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Angelo Angeli
Angelo Angeli (20 August 1864 – 31 May 1931) was an Italian chemist. Angeli's salt and the Angeli–Rimini reaction are named after him. Scientific career Angeli studied in Padua, where he met the chemist Giacomo Luigi Ciamician. When Ciamician moved to a new appointment in Bologna, he chose Angeli to work as his assistant, even before Angeli had graduated. In 1891, Angeli was awarded his doctorate in chemistry at Bologna. In 1893, he became a lecturer in Bologna, and in 1895 he became a professor. In 1894, he worked briefly in Munich with Adolf von Baeyer, learning medicinal chemistry. In 1897, he moved to the University of Palermo where he became Professor of Pharmaceutical Chemistry. In 1913, Angeli became director of the Pharmacy School in Florence. In 1915, he became Professor of Organic Chemistry at the University of Florence (Istituto di Studi Superiori), a position that was created specifically for him. Angeli focused on nitrogen compounds. He investigated the s ...
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Tarcento
Tarcento ( fur, Tarcint, sl, Čenta) is a small city, having become a city officially when the church was given back its rank of Duomo, cathedral, and ''comune'' (municipality) in the province of Udine, in the Friuli Venezia Giulia region of north-eastern Italy. History Tarcento occupies a strategic location at a bridging point on the River Torre. Archaeological finds indicate a very early date for its first human occupation. Tarcento first appears in the historical record around the year 1126 CE, when an Austrian nobleman, Machland, from Perg, was feudal overlord of the castle around which the town had developed. Subsequently, a second castle was built on the hill of Coia. In 1219 the Caporiacco family took over as feudal overlords. Both castles were badly damaged during wars for control of the area between the Holy Roman Empire and the Republic of Venice in the Middle Ages, and in 1420 CE Tarcento became part of the territory controlled by the Venetian Republic. The main castl ...
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Nitroxyl Radical
Aminoxyl denotes a radical functional group with general structure R2N–O•. It is commonly known as a nitroxyl radical or a nitroxide, however IUPAC discourages the use of these terms, as they erroneously suggest the presence of a nitro group. Aminoxyls are structurally related to hydroxylamines and ''N''-oxoammonium salts, with which they can interconvert via a series of redox steps. Aminoxyl radical.svg, The general structure of the aminoxyl radical 2,2,6,6-Tetramethylpiperidinyloxyl.svg, TEMPO, a commonly encountered organic aminoxyl radical Kaliumnitrosodisulfonat.svg, Fremy's salt, an inorganic aminoxyl radical Sterically unhindered aminoxyls baring α-hydrogens are unstable and undergo rapid disproportionation to nitrones and hydroxylamines. Sterically hindered aminoxyls without α-hydrogens, such TEMPO and TEMPOL, and are persistent (stable) radicals and find use in a range of applications, both on the laboratory scale and in industry. Their ability to reversibly ...
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1931 Deaths
Events January * January 2 – South Dakota native Ernest Lawrence invents the cyclotron, used to accelerate particles to study nuclear physics. * January 4 – German pilot Elly Beinhorn begins her flight to Africa. * January 22 – Sir Isaac Isaacs is sworn in as the first Australian-born Governor-General of Australia. * January 25 – Mohandas Gandhi is again released from imprisonment in India. * January 27 – Pierre Laval forms a government in France. February * February 4 – Soviet leader Joseph Stalin gives a speech calling for rapid industrialization, arguing that only strong industrialized countries will win wars, while "weak" nations are "beaten". Stalin states: "We are fifty or a hundred years behind the advanced countries. We must make good this distance in ten years. Either we do it, or they will crush us." The first five-year plan in the Soviet Union is intensified, for the industrialization and collectivization of agriculture. * February 10 – O ...
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1864 Births
Events January–March * January 13 – American songwriter Stephen Foster ("Oh! Susanna", "Old Folks at Home") dies aged 37 in New York City, leaving a scrap of paper reading "Dear friends and gentle hearts". His parlor song " Beautiful Dreamer" is published in March. * January 16 – Denmark rejects an Austrian-Prussian ultimatum to repeal the Danish Constitution, which says that Schleswig-Holstein is part of Denmark. * January 21 – New Zealand Wars: The Tauranga campaign begins. * February – John Wisden publishes '' The Cricketer's Almanack for the year 1864'' in England; it will go on to become the major annual cricket reference publication. * February 1 – Danish-Prussian War (Second Schleswig War): 57,000 Austrian and Prussian troops cross the Eider River into Denmark. * February 15 – Heineken brewery founded in Netherlands. * February 17 – American Civil War: The tiny Confederate hand-propelled submarine ''H. L. Hunl ...
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Chemische Berichte
''Chemische Berichte'' (usually abbreviated as ''Ber.'' or ''Chem. Ber.'') was a German-language scientific journal of all disciplines of chemistry founded in 1868. It was one of the oldest scientific journals in chemistry, until it merged with ''Recueil des Travaux Chimiques des Pays-Bas'' to form ''Chemische Berichte/Recueil'' in 1997. ''Chemische Berichte/Recueil'' was then merged with other European journals in 1998 to form ''European Journal of Inorganic Chemistry''. History Founded in 1868 as ''Berichte der Deutschen Chemischen Gesellschaft'' (, CODEN BDCGAS), it operated under this title until 1928 (Vol. 61). The journal was then split into: * ''Berichte der Deutschen Chemischen Gesellschaft, A: Vereins-Nachrichten'' (, CODEN BDCAAS), and * ''Berichte der Deutschen Chemischen Gesellschaft, B: Abhandlungen'' (, CODEN BDCBAD). Vol. 78 and 79 (1945–1946) were omitted and not published due to World War II. The journal was renamed ''Chemische Berichte'' (, CODEN CHBEAM) in 19 ...
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Accademia Dei Lincei
The Accademia dei Lincei (; literally the "Academy of the Lynx-Eyed", but anglicised as the Lincean Academy) is one of the oldest and most prestigious European scientific institutions, located at the Palazzo Corsini on the Via della Lungara in Rome, Italy. Founded in the Papal States in 1603 by Federico Cesi, the academy was named after the lynx, an animal whose sharp vision symbolizes the observational prowess that science requires. Galileo Galilei was the intellectual centre of the academy and adopted "Galileo Galilei Linceo" as his signature. "The Lincei did not long survive the death in 1630 of Cesi, its founder and patron", and "disappeared in 1651". During the nineteenth century, it was revived, first in the Vatican and later in the nation of Italy. Thus the Pontifical Academy of Science, founded in 1847, claims this heritage as the ''Accademia Pontificia dei Nuovi Lincei ("Pontifical Academy of the New Lynxes")'', descending from the first two incarnations of the Academy. ...
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Julius Bredt
Julius Bredt (March 29, 1855 – September 21, 1937) was a German organic chemist. He was the first to determine, in 1893, the correct structure of camphor. Bredt also discovered that a double bond cannot be placed at the bridgehead of a bridged ring system, a statement now known as Bredt's rule Bredt's rule is an empirical observation in organic chemistry that states that a double bond cannot be placed at the bridgehead of a bridged ring system, unless the rings are large enough. The rule is named after Julius Bredt, who first discussed .... Awards There is a Julius Bredt lecture in his remembrance at the RWTH Aachen University. Further reading * References 1855 births 1937 deaths 19th-century German chemists Organic chemists 20th-century German chemists Scientists from Berlin RWTH Aachen University faculty {{Germany-chemist-stub ...
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Camphor
Camphor () is a waxy, colorless solid with a strong aroma. It is classified as a terpenoid and a cyclic ketone. It is found in the wood of the camphor laurel ('' Cinnamomum camphora''), a large evergreen tree found in East Asia; and in the kapur tree ( ''Dryobalanops'' sp.), a tall timber tree from South East Asia. It also occurs in some other related trees in the laurel family, notably '' Ocotea usambarensis''. Rosemary leaves (''Rosmarinus officinalis'') contain 0.05 to 0.5% camphor, while camphorweed (''Heterotheca'') contains some 5%. A major source of camphor in Asia is camphor basil (the parent of African blue basil). Camphor can also be synthetically produced from oil of turpentine. The compound is chiral, existing in two possible enantiomers as shown in the structural diagrams. The structure on the left is the naturally occurring (+)-camphor ((1''R'',4''R'')-bornan-2-one), while its mirror image shown on the right is the (−)-camphor ((1''S'',4''S'')-bornan-2-one). ...
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Aldehyde
In organic chemistry, an aldehyde () is an organic compound containing a functional group with the structure . The functional group itself (without the "R" side chain) can be referred to as an aldehyde but can also be classified as a formyl group. Aldehydes are common and play important roles in the technology and biological spheres. Structure and bonding Aldehydes feature a carbon center that is connected by a double bond to oxygen and a single bond to hydrogen and single bond to a third substituent, which is carbon or, in the case of formaldehyde, hydrogen. The central carbon is often described as being sp2- hybridized. The aldehyde group is somewhat polar. The C=O bond length is about 120-122 picometers. Physical properties and characterization Aldehydes have properties that are diverse and that depend on the remainder of the molecule. Smaller aldehydes are more soluble in water, formaldehyde and acetaldehyde completely so. The volatile aldehydes have pungent odors. Al ...
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Hydrazoic Acid
Hydrazoic acid, also known as hydrogen azide or azoimide, This also contains a detailed description of the contemporaneous production process. is a compound with the chemical formula . It is a colorless, volatile, and explosive liquid at room temperature and pressure. It is a compound of nitrogen and hydrogen, and is therefore a pnictogen hydride. It was first isolated in 1890 by Theodor Curtius. The acid has few applications, but its conjugate acid, conjugate base, the azide ion, is useful in specialized processes. Hydrazoic acid, like its fellow mineral acids, is soluble in water. Undiluted hydrazoic acid is dangerously explosive with a standard enthalpy of formation ΔfHo (l, 298K) = +264 kJ/mol. When dilute, the gas and aqueous solutions (<10%) can be safely prepared but should be used immediately; because of its low boiling point, hydrazoic acid is enriched upon evaporation and condensation such that dilute solutions incapable of explosion can form droplets in the headspace o ...
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Kingdom Of Italy
The Kingdom of Italy ( it, Regno d'Italia) was a state that existed from 1861, when Victor Emmanuel II of Kingdom of Sardinia, Sardinia was proclamation of the Kingdom of Italy, proclaimed King of Italy, until 1946, when civil discontent led to an 1946 Italian institutional referendum, institutional referendum to abandon the monarchy and form the modern Italy, Italian Republic. The state resulted from a decades-long process, the ''Italian unification, Risorgimento'', of consolidating the different states of the Italian Peninsula into a single state. That process was influenced by the House of Savoy, Savoy-led Kingdom of Sardinia, which can be considered Italy's legal Succession of states, predecessor state. Italy Third Italian War of Independence, declared war on Austrian Empire, Austria in alliance with Kingdom of Prussia, Prussia in 1866 and received the region of Veneto following their victory. Italian troops Capture of Rome, entered Rome in 1870, ending Papal States, more tha ...
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Adolf Von Baeyer
Johann Friedrich Wilhelm Adolf von Baeyer (; 31 October 1835 – 20 August 1917) was a German chemist who synthesised indigo and developed a nomenclature for cyclic compounds (that was subsequently extended and adopted as part of the IUPAC organic nomenclature). He was ennobled in the Kingdom of Bavaria in 1885 and was the 1905 recipient of the Nobel Prize in Chemistry.''Adolf von Baeyer: Winner of the Nobel Prize for Chemistry 1905 '' Armin de Meijere Angewandte Chemie International Edition Volume 44, Issue 48, Pages 7836 – 7840 2005''Abstract/ref> Family and education Baeyer was born in Berlin as the son of the noted geodesist and captain of the Royal Prussian Army Johann Jacob Baeyer and his wife Eugenie Baeyer née Hitzig (1807–1843). Both his parents were Lutherans at the time of his birth and he was raised in the Lutheran religion. His mother was the daughter of Julius Eduard Hitzig and a member of the originally Jewish Itzig family, and had converted to Christianity ...
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