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Corkite is a
phosphate mineral Phosphate minerals contain the tetrahedrally coordinated phosphate (PO43−) anion along sometimes with arsenate (AsO43−) and vanadate (VO43−) substitutions, and chloride (Cl−), fluoride (F−), and hydroxide (OH−) anions that also fit ...
in the
beudantite Beudandite is a secondary mineral occurring in the oxidized zones of polymetallic deposits. It is a lead, iron, arsenate, sulfate with endmember formula: PbFe3(OH)6SO4AsO4. Beudantite is in a subgroup of the alunite group. It is the arsenate an ...
subgroup of the alunite group. Corkite is the phosphate analogue of beudantite and with it, a complete
solid solution A solid solution, a term popularly used for metals, is a homogenous mixture of two different kinds of atoms in solid state and have a single crystal structure. Many examples can be found in metallurgy, geology, and solid-state chemistry. The wor ...
range exists. Corkite will also form a solid solution with kintoreite. Corkite is named after
County Cork County Cork ( ga, Contae Chorcaí) is the largest and the southernmost county of Ireland, named after the city of Cork, the state's second-largest city. It is in the province of Munster and the Southern Region. Its largest market towns a ...
,
Ireland Ireland ( ; ga, Éire ; Ulster Scots dialect, Ulster-Scots: ) is an island in the Atlantic Ocean, North Atlantic Ocean, in Northwestern Europe, north-western Europe. It is separated from Great Britain to its east by the North Channel (Grea ...
; the location where the first notable amount was discovered in 1869. Like many of the other minerals in the beudantite group, corkite is a relatively uncommon, secondary mineral that occurs in oxidation zones near
hydrothermal Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...
base metal A base metal is a common and inexpensive metal, as opposed to a precious metal such as gold or silver. In numismatics, coins often derived their value from the precious metal content; however, base metals have also been used in coins in the past ...
deposits. It occurs associated with
pyromorphite Pyromorphite is a mineral species composed of lead chlorophosphate: Pb5( P O4)3 Cl, sometimes occurring in sufficient abundance to be mined as an ore of lead. Crystals are common, and have the form of a hexagonal prism terminated by the basal pl ...
,
malachite Malachite is a copper carbonate hydroxide mineral, with the formula Cu2CO3(OH)2. This opaque, green-banded mineral crystallizes in the monoclinic crystal system, and most often forms botryoidal, fibrous, or stalagmitic masses, in fracture ...
, plumbojarosite, limonite and
quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical ...
.


References

Phosphate minerals Sulfate minerals Lead minerals Iron minerals Trigonal minerals Minerals in space group 160 Beudantite group {{phosphate-mineral-stub