Beudantite
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Beudantite
Beudandite is a secondary mineral occurring in the oxidized zones of polymetallic deposits. It is a lead, iron, arsenate, sulfate with endmember formula: PbFe3(OH)6SO4AsO4. Beudantite is in a subgroup of the alunite group. It is the arsenate analogue of the phosphate corkite. Beudantite also forms a solid-solution with segnitite and plumbojarosite. It crystallizes in the trigonal crystal system and shows a variety of crystal habits including tabular, acute rhombohedral, pseudo-cubic and pseudo-cuboctahedral. It occurs in association with carminite, scorodite, mimetite, dussertite, arseniosiderite, pharmacosiderite, olivenite, bayldonite, duftite, anglesite, cerussite and azurite. Discovery Beudantite was first described in 1826 for an occurrence in the Louise Mine, Wied Iron Spar District, Westerwald, Rhineland-Palatinate, Germany. It was named by Armand Lévy after his fellow Frenchman and mineralogist François Sulpice Beudant (1787–1850). See also *List of miner ...
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Arsenate Minerals
Arsenate minerals usually refer to the naturally occurring orthoarsenates, possessing the (AsO4)3− anion group and, more rarely, other arsenates with anions like AsO3(OH)2− (also written HAsO42−) (example: pharmacolite Ca(AsO3OH).2H2O) or (very rarely) sO2(OH)2sup>− (example: andyrobertsite). Arsenite minerals are much less common. Both the Dana and the Strunz mineral classifications place the arsenates in with the phosphate minerals. Example arsenate minerals include: * Annabergite Ni3(AsO4)2·8H2O *Austinite CaZn(AsO4)(OH) *Clinoclase Cu3(AsO4)(OH)3 *Conichalcite CaCu(AsO4)(OH) * Cornubite Cu5(AsO4)2(OH)4 *Cornwallite Cu2+5(AsO4)2(OH)2 *Erythrite Co3(AsO4)2·8H2O *Mimetite Pb5(AsO4)3Cl * Olivenite Cu2(AsO4)OH Nickel–Strunz Classification -08- Phosphates IMA-CNMNC proposes a new hierarchical scheme (Mills et al., 2009). This list uses it to modify the Classification of Nickel–Strunz ( mindat.org, 10 ed, pending publication). *Abbreviations: **"*" - discredi ...
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Corkite
Corkite is a phosphate mineral in the beudantite subgroup of the alunite group. Corkite is the phosphate analogue of beudantite and with it, a complete solid solution range exists. Corkite will also form a solid solution with kintoreite. Corkite is named after County Cork, Ireland; the location where the first notable amount was discovered in 1869. Like many of the other minerals in the beudantite group, corkite is a relatively uncommon, secondary mineral that occurs in oxidation zones near hydrothermal base metal deposits. It occurs associated with pyromorphite, malachite, plumbojarosite, limonite and quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical .... References Phosphate minerals Sulfate minerals Lead minerals Iron minerals Trigonal minerals Minerals in ...
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Segnitite
} Segnitite is a lead iron(III) arsenate mineral. Segnitite was first found in the Broken Hill ore deposit in Broken Hill, New South Wales, Australia. In 1991, segnitite was approved as a new mineral. Segnitite has since been found worldwide near similar locality types where rocks are rich in zinc and lead especially. it was named for Australian mineralogist, gemologist and petrologist Edgar Ralph Segnit. The mineral was named after E. R. Segnit due to his contributions to Australian mineralogy. Segnitite is not a primary ore mineral, but is found amongst other well known ore minerals such as galena, sphalerite, pyrite and more. Many minerals found with segnitite are important for industrial purposes. Minerals associated with segnitite make up metal alloys, batteries and even pigments. Carminite and beudanite are closely related to segnitite. In fact, forms of beudanite are commonly confused with segnitite, as the sulfate and arsenate anions readily exchangeable with each oth ...
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Arsenate Mineral
Arsenate minerals usually refer to the naturally occurring orthoarsenates, possessing the (AsO4)3− anion group and, more rarely, other arsenates with anions like AsO3(OH)2− (also written HAsO42−) (example: pharmacolite Ca(AsO3OH).2H2O) or (very rarely) sO2(OH)2sup>− (example: andyrobertsite). Arsenite minerals are much less common. Both the Dana and the Strunz mineral classifications place the arsenates in with the phosphate minerals. Example arsenate minerals include: *Annabergite Ni3(AsO4)2·8H2O *Austinite CaZn(AsO4)(OH) *Clinoclase Cu3(AsO4)(OH)3 *Conichalcite CaCu(AsO4)(OH) *Cornubite Cu5(AsO4)2(OH)4 *Cornwallite Cu2+5(AsO4)2(OH)2 *Erythrite Co3(AsO4)2·8H2O *Mimetite Pb5(AsO4)3Cl *Olivenite Cu2(AsO4)OH Nickel–Strunz Classification -08- Phosphates IMA-CNMNC proposes a new hierarchical scheme (Mills et al., 2009). This list uses it to modify the Classification of Nickel–Strunz ( mindat.org, 10 ed, pending publication). *Abbreviations: **"*" - discredited ( ...
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Anglesite
Anglesite is a lead sulfate mineral with the chemical formula PbSO4. It occurs as an oxidation product of primary lead sulfide ore, galena. Anglesite occurs as prismatic orthorhombic crystals and earthy masses, and is isomorphous with barite and celestine. It contains 74% of lead by mass and therefore has a high specific gravity of 6.3. Anglesite's color is white or gray with pale yellow streaks. It may be dark gray if impure. It was first recognized as a mineral species by William Withering in 1783, who discovered it in the Parys copper-mine in Anglesey; the name anglesite, from this locality, was given by F. S. Beudant in 1832. The crystals from Anglesey, which were formerly found abundantly on a matrix of dull limonite, are small in size and simple in form, being usually bounded by four faces of a prism and four faces of a dome; they are brownish-yellow in colour owing to a stain of limonite. Crystals from some other localities, notably from in Sardinia, are transparent and ...
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Duftite
Duftite is a relatively common arsenate mineral with the formula CuPb(AsO4)(OH), related to conichalcite. It is green and often forms botryoidal aggregates. It is a member of the adelite-descloizite Group, Conichalcite-Duftite Series. Duftite and conichalcite specimens from Tsumeb are commonly zoned in color and composition. Microprobe analyses and X-ray powder-diffraction studies indicate extensive substitution of Zn for Cu, and Ca for Pb in the duftite structure. This indicates a solid solution among conichalcite, CaCu(AsO4 )(OH), austinite, CaZn(AsO4)(OH) and duftite PbCu(AsO4)(OH), all of them belonging to the adelite group of arsenates. It was named after Mining Councilor G Duft, Director of the Otavi Mine and Railroad Company, Tsumeb, Namibia. The type locality is the Tsumeb Mine, Tsumeb, Otjikoto Region, Namibia. Structure The structure is composed of chains of edge-sharing CuO6 distorted octahedra parallel to the c axis. The chains are linked by AsO4 tetrahedra and Pb ato ...
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Bayldonite
Bayldonite (BAIL-done-ite) is a rare secondary mineral with the chemical formula PbCu3(AsO4)2(OH)2. It was first discovered in Penberthy Croft Mine, Cornwall, England, United Kingdom. It is named after its discoverer, John Bayldon (1837(8) – 1872). Specimens are also found in Tsumeb, Namibia, and Arizona, United States. It is sometimes used as a gemstone A gemstone (also called a fine gem, jewel, precious stone, or semiprecious stone) is a piece of mineral crystal which, in cut and polished form, is used to make jewelry or other adornments. However, certain rocks (such as lapis lazuli, opal, ....Gemstones: Properties, Identification and Use By Arthur Thomas, p.159 References Arsenate minerals Copper minerals Gemstones Monoclinic minerals Minerals in space group 15 {{mineral-stub ...
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Olivenite
Olivenite is a copper arsenate mineral, formula Cu2 As O4O H. It crystallizes in the monoclinic system (pseudo-orthorhombic), and is sometimes found in small brilliant crystals of simple prismatic habit terminated by domal faces. More commonly, it occurs as globular aggregates of acicular crystals, these fibrous forms often having a velvety luster; sometimes it is lamellar in structure, or soft and earthy. A characteristic feature, and one to which the name alludes (German, ''Olivenerz'', of A. G. Werner, 1789), is the olive-green color, which varies in shade from blackish-green in the crystals to almost white in the finely fibrous variety known as ''woodcopper''. The hardness is 3, and the specific gravity is 4.3. The mineral was formerly found in some abundance, associated with limonite and quartz, in the upper workings in the copper mines of the St Day district in Cornwall; also near Redruth, and in the Tintic Mining District in Utah. It is a mineral of secondary origin, a ...
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Crystal Habit
In mineralogy, crystal habit is the characteristic external shape of an individual crystal or crystal group. The habit of a crystal is dependent on its crystallographic form and growth conditions, which generally creates irregularities due to limited space in the crystallizing medium (commonly in rocks).Klein, Cornelis, 2007, ''Minerals and Rocks: Exercises in Crystal and Mineral Chemistry, Crystallography, X-ray Powder Diffraction, Mineral and Rock Identification, and Ore Mineralogy,'' Wiley, third edition, Wenk, Hans-Rudolph and Andrei Bulakh, 2004, ''Minerals: Their Constitution and Origin,'' Cambridge, first edition, Recognizing the habit can aid in mineral identification and description, as the crystal habit is an external representation of the internal ordered atomic arrangement. Most natural crystals, however, do not display ideal habits and are commonly malformed. Hence, it is also important to describe the quality of the shape of a mineral specimen: * Euhedral: a cr ...
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Pharmacosiderite
Pharmacosiderite is a hydrated basic ferric arsenate, with chemical formula K Fe4( As O4)3(O H)4·(6-7) H2O and a molecular weight of 873.38 g/mol. It consists of the elements arsenic, iron, hydrogen, potassium, sodium and oxygen. It has a Mohs hardness of 2 to 3, about that of a finger nail. Its specific gravity is about 2.7 to 2.9, has indistinct cleavage, and is usually transparent or translucent. It has a yellow or white streak and a yellow, green, brown or red color. Its lustre is adamantine, vitreous and resinous, and it has conchoidal, brittle and sectile fracture. Pharmacosiderite has an isometric crystal system, with yellowish-green, sharply defined cube crystals. Its crystals are doubly refracting, and exhibit a banded structure in polarized light. When placed in ammonium solution, a crystal changes color to a distinguishing red. Upon placing it into dilute hydrochloric acid the original color is restored. This secondary origin mineral is normally formed in the oxid ...
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Arseniosiderite
Arseniosiderite is a rare arsenate mineral formed by the oxidation of other arsenic-containing minerals, such as scorodite or arsenopyrite Arsenopyrite ( IMA symbol: Apy) is an iron arsenic sulfide (FeAsS). It is a hard ( Mohs 5.5-6) metallic, opaque, steel grey to silver white mineral with a relatively high specific gravity of 6.1. When dissolved in nitric acid, it releases eleme .... It occurs in association with beudantite, carminite, dussertite, pharmacolite, pitticite, adamite and erythrite. The name arseniosiderite reflects two major elements of the mineral, arsenic and iron (Greek ''sideros'' means iron). References Arsenate minerals Monoclinic minerals Minerals in space group 15 {{mineral-stub ...
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