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Ashburtonite
Ashburtonite is a rare lead copper silicate-bicarbonate mineral with formula: HPb4Cu2+4Si4O12(HCO3)4(OH)4Cl. Geological occurrence Ashburtonite was first described as a secondary mineral in a shear zone in a series of shales and graywackes. It is an alteration product of galena and chalcopyrite. The secondary minerals within the shear consist of carbonates, arsenates, and sulfates of lead and copper, and to a much lesser extent of zinc and iron. Ashburtonite is associated with beudantite, brochantite, caledonite, cerussite, diaboleite, duftite, malachite, plattnerite, adamite, antlerite, bayldonite, bindheimite, carminite, chenevixite, chlorargyrite, chrysocolla, cinnabar, hemimorphite, hydrozincite, jarosite, lavendulan, linarite, mimetite, olivenite, paratacamite, and rosasite. Ashburtonite was first described in 1991 for an occurrence in the Anticline prospects southwest of Ashburton Downs in the Capricorn Range of Western Australia. It has also been reporte ...
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Cyclosilicates
Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, silica (silicon dioxide, ) is usually considered a silicate mineral. Silica is found in nature as the mineral quartz, and its polymorphism (materials science), polymorphs. On Earth, a wide variety of silicate minerals occur in an even wider range of combinations as a result of the processes that have been forming and re-working the crust for billions of years. These processes include partial melting, crystallization, fractionation, metamorphism, weathering, and diagenesis. Living organisms also contribute to this carbonate–silicate cycle, geologic cycle. For example, a type of plankton known as diatoms construct their exoskeletons ("frustules") from silica extracted from seawater. The frustules of dead diatoms are a major constituent of deep ocean sediment, and of diatomaceous e ...
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Caledonite
Caledonite, whose name derives from Caledonia, the historical name of its place of discovery (Scotland), is a richly colored blue-green sulfate-carbonate mineral of lead and copper with an orthorhombic crystal structure. It is an uncommon mineral found in the oxidized zones of copper-lead deposits. Collectible properties Caledonite's primary use is a collector's mineral. Although it contains copper and lead, it is a secondary mineral and is not prevalent enough in any known deposits to be used as an ore. Caledonite, when developed into full crystals, can have a deep blue-green color reminiscent of secondary copper minerals. Its high lustre, on the other hand, is more like secondary lead minerals. Localities in which caledonite occurs as well developed crystals are quite rare and include the Mammoth-St. Anthony Mine at Tiger, Arizona, a few mines in California, such as the Reward Mine. A few other mines in Arizona and Chile have been known to produce samples. Associated minerals ...
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Chrysocolla
Chrysocolla ( ) is a hydrated copper phyllosilicate mineral and mineraloid with formula (x<1) or . The structure of the mineral has been questioned, as a 2006 spectrographic study suggest material identified as chrysocolla may be a mixture of the copper hydroxide and .


History

The name comes from the χρυσός (''chrysos'') and κολλα (''kolla''), "gold" and "glue," in allusion to the name of the material used to solder

Chlorargyrite
Chlorargyrite is the mineral form of silver chloride (AgCl). Chlorargyrite occurs as a secondary mineral phase in the oxidation of silver mineral deposits. It crystallizes in the isometric - hexoctahedral crystal class. Typically massive to columnar in occurrence it also has been found as colorless to variably yellow cubic crystals. The color changes to brown or purple on exposure to light. It is quite soft with a Mohs hardness of 1 to 2 and dense with a specific gravity of 5.55. It is also known as cerargyrite and, when weathered by desert air, as horn silver. Bromian chlorargyrite (or embolite) is also common. Chlorargyrite is water-insoluble. It occurs associated with native silver, cerussite, iodargyrite, atacamite, malachite, jarosite and various iron–manganese oxides. It was first described in 1875 for occurrences in the Broken Hill district, New South Wales, Australia. The rich Bridal Chamber deposit at Lake Valley, Sierra County, New Mexico was almost pure chorargyrit ...
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Carminite
Carminite (PbFe3+2(AsO4)2(OH)2) is an anhydrous arsenate mineral containing hydroxyl. It is a rare secondary mineral that is structurally related to palermoite (Li2SrAl4(PO4)4(OH)4). Sewardite (CaFe3+2(AsO4)2(OH)2) is an analogue of carminite, with calcium in sewardite in place of the lead in carminite. Mawbyite is a dimorph (same formula, different structure) of carminite; mawbyite is monoclinic and carminite is orthorhombic. It has a molar mass of 639.87 g. It was discovered in 1850 and named for the characteristic carmine colour. Structure Carminite belongs to the orthorhombic crystal class (2/m 2/m 2/m) and has space group C ccm or C cc2.Finney J J (1963) American Mineralogist 48: 1-13 The structure consists of linked octahedra of iron surrounded by oxygen and hydroxyl which are aligned parallel to the c axis. They are connected together in the direction of the a axis by arsenate tetrahedra (arsenic surrounded by 4 oxygen). Coordination about the lead a ...
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Bindheimite
__TOC__ B Ba # Babánekite (vivianite: IMA2012-007) 8.CE o o(IUPAC: tricopper diarsenate octahydrate) #Babefphite (IMA1966-003) 8.BA.1

(IUPAC: barium beryllium fluoro phosphate) # (rhodonite: 1824) 9.DK.0

#
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Bayldonite
Bayldonite (BAIL-done-ite) is a rare secondary mineral with the chemical formula PbCu3(AsO4)2(OH)2. It was first discovered in Penberthy Croft Mine, Cornwall, England, United Kingdom. It is named after its discoverer, John Bayldon (1837(8) – 1872). Specimens are also found in Tsumeb, Namibia, and Arizona, United States. It is sometimes used as a gemstone A gemstone (also called a fine gem, jewel, precious stone, or semiprecious stone) is a piece of mineral crystal which, in cut and polished form, is used to make jewelry or other adornments. However, certain rocks (such as lapis lazuli, opal, ....Gemstones: Properties, Identification and Use By Arthur Thomas, p.159 References Arsenate minerals Copper minerals Gemstones Monoclinic minerals Minerals in space group 15 {{mineral-stub ...
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Antlerite
Antlerite is a greenish hydrous copper sulfate mineral, with the formula Cu3(SO4)(OH)4. It occurs in tabular, acicular, or fibrous crystals with a vitreous luster. Originally believed to be a rare mineral, antlerite was found to be the primary ore of the oxidised zones in several copper mines across the world, including the Chuquicamata mine in Chile, and the Antler mine in Arizona, US from which it takes its name. It is chemically and optically similar in many respects to other copper minerals such as malachite and brochantite, though it can be distinguished from the former by a lack of effervescence in hydrochloric acid. Antlerite is a common corrosion product on bronze sculptures located in urban areas, where atmospheric sulfur dioxide (a common pollutant) is present. Antlerite forms mainly in sheltered areas where weathering is low, which permits accumulation of copper ions and enhancement in the acidity of water films.Leygraf C, Graedel TE. Atmospheric corrosion. New Yor ...
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Adamite
Adamite is a zinc arsenate hydroxide mineral, Zn2 As O4O H. It is a mineral that typically occurs in the oxidized or weathered zone above zinc ore occurrences. Pure adamite is colorless, but usually it possess yellow color due to Fe compounds admixture. Tints of green also occur and are connected with copper substitutions in the mineral structure. Olivenite is a copper arsenate that is isostructural with adamite and there is considerable substitution between zinc and copper resulting in an intermediate called ''cuproadamite''. Zincolivenite is a recently discovered mineral being an intermediate mineral with formula CuZn(AsO4)(OH). Manganese, cobalt, and nickel also substitute in the structure. An analogous zinc phosphate, ''tarbuttite'', is known. Occurrence Adamite occurs as a secondary mineral in the oxidized zone of zinc- and arsenic-bearing hydrothermal mineral deposits. It occurs in association with smithsonite, hemimorphite, scorodite, olivenite, calcite, quartz and iron ...
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Plattnerite
Plattnerite is an oxide mineral and is the beta crystalline form of lead dioxide (β-PbO2), scrutinyite being the other, alpha form. It was first reported in 1845 and named after German mineralogist Karl Friedrich Plattner. Plattnerite forms bundles of dark needle-like crystals on various minerals; the crystals are hard and brittle and have tetragonal symmetry. Occurrence Plattnerite is found in numerous arid locations in North America (US and Mexico), most of Europe, Asia (Iran and Russia), Africa (Namibia) and Southern and Western Australia. It occurs in weathered Hydrothermal circulation, hydrothermal base-metal deposits as hay-like bundles of dark prismatic crystals with a length of a few millimeters; the bundles grow on, or sometimes within various minerals, including cerussite, smithsonite, hemimorphite, leadhillite, hydrozincite, rosasite, aurichalcite, murdochite, limonite, pyromorphite, wulfenite, calcite and quartz. Properties and applications Basic properties of plat ...
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Malachite
Malachite is a copper carbonate hydroxide mineral, with the formula Cu2CO3(OH)2. This opaque, green-banded mineral crystallizes in the monoclinic crystal system, and most often forms botryoidal, fibrous, or stalagmitic masses, in fractures and deep, underground spaces, where the water table and hydrothermal fluids provide the means for chemical precipitation. Individual crystals are rare, but occur as slender to acicular prisms. Pseudomorphs after more tabular or blocky azurite crystals also occur. Etymology and history The stone's name derives (via la, molochītis, frm, melochite, and Middle English ''melochites'') from Greek Μολοχίτης λίθος ''molochites lithos'', "mallow-green stone", from μολόχη ''molochē'', variant of μαλάχη ''malāchē'', "mallow". The mineral was given this name due to its resemblance to the leaves of the mallow plant. Malachite was mined from deposits near the Isthmus of Suez and the Sinai as early as 4000 BCE. It wa ...
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