Duftite is a relatively common

arsenate mineral Arsenate minerals usually refer to the naturally occurring orthoarsenates, possessing the (AsO4)3− anion group and, more rarely, other arsenates with anions like AsO3(OH)2− (also written HAsO42−) (example: pharmacolite Ca(AsO3OH).2H2O) or ( ...

with the formula CuPb(AsO₄)(OH), related to conichalcite. It is green and often forms botryoidal aggregates. It is a member of the adelite- descloizite Group, Conichalcite-Duftite Series. Duftite and conichalcite specimens from Tsumeb are commonly zoned in color and composition. Microprobe analyses and X-ray powder-diffraction studies indicate extensive substitution of Zn for Cu, and Ca for Pb in the duftite structure. This indicates a solid solution among conichalcite, CaCu(AsO₄ )(OH),

austinite Austinite is a member of the adelite- descloizite group, adelite subgroup, the zinc (Zn) end member of the copper-Zn series with conichalcite. It is the zinc analogue of cobaltaustinite and nickelaustinite. At one time “brickerite” was tho ...

, CaZn(AsO₄)(OH) and duftite PbCu(AsO₄)(OH), all of them belonging to the adelite group of arsenates. It was named after Mining Councilor G Duft, Director of the Otavi Mine and Railroad Company, Tsumeb, Namibia. The type locality is the Tsumeb Mine,

Tsumeb , nickname = , settlement_type = City , motto = ''Glück Auf'' (German for ''Good luck'') , image_skyline = Welcome to tsumeb.jpg , imagesize = , image_caption = , image_flag ...

, Otjikoto Region, Namibia.

Structure

The structure is composed of chains of edge-sharing CuO₆ distorted octahedra parallel to the c axis. The chains are linked by AsO₄ tetrahedra and Pb atoms.

Environment

Duftite is an uncommon product of weathered sulfide ore deposits. It is associated with

azurite Azurite is a soft, deep-blue copper mineral produced by weathering of copper ore deposits. During the early 19th century, it was also known as chessylite, after the type locality at Chessy-les-Mines near Lyon, France. The mineral, a basic car ...

at the type locality, and with bayldonite, segnitite,

agardite Agardite is a mineral group consisting of agardite-(Y), agardite-(Ce), agardite-(Nd), and agardite-(La). They comprise a group of minerals that are hydrous hydrated arsenates of rare-earth elements (REE) and copper, with the general chemical for ...

and gartrellite at the Central Cobar Mines, New South Wales, Australia, where some

pseudomorphs In mineralogy, a pseudomorph is a mineral or mineral compound that appears in an atypical form ( crystal system), resulting from a substitution process in which the appearance and dimensions remain constant, but the original mineral is replaced b ...

of duftite after

mimetite Mimetite is a lead arsenate chloride mineral (Pb5(AsO4)3Cl) which forms as a secondary mineral in lead deposits, usually by the oxidation of galena and arsenopyrite. The name derives from the Greek Μιμητής ''mimetes'', meaning "imitator" a ...

have also found. It occurs in association with

olivenite Olivenite is a copper arsenate mineral, formula Cu2 As O4O H. It crystallizes in the monoclinic system (pseudo-orthorhombic), and is sometimes found in small brilliant crystals of simple prismatic habit terminated by domal faces. More commo ...

, mottramite,

malachite Malachite is a copper carbonate hydroxide mineral, with the formula Cu2CO3(OH)2. This opaque, green-banded mineral crystallizes in the monoclinic crystal system, and most often forms botryoidal, fibrous, or stalagmitic masses, in fracture ...

, wulfenite and

calcite Calcite is a carbonate mineral and the most stable polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on the Mohs scale of mineral hardness, based on scratc ...

in the Tsumeb, Namibia deposit. It occurs with bayldonite, beudantite,

and

cerussite Cerussite (also known as lead carbonate or white lead ore) is a mineral consisting of lead carbonate (PbCO3), and is an important ore of lead. The name is from the Latin ''cerussa'', white lead. ''Cerussa nativa'' was mentioned by Conrad Gess ...

in the Cap Garonne mine,

France France (), officially the French Republic ( ), is a country primarily located in Western Europe. It also comprises of Overseas France, overseas regions and territories in the Americas and the Atlantic Ocean, Atlantic, Pacific Ocean, Pac ...

Distribution

Reported from Argentina, Australia, Austria, Chile, the Czech Republic, France, Germany, Greece, Italy, Japan, Mexico, Namibia, Poland, Portugal, Russia, South Africa, Spain, Switzerland, the UK, the US and Zimbabwe.

References

Bibliography

*Palache, P.; Berman H.; Frondel, C. (1960). "''Dana's System of Mineralogy, Volume II: Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. (Seventh Edition)"'' John Wiley and Sons, Inc., New York, pp. 810-811. {{Commons category, Duftite, position=left Arsenate minerals Copper(II) minerals Lead minerals Orthorhombic minerals Minerals in space group 19