Associated Legendre Polynomials
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Associated Legendre Polynomials
In mathematics, the associated Legendre polynomials are the canonical solutions of the general Legendre equation \left(1 - x^2\right) \frac P_\ell^m(x) - 2 x \frac P_\ell^m(x) + \left \ell (\ell + 1) - \frac \rightP_\ell^m(x) = 0, or equivalently \frac \left \left(1 - x^2\right) \frac P_\ell^m(x) \right+ \left \ell (\ell + 1) - \frac \rightP_\ell^m(x) = 0, where the indices ''ℓ'' and ''m'' (which are integers) are referred to as the degree and order of the associated Legendre polynomial respectively. This equation has nonzero solutions that are nonsingular on only if ''ℓ'' and ''m'' are integers with 0 ≤ ''m'' ≤ ''ℓ'', or with trivially equivalent negative values. When in addition ''m'' is even, the function is a polynomial. When ''m'' is zero and ''ℓ'' integer, these functions are identical to the Legendre polynomials. In general, when ''ℓ'' and ''m'' are integers, the regular solutions are sometimes called "associated Legendre polynomials", even though they are ...
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Mathematics
Mathematics is an area of knowledge that includes the topics of numbers, formulas and related structures, shapes and the spaces in which they are contained, and quantities and their changes. These topics are represented in modern mathematics with the major subdisciplines of number theory, algebra, geometry, and analysis, respectively. There is no general consensus among mathematicians about a common definition for their academic discipline. Most mathematical activity involves the discovery of properties of abstract objects and the use of pure reason to prove them. These objects consist of either abstractions from nature orin modern mathematicsentities that are stipulated to have certain properties, called axioms. A ''proof'' consists of a succession of applications of deductive rules to already established results. These results include previously proved theorems, axioms, andin case of abstraction from naturesome basic properties that are considered true starting points of ...
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Laplacian
In mathematics, the Laplace operator or Laplacian is a differential operator given by the divergence of the gradient of a scalar function on Euclidean space. It is usually denoted by the symbols \nabla\cdot\nabla, \nabla^2 (where \nabla is the nabla operator), or \Delta. In a Cartesian coordinate system, the Laplacian is given by the sum of second partial derivatives of the function with respect to each independent variable. In other coordinate systems, such as cylindrical and spherical coordinates, the Laplacian also has a useful form. Informally, the Laplacian of a function at a point measures by how much the average value of over small spheres or balls centered at deviates from . The Laplace operator is named after the French mathematician Pierre-Simon de Laplace (1749–1827), who first applied the operator to the study of celestial mechanics: the Laplacian of the gravitational potential due to a given mass density distribution is a constant multiple of that densit ...
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Lie Group
In mathematics, a Lie group (pronounced ) is a group that is also a differentiable manifold. A manifold is a space that locally resembles Euclidean space, whereas groups define the abstract concept of a binary operation along with the additional properties it must have to be thought of as a "transformation" in the abstract sense, for instance multiplication and the taking of inverses (division), or equivalently, the concept of addition and the taking of inverses (subtraction). Combining these two ideas, one obtains a continuous group where multiplying points and their inverses are continuous. If the multiplication and taking of inverses are smooth (differentiable) as well, one obtains a Lie group. Lie groups provide a natural model for the concept of continuous symmetry, a celebrated example of which is the rotational symmetry in three dimensions (given by the special orthogonal group \text(3)). Lie groups are widely used in many parts of modern mathematics and physics. Lie ...
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Riemann Sphere
In mathematics, the Riemann sphere, named after Bernhard Riemann, is a model of the extended complex plane: the complex plane plus one point at infinity. This extended plane represents the extended complex numbers, that is, the complex numbers plus a value \infty for infinity. With the Riemann model, the point \infty is near to very large numbers, just as the point 0 is near to very small numbers. The extended complex numbers are useful in complex analysis because they allow for division by zero in some circumstances, in a way that makes expressions such as 1/0=\infty well-behaved. For example, any rational function on the complex plane can be extended to a holomorphic function on the Riemann sphere, with the poles of the rational function mapping to infinity. More generally, any meromorphic function can be thought of as a holomorphic function whose codomain is the Riemann sphere. In geometry, the Riemann sphere is the prototypical example of a Riemann surface, and is one of ...
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Spherical Harmonic
In mathematics and physical science, spherical harmonics are special functions defined on the surface of a sphere. They are often employed in solving partial differential equations in many scientific fields. Since the spherical harmonics form a complete set of orthogonal functions and thus an orthonormal basis, each function defined on the surface of a sphere can be written as a sum of these spherical harmonics. This is similar to periodic functions defined on a circle that can be expressed as a sum of circular functions (sines and cosines) via Fourier series. Like the sines and cosines in Fourier series, the spherical harmonics may be organized by (spatial) angular frequency, as seen in the rows of functions in the illustration on the right. Further, spherical harmonics are basis functions for irreducible representations of SO(3), the group of rotations in three dimensions, and thus play a central role in the group theoretic discussion of SO(3). Spherical harmonics originat ...
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Symmetry
Symmetry (from grc, συμμετρία "agreement in dimensions, due proportion, arrangement") in everyday language refers to a sense of harmonious and beautiful proportion and balance. In mathematics, "symmetry" has a more precise definition, and is usually used to refer to an object that is invariant under some transformations; including translation, reflection, rotation or scaling. Although these two meanings of "symmetry" can sometimes be told apart, they are intricately related, and hence are discussed together in this article. Mathematical symmetry may be observed with respect to the passage of time; as a spatial relationship; through geometric transformations; through other kinds of functional transformations; and as an aspect of abstract objects, including theoretic models, language, and music. This article describes symmetry from three perspectives: in mathematics, including geometry, the most familiar type of symmetry for many people; in science and nature ...
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Spherical
A sphere () is a geometrical object that is a three-dimensional analogue to a two-dimensional circle. A sphere is the set of points that are all at the same distance from a given point in three-dimensional space.. That given point is the centre of the sphere, and is the sphere's radius. The earliest known mentions of spheres appear in the work of the ancient Greek mathematicians. The sphere is a fundamental object in many fields of mathematics. Spheres and nearly-spherical shapes also appear in nature and industry. Bubbles such as soap bubbles take a spherical shape in equilibrium. The Earth is often approximated as a sphere in geography, and the celestial sphere is an important concept in astronomy. Manufactured items including pressure vessels and most curved mirrors and lenses are based on spheres. Spheres roll smoothly in any direction, so most balls used in sports and toys are spherical, as are ball bearings. Basic terminology As mentioned earlier is the sphere's r ...
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The First Few Associated Legendre Functions
''The'' () is a grammatical article in English, denoting persons or things already mentioned, under discussion, implied or otherwise presumed familiar to listeners, readers, or speakers. It is the definite article in English. ''The'' is the most frequently used word in the English language; studies and analyses of texts have found it to account for seven percent of all printed English-language words. It is derived from gendered articles in Old English which combined in Middle English and now has a single form used with pronouns of any gender. The word can be used with both singular and plural nouns, and with a noun that starts with any letter. This is different from many other languages, which have different forms of the definite article for different genders or numbers. Pronunciation In most dialects, "the" is pronounced as (with the voiced dental fricative followed by a schwa) when followed by a consonant sound, and as (homophone of pronoun ''thee'') when followed by a ...
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Gamma Function
In mathematics, the gamma function (represented by , the capital letter gamma from the Greek alphabet) is one commonly used extension of the factorial function to complex numbers. The gamma function is defined for all complex numbers except the non-positive integers. For every positive integer , \Gamma(n) = (n-1)!\,. Derived by Daniel Bernoulli, for complex numbers with a positive real part, the gamma function is defined via a convergent improper integral: \Gamma(z) = \int_0^\infty t^ e^\,dt, \ \qquad \Re(z) > 0\,. The gamma function then is defined as the analytic continuation of this integral function to a meromorphic function that is holomorphic in the whole complex plane except zero and the negative integers, where the function has simple poles. The gamma function has no zeroes, so the reciprocal gamma function is an entire function. In fact, the gamma function corresponds to the Mellin transform of the negative exponential function: \Gamma(z) = \mathcal M \ (z ...
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Coulomb Operator
The Coulomb operator, named after Charles-Augustin de Coulomb, is a quantum mechanics, quantum mechanical operator (mathematics), operator used in the field of quantum chemistry. Specifically, it is a term found in the Hartree–Fock, Fock operator. It is defined as: \widehat J_j (1) f_i(1)= f_i(1) \int ^2 \frac\,dr_2 where \widehat J_j (1) is the one-electron Coulomb operator defining the repulsion resulting from electron ''j'', f_i(1) is the one-electron wavefunction of the i^ electron being acted upon by the Coulomb operator, \varphi_j(1) is the one-electron wavefunction of the j^ electron, r_ is the distance between electrons (i) and (j) . See also *Core Hamiltonian *Exchange operator References

Quantum chemistry Theoretical chemistry Computational chemistry {{quantum-chemistry-stub ...
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