Ashburtonite is a rare lead copper silicate-bicarbonate mineral with formula: HPb₄Cu²⁺₄Si₄O₁₂(HCO₃)₄(OH)₄Cl.

Geological occurrence

Ashburtonite was first described as a secondary mineral in a

shear zone In geology, a shear zone is a thin zone within the Earth's crust or upper mantle that has been strongly deformed, due to the walls of rock on either side of the zone slipping past each other. In the upper crust, where rock is brittle, the shear ...

in a series of

shale Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4) and tiny fragments (silt-sized particles) of other minerals, especial ...

s and graywackes. It is an alteration product of

galena Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver. Galena is one of the most abundant and widely distributed sulfide minerals. It cryst ...

and chalcopyrite. The secondary minerals within the shear consist of carbonates, arsenates, and sulfates of

lead Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cu ...

and

copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkis ...

, and to a much lesser extent of

zinc Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodi ...

and

iron Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...

. Ashburtonite is associated with beudantite,

brochantite Brochantite is a sulfate mineral, one of a number of cupric sulfates. Its chemical formula is Cu4SO4(OH)6. Formed in arid climates or in rapidly oxidizing copper sulfide deposits, it was named by Armand Lévy for his fellow Frenchman, geologist ...

, caledonite,

cerussite Cerussite (also known as lead carbonate or white lead ore) is a mineral consisting of lead carbonate (PbCO3), and is an important ore of lead. The name is from the Latin ''cerussa'', white lead. ''Cerussa nativa'' was mentioned by Conrad Gessner ...

, diaboleite, duftite,

malachite Malachite is a copper carbonate hydroxide mineral, with the formula Cu2CO3(OH)2. This opaque, green-banded mineral crystallizes in the monoclinic crystal system, and most often forms botryoidal, fibrous, or stalagmitic masses, in fractures ...

plattnerite Plattnerite is an oxide mineral and is the beta crystalline form of lead dioxide (β-PbO2), scrutinyite being the other, alpha form. It was first reported in 1845 and named after German mineralogist Karl Friedrich Plattner. Plattnerite forms bundle ...

adamite Adamite is a zinc arsenate hydroxide mineral, Zn2 As O4O H. It is a mineral that typically occurs in the oxidized or weathered zone above zinc ore occurrences. Pure adamite is colorless, but usually it possess yellow color due to Fe compounds a ...

, antlerite, bayldonite,

bindheimite __TOC__ B Ba # Babánekite (vivianite: IMA2012-007) 8.CE o o(IUPAC: tricopper diarsenate octahydrate) #Babefphite (IMA1966-003) 8.BA.1

carminite Carminite (PbFe3+2(AsO4)2(OH)2) is an anhydrous arsenate mineral containing hydroxyl. It is a rare secondary mineral that is structurally related to palermoite (Li2SrAl4(PO4)4(OH)4). Sewardite (CaFe3+2(AsO4)2(OH)2) is an analogue of carmin ...

, chenevixite,

chlorargyrite Chlorargyrite is the mineral form of silver chloride (AgCl). Chlorargyrite occurs as a secondary mineral phase in the oxidation of silver mineral deposits. It crystallizes in the isometric - hexoctahedral crystal class. Typically massive to colum ...

, chrysocolla, cinnabar, hemimorphite,

hydrozincite Hydrozincite, also known as zinc bloom or marionite, is a white carbonate mineral consisting of Zn5( CO3)2( OH)6. It is usually found in massive rather than crystalline form. It occurs as an oxidation product of zinc ores and as post mine incru ...

jarosite Jarosite is a basic hydrous sulfate of potassium and ferric iron (Fe-III) with a chemical formula of KFe3(SO4)2(OH)6. This sulfate mineral is formed in ore deposits by the oxidation of iron sulfides. Jarosite is often produced as a byproduct duri ...

lavendulan Lavendulan is an uncommon copper arsenate mineral, known for its characteristic intense electric blue colour. It belongs to the lavendulan group, which has four members: * Lavendulan NaCaCu5(AsO4)4Cl.5H2O * Lemanskiite NaCaCu5(AsO4)4Cl.5H2O * Sam ...

, linarite, mimetite,

olivenite Olivenite is a copper arsenate mineral, formula Cu2 As O4O H. It crystallizes in the monoclinic system (pseudo-orthorhombic), and is sometimes found in small brilliant crystals of simple prismatic habit terminated by domal faces. More commonly ...

paratacamite Paratacamite is a mineral in the halide minerals category. Its chemical formula is . Its name is derived from its association with atacamite. It is found in Chile, Botallack Mine in Cornwall, Broken Hill, Australia, and in Italy in Capo Calamita ...

, and

rosasite Rosasite is a carbonate mineral with minor potential for use as a zinc and copper ore. Chemically, it is a copper zinc carbonate hydroxide with a copper to zinc ratio of 3:2, occurring in the secondary oxidation zone of copper-zinc deposits. It wa ...

. Ashburtonite was first described in 1991 for an occurrence in the Anticline prospects southwest of Ashburton Downs in the Capricorn Range of

Western Australia Western Australia (commonly abbreviated as WA) is a state of Australia occupying the western percent of the land area of Australia excluding external territories. It is bounded by the Indian Ocean to the north and west, the Southern Ocean to th ...

. It has also been reported from the Tonopah–Belmont Mine in the

Big Horn Mountains The Bighorn Mountains ( cro, Basawaxaawúua, lit=our mountains or cro, Iisaxpúatahchee Isawaxaawúua, label=none, lit=bighorn sheep's mountains) are a mountain range in northern Wyoming and southern Montana in the United States, forming a nort ...

of Maricopa County, Arizona.

References

Tetragonal minerals Minerals in space group 87 Cyclosilicates {{silicate-mineral-stub