is not opposite in the sense that the bond becomes stronger, but in the sense that the molecule enters a state that is diametrically opposite to the bond-softened state. Such states require laser pulses of high intensity, in the range of 1013–1015 W/cm2, and they disappear once the pulse is gone. Theory Bond hardening and bond softening share the same theoretical basis, which is described under the latter entry. Briefly, the ground and the first excited energy curves of the H2+ ion are dressed in photons. The laser field perturbs the curves and turns their crossings into anticrossings. Bond softening occurs on the lower branches of the anticrossings and bond hardening happens if the molecule is excited to the upper branches – see Fig. 1. To trap the molecule in the bond-hardened state, the anticrossing gap cannot be too small or too large. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Bond
A chemical bond is a lasting attraction between atoms or ions that enables the formation of molecules and crystals. The bond may result from the electrostatic force between oppositely charged ions as in ionic bonds, or through the sharing of electrons as in covalent bonds. The strength of chemical bonds varies considerably; there are "strong bonds" or "primary bonds" such as covalent, ionic and metallic bonds, and "weak bonds" or "secondary bonds" such as dipole–dipole interactions, the London dispersion force and hydrogen bonding. Strong chemical bonding arises from the sharing or transfer of electrons between the participating atoms. Since opposite electric charges attract, the negatively charged electrons surrounding the nucleus and the positively charged protons within a nucleus attract each other. An electron positioned between two nuclei will be attracted to both of them, and the nuclei will be attracted toward electrons in this position. This attraction constitu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dynamics Of Bond Hardening
Dynamics (from Greek δυναμικός ''dynamikos'' "powerful", from δύναμις ''dynamis'' "power") or dynamic may refer to: Physics and engineering * Dynamics (mechanics) ** Aerodynamics, the study of the motion of air ** Analytical dynamics, the motion of bodies as induced by external forces ** Brownian dynamics, the occurrence of Langevin dynamics in the motion of particles in solution ** File dynamics, stochastic motion of particles in a channel ** Flight dynamics, the science of aircraft and spacecraft design ** Fluid dynamics or ''hydrodynamics'', the study of fluid flow *** Computational fluid dynamics, a way of studying fluid dynamics using numerical methods ** Fractional dynamics, dynamics with integrations and differentiations of fractional orders ** Molecular dynamics, the study of motion on the molecular level ** Langevin dynamics, a mathematical model for stochastic dynamics ** Orbital dynamics, the study of the motion of rockets and spacecraft ** Quantum chro ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Molecular Physics
Molecular physics is the study of the physical properties of molecules and molecular dynamics. The field overlaps significantly with physical chemistry, chemical physics, and quantum chemistry. It is often considered as a sub-field of atomic, molecular, and optical physics. Research groups studying molecular physics are typically designated as one of these other fields. Molecular physics addresses phenomena due to both molecular structure and individual atomic processes within molecules. Like atomic physics, it relies on a combination of classical and quantum mechanics to describe interactions between electromagnetic radiation and matter. Experiments in the field often rely heavily on techniques borrowed from atomic physics, such as spectroscopy and scattering. Molecular Structure In a molecule, both the electrons and nuclei experience similar-scale forces from the Coulomb interaction. However, the nuclei remain at nearly fixed locations in the molecule while the electrons ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Conical Intersection
In quantum chemistry, a conical intersection of two or more potential energy surfaces is the set of molecular geometry points where the potential energy surfaces are degenerate (intersect) and the non-adiabatic couplings between these states are non-vanishing. In the vicinity of conical intersections, the Born–Oppenheimer approximation breaks down and the coupling between electronic and nuclear motion becomes important, allowing non-adiabatic processes to take place. The location and characterization of conical intersections are therefore essential to the understanding of a wide range of important phenomena governed by non-adiabatic events, such as photoisomerization, photosynthesis, vision and the photostability of DNA. The conical intersection involving the ground electronic state potential energy surface of the C6H3F3+ molecular ion is discussed in connection with the Jahn–Teller effect in Section 13.4.2 on pages 380-388 of the textbook by Bunker and Jensen. Conical inters ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Raman Effect
Raman scattering or the Raman effect () is the inelastic scattering of photons by matter, meaning that there is both an exchange of energy and a change in the light's direction. Typically this effect involves vibrational energy being gained by a molecule as incident photons from a visible laser are shifted to lower energy. This is called normal Stokes Raman scattering. The effect is exploited by chemists and physicists to gain information about materials for a variety of purposes by performing various forms of Raman spectroscopy. Many other variants of Raman spectroscopy allow rotational energy to be examined (if gas samples are used) and electronic energy levels may be examined if an X-ray source is used in addition to other possibilities. More complex techniques involving pulsed lasers, multiple laser beams and so on are known. Light has a certain probability of being scattered by a material. When photons are scattered, most of them are elastically scattered (Rayleigh scatt ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Willis E
Willis may refer to: Places United States * Willis, Florida, an unincorporated community * Willis, Indiana, an unincorporated community * Willis, Kansas, a city * Willis, Michigan, an unincorporated community * Willis, Nebraska, an unincorporated community * Willis, Oklahoma, an unincorporated community * Willis, Texas, a city * Willis, Floyd County, Virginia, an unincorporated community * Willis, Russell County, Virginia, an unincorporated community * Willis River, a tributary of the James River in Virginia Elsewhere * Willis, Grenada, a town * Willis Island, Coral Sea Islands Territory, Australia * Willis Islands, South Georgia Islands Arts and entertainment Works * '' Giselle'' or ''The Willis'', a ballet (in the ballet, the Willis are a group of supernatural women) * ''Le Villi'' (''The Willis'' or ''The Fairies''), an opera-ballet composed by Giacomo Puccini * ''Willis'' (album), by The Pietasters Fictional characters * Willis Jackson (character), in the 1970s- ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Quasiparticles
In physics, quasiparticles and collective excitations are closely related emergent phenomena arising when a microscopically complicated system such as a solid behaves as if it contained different weakly interacting particles in vacuum. For example, as an electron travels through a semiconductor, its motion is disturbed in a complex way by its interactions with other electrons and with atomic nuclei. The electron behaves as though it has a different effective mass travelling unperturbed in vacuum. Such an electron is called an ''electron quasiparticle''. In another example, the aggregate motion of electrons in the valence band of a semiconductor or a hole band in a metal behave as though the material instead contained positively charged quasiparticles called ''electron holes''. Other quasiparticles or collective excitations include the ''phonon'', a quasiparticle derived from the vibrations of atoms in a solid, and the ''plasmons'', a particle derived from plasma oscillation. Th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Photoelectrochemical Process
Photoelectrochemical processes are processes in photoelectrochemistry; they usually involve transforming light into other forms of energy. These processes apply to photochemistry, optically pumped lasers, sensitized solar cells, luminescence, and photochromism. Electron excitation Electron excitation is the movement of an electron to a higher energy state. This can either be done by photoexcitation (PE), where the original electron absorbs the photon and gains all the photon's energy or by electrical excitation (EE), where the original electron absorbs the energy of another, energetic electron. Within a semiconductor crystal lattice, thermal excitation is a process where lattice vibrations provide enough energy to move electrons to a higher energy band. When an excited electron falls back to a lower energy state again, it is called electron relaxation. This can be done by radiation of a photon or giving the energy to a third spectator particle as well. In physics there is a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sapphire Laser
Sapphire is a precious gemstone, a variety of the mineral corundum, consisting of aluminium oxide () with trace amounts of elements such as iron, titanium, chromium, vanadium, or magnesium. The name sapphire is derived via the Latin "sapphirus" from the Greek "sappheiros", which referred to lapis lazuli. It is typically blue, but natural "fancy" sapphires also occur in yellow, purple, orange, and green colors; "parti sapphires" show two or more colors. Red corundum stones also occur, but are called rubies rather than sapphires. Pink-colored corundum may be classified either as ruby or sapphire depending on locale. Commonly, natural sapphires are cut and polished into gemstones and worn in jewelry. They also may be created synthetically in laboratories for industrial or decorative purposes in large crystal boules. Because of the remarkable hardness of sapphires 9 on the Mohs scale (the third hardest mineral, after diamond at 10 and moissanite at 9.5) sapphires are also u ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bond Softening
Bond softening is an effect of reducing the strength of a chemical bond by strong laser fields. To make this effect significant, the strength of the electric field in the laser light has to be comparable with the electric field the bonding electron "feels" from the nuclei of the molecule. Such fields are typically in the range of 1–10 V/Å, which corresponds to laser intensities 1013–1015 W/cm2. Nowadays, these intensities are routinely achievable from table-top Ti:Sapphire lasers. Theory Theoretical description of bond softening can be traced back to early work on dissociation of diatomic molecules in intense laser fields. While the quantitative description of this process requires quantum mechanics, it can be understood qualitatively using quite simple models. Low-intensity description Consider the simplest diatomic molecule, the H2+ ion. The ground state of this molecule is bonding and the first excited state is antibonding. This means that when we plot the potential ene ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chirped Pulse Amplifier
Chirped pulse amplification (CPA) is a technique for amplifying an ultrashort laser pulse up to the petawatt level, with the laser pulse being stretched out temporally and spectrally, then amplified, and then compressed again. The stretching and compression uses devices that ensure that the different color components of the pulse travel different distances. CPA for lasers was introduced by Donna Strickland and Gérard Mourou at the University of Rochester in the mid-1980s, work for which they received the Nobel Prize in Physics in 2018. CPA is the current state-of-the-art technique used by most of the highest-power lasers in the world. Background Before the introduction of CPA in the mid-1980s, the peak power of laser pulses was limited because a laser pulse at intensities of gigawatts per square centimeter causes serious damage to the gain medium through nonlinear processes such as self-focusing. For example, some of the most powerful compressed CPA laser beams, even in an un ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
