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Chrysocolla ( ) is a hydrous
copper Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...
phyllosilicate Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, the crystalline forms of silica (silicon dio ...
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Mi ...
and
mineraloid A mineraloid is a naturally occurring substance that resembles a mineral, but does not demonstrate the crystallinity of a mineral. Mineraloid substances possess chemical compositions that vary beyond the generally accepted ranges for specific mi ...
with the
formula In science, a formula is a concise way of expressing information symbolically, as in a mathematical formula or a ''chemical formula''. The informal use of the term ''formula'' in science refers to the general construct of a relationship betwe ...
(''x'' < 1) or . The structure of the mineral has been questioned, as a 2006 spectrographic study suggest material identified as chrysocolla may be a mixture of the copper hydroxide spertiniite and
chalcedony Chalcedony ( or ) is a cryptocrystalline form of silica, composed of very fine intergrowths of quartz and moganite. These are both silica minerals, but they differ in that quartz has a trigonal crystal structure, while moganite is monoclinic ...
. Chrysocolla typically forms amorphously.


History

The name ''chrysocolla'' comes from the
Ancient Greek Ancient Greek (, ; ) includes the forms of the Greek language used in ancient Greece and the classical antiquity, ancient world from around 1500 BC to 300 BC. It is often roughly divided into the following periods: Mycenaean Greek (), Greek ...
(') and ('), meaning "gold" and "glue" respectively, in allusion to the name of the material used to
solder Solder (; North American English, NA: ) is a fusible alloy, fusible metal alloy used to create a permanent bond between metal workpieces. Solder is melted in order to wet the parts of the joint, where it adheres to and connects the pieces aft ...
gold Gold is a chemical element; it has chemical symbol Au (from Latin ) and atomic number 79. In its pure form, it is a brightness, bright, slightly orange-yellow, dense, soft, malleable, and ductile metal. Chemically, gold is a transition metal ...
. The word was first used by
Theophrastus Theophrastus (; ; c. 371 – c. 287 BC) was an ancient Greek Philosophy, philosopher and Natural history, naturalist. A native of Eresos in Lesbos, he was Aristotle's close colleague and successor as head of the Lyceum (classical), Lyceum, the ...
in 315 BC.


Geology

Chrysocolla has a
cyan Cyan () is the color between blue and green on the visible spectrum of light. It is evoked by light with a predominant wavelength between 500 and 520 nm, between the wavelengths of green and blue. In the subtractive color system, or CMYK c ...
(blue-green) color and is a minor ore of copper, having a
hardness In materials science, hardness (antonym: softness) is a measure of the resistance to plastic deformation, such as an indentation (over an area) or a scratch (linear), induced mechanically either by Pressing (metalworking), pressing or abrasion ...
of 2.5 to 7.0. It is of secondary origin and forms in the
oxidation Redox ( , , reduction–oxidation or oxidation–reduction) is a type of chemical reaction in which the oxidation states of the reactants change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is ...
zones of copper
ore Ore is natural rock or sediment that contains one or more valuable minerals, typically including metals, concentrated above background levels, and that is economically viable to mine and process. The grade of ore refers to the concentration ...
bodies. Associated minerals are
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...
,
limonite Limonite () is an iron ore consisting of a mixture of hydrated iron(III) oxide-hydroxides in varying composition. The generic formula is frequently written as , although this is not entirely accurate as the ratio of oxide to hydroxide can vary qu ...
,
azurite Azurite or '' Azure spar'Krivovichev V. G.'' Mineralogical glossary. Scientific editor A. G. Bulakh. — St.Petersburg: St.Petersburg Univ. Publ. House. 2009. — 556 p. — ISBN 978-5-288-04863-0. ''(in Russian)'' is a soft, deep-blue copp ...
,
malachite Malachite () is a copper Carbonate mineral, carbonate hydroxide mineral, with the chemical formula, formula Basic copper carbonate, Cu2CO3(OH)2. This opaque, green-banded mineral crystallizes in the monoclinic crystal system, and most often for ...
, cuprite, and other secondary copper minerals. It is typically found as
botryoidal A botryoidal ( ) texture or mineral habit, is one in which the mineral has an external form composed of many rounded segments, named for the Ancient Greek (), meaning "a bunch of grapes".Adjective form: ''botruoeidēs'' This is a common form f ...
or rounded masses and crusts, or vein fillings. A 2006 study has produced evidence that chrysocolla may be a microscopic mixture of the copper hydroxide mineral spertiniite, amorphous silica and water.François Farges, Karim Benzerara, Gordon E. Brown, Jr.; ''Chrysocolla Redefined as Spertiniite''; SLAC-PUB-12232; 13th International Conference On X-Ray Absorption Fine Structure (XAFS13); July 9-14, 2006; Stanford, California
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Jewelry

Due to being somewhat more common than
turquoise Turquoise is an opaque, blue-to-green mineral that is a hydrous phosphate of copper and aluminium, with the chemical formula . It is rare and valuable in finer grades and has been prized as a gemstone for millennia due to its hue. The robi ...
, its wide availability, and vivid, beautiful blue and blue-green colors, chrysocolla has been popular for use as a gemstone for carvings and ornamental use since antiquity. It is often used in
silversmithing A silversmith is a metalworker who crafts objects from silver. The terms ''silversmith'' and ''goldsmith'' are not exact synonyms, as the techniques, training, history, and guilds are (or were, at least) largely the same but differed in that t ...
and
goldsmithing A goldsmith is a metalworker who specializes in working with gold and other precious metals. Modern goldsmiths mainly specialize in jewelry-making but historically, they have also made silverware, platters, goblets, decorative and serviceable ...
in place of turquoise and is relatively easy to work and shape. Chrysocolla exhibits a wide range of
Mohs hardness The Mohs scale ( ) of mineral hardness is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fair ...
ranging from 2 through 7, which is dependent on the amount of silica incorporated into the stone when it is forming. Generally, dark navy blue chrysocolla is too soft to be used in jewelry, while cyan, green, and blue-green chrysocolla can have a hardness approaching 6, similar to turquoise. Chrysocolla chalcedony is a heavily silicified form of chrysocolla that forms in quartz deposits and can be very hard and approach a hardness of 7.


Gallery

Chrysocolla-Tyrolite-Clinotyrolite-202106.jpg, Powder-blue chrysocolla as stalactitic growths and as a thin carpet in vugs inside a boulder of nearly solid
tyrolite Tyrolite is a hydrous calcium copper arsenate carbonate mineral with the formula Ca Cu5( As O4)2 CO3(O H)4⋅6 H2O. Tyrolite forms glassy, blue to green orthorhombic radial crystals and botryoidal masses. It has a Mohs hardness of 1.5–2.0 and ...
, from the San Simon Mine,
Iquique Province Iquique Province () is one of two provinces in the northern Chilean region of Tarapacá. Its capital is the port city of Iquique. History Until October 2007, the Province of Iquique was composed of 7 communes: Alto Hospicio, Camina, Colchane, Hu ...
, Chile (size: ) Chrysocolla-201585.jpg, Banded white to blue green chrysocolla, from
Bisbee, Arizona Bisbee is a city in and the county seat of Cochise County, Arizona, Cochise County in southeastern Arizona, United States. It is southeast of Tucson, Arizona, Tucson and north of the Mexican border. According to the 2020 United States census, ...
(size: ) Chrysocolla-bolo.jpg, Chrysocolla and silver bolo tie. This chrysocolla specimen is from the Kennecot Copper Mine in Bingham Canyon,
West Valley City, Utah West Valley City is a city in Salt Lake County and an inner suburb of Salt Lake City in the U.S. state of Utah. The population was 140,230 at the 2020 census, making it the second-most populous city in Utah after Salt Lake City. The city inco ...
. Brochantite-Chrysocolla-k329b.jpg,
Brochantite Brochantite is a sulfate mineral, one of a number of cupric sulfates. Its chemical formula is Cu4SO4(OH)6. Formed in arid climates or in rapidly oxidizing copper sulfide deposits, it was named by Armand Lévy (mineralogist), Armand Lévy for his ...
(emerald green) and chrysocolla, from the Rokana Mine, Zambian Copperbelt


See also

* Chrysocolla (gold-solder)


References

{{Jewellery Copper ores Phyllosilicates Orthorhombic minerals Gemstones Blendes