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Julius Bredt
Julius Bredt (March 29, 1855 – September 21, 1937) was a German organic chemist. He was the first to determine, in 1893, the correct structure of camphor. Bredt also discovered that a double bond cannot be placed at the bridgehead of a bridged ring system, a statement now known as Bredt's rule Bredt's rule is an empirical observation in organic chemistry that states that a double bond cannot be placed at the bridgehead of a bridged ring system, unless the rings are large enough. The rule is named after Julius Bredt, who first discussed .... Awards There is a Julius Bredt lecture in his remembrance at the RWTH Aachen University. Further reading * References 1855 births 1937 deaths 19th-century German chemists Organic chemists 20th-century German chemists Scientists from Berlin RWTH Aachen University faculty {{Germany-chemist-stub ...
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Berlin
Berlin ( , ) is the capital and largest city of Germany by both area and population. Its 3.7 million inhabitants make it the European Union's most populous city, according to population within city limits. One of Germany's sixteen constituent states, Berlin is surrounded by the State of Brandenburg and contiguous with Potsdam, Brandenburg's capital. Berlin's urban area, which has a population of around 4.5 million, is the second most populous urban area in Germany after the Ruhr. The Berlin-Brandenburg capital region has around 6.2 million inhabitants and is Germany's third-largest metropolitan region after the Rhine-Ruhr and Rhine-Main regions. Berlin straddles the banks of the Spree, which flows into the Havel (a tributary of the Elbe) in the western borough of Spandau. Among the city's main topographical features are the many lakes in the western and southeastern boroughs formed by the Spree, Havel and Dahme, the largest of which is Lake Müggelsee. Due to its l ...
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RWTH Aachen University
RWTH Aachen University (), also known as North Rhine-Westphalia Technical University of Aachen, Rhine-Westphalia Technical University of Aachen, Technical University of Aachen, University of Aachen, or ''Rheinisch-Westfälische Technische Hochschule Aachen'', is a German public research university located in Aachen, North Rhine-Westphalia, Germany. With more than 47,000 students enrolled in 144 study programs, it is the largest technical university in Germany. In 2018, the university was ranked 31st in the world university rankings in the field of engineering and technology, and 36th world-wide in the category of natural sciences.Daten & Fakten – RWTH AACHEN UNIVERSITY – Deutsch
Rwth-aachen.de (12 December 2011). Retrieved on 2013-09-18.

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Organic Chemists
Organic may refer to: * Organic, of or relating to an organism, a living entity * Organic, of or relating to an anatomical organ Chemistry * Organic matter, matter that has come from a once-living organism, is capable of decay or is the product of decay, or is composed of organic compounds * Organic compound, a compound that contains carbon ** Organic chemistry, chemistry involving organic compounds Farming, certification and products * Organic farming, agriculture conducted according to certain standards, especially the use of stated methods of fertilization and pest control * Organic certification, accreditation process for producers of organically-farmed products * Organic horticulture, the science and art of growing fruits, vegetables, flowers, or ornamental plants by following the essential principles of organic agriculture * Organic products, "organics": ** Organic food, food produced from organic farming methods and often certified organic according to organic farming sta ...
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19th-century German Chemists
The 19th (nineteenth) century began on 1 January 1801 ( MDCCCI), and ended on 31 December 1900 ( MCM). The 19th century was the ninth century of the 2nd millennium. The 19th century was characterized by vast social upheaval. Slavery was abolished in much of Europe and the Americas. The First Industrial Revolution, though it began in the late 18th century, expanding beyond its British homeland for the first time during this century, particularly remaking the economies and societies of the Low Countries, the Rhineland, Northern Italy, and the Northeastern United States. A few decades later, the Second Industrial Revolution led to ever more massive urbanization and much higher levels of productivity, profit, and prosperity, a pattern that continued into the 20th century. The Gunpowder empires, Islamic gunpowder empires fell into decline and European imperialism brought much of South Asia, Southeast Asia, and almost all of Africa under Colonialism, colonial rule. It was also marked ...
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1937 Deaths
Events January * January 1 – Anastasio Somoza García becomes President of Nicaragua. * January 5 – Water levels begin to rise in the Ohio River in the United States, leading to the Ohio River flood of 1937, which continues into February, leaving 1 million people homeless and 385 people dead. * January 15 – Spanish Civil War: Second Battle of the Corunna Road ends inconclusively. * January 20 – Second inauguration of Franklin D. Roosevelt: Franklin D. Roosevelt is sworn in for a second term as President of the United States. This is the first time that the United States presidential inauguration occurs on this date; the change is due to the ratification in 1933 of the Twentieth Amendment to the United States Constitution. * January 23 – Moscow Trials: Trial of the Anti-Soviet Trotskyist Center – In the Soviet Union 17 leading Communists go on trial, accused of participating in a plot led by Leon Trotsky to overthrow Joseph Stalin's regime, and assa ...
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1855 Births
Events January–March * January 1 – Ottawa, Ontario, is incorporated as a city. * January 5 – Ramón Castilla begins his third term as President of Peru. * January 23 ** The first bridge over the Mississippi River opens in modern-day Minneapolis, a predecessor of the Father Louis Hennepin Bridge. ** The 8.2–8.3 Wairarapa earthquake claims between five and nine lives near the Cook Strait area of New Zealand. * January 26 – The Point No Point Treaty is signed in the Washington Territory. * January 27 – The Panama Railway becomes the first railroad to connect the Atlantic and Pacific Oceans. * January 29 – Lord Aberdeen resigns as Prime Minister of the United Kingdom, over the management of the Crimean War. * February 5 – Lord Palmerston becomes Prime Minister of the United Kingdom. * February 11 – Kassa Hailu is crowned Tewodros II, Emperor of Ethiopia. * February 12 – Michigan State University (the "pioneer" l ...
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George B
George may refer to: People * George (given name) * George (surname) * George (singer), American-Canadian singer George Nozuka, known by the mononym George * George Washington, First President of the United States * George W. Bush, 43rd President of the United States * George H. W. Bush, 41st President of the United States * George V, King of Great Britain, Ireland, the British Dominions and Emperor of India from 1910-1936 * George VI, King of Great Britain, Ireland, the British Dominions and Emperor of India from 1936-1952 * Prince George of Wales * George Papagheorghe also known as Jorge / GEØRGE * George, stage name of Giorgio Moroder * George Harrison, an English musician and singer-songwriter Places South Africa * George, Western Cape ** George Airport United States * George, Iowa * George, Missouri * George, Washington * George County, Mississippi * George Air Force Base, a former U.S. Air Force base located in California Characters * George (Peppa Pig), a 2-year-old pig ...
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Bredt Distributor
Bredt is a surname of German origin. Among those bearing this surname we find: * Alice Verne-Bredt (1868-1958), English piano teacher, violinist and composer * Bertha McNamara Bredt (1853-1931), Australian socialist agitator, feminist, pamphleteer, bookseller * David S. Bredt (born 1964), American molecular neuroscientist * Ferdinand Max Bredt (1868-1921), German painter * Irene Sänger-Bredt (1911-1983), German engineer, mathematician and physicist * Johann Viktor Bredt (1879-1940), German Weimar era justice minister * Julius Bredt Julius Bredt (March 29, 1855 – September 21, 1937) was a German organic chemist. He was the first to determine, in 1893, the correct structure of camphor. Bredt also discovered that a double bond cannot be placed at the bridgehead of a brid ... (1855-1937), German organic chemist {{surname Surnames of German origin German-language surnames ...
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Germany
Germany,, officially the Federal Republic of Germany, is a country in Central Europe. It is the second most populous country in Europe after Russia, and the most populous member state of the European Union. Germany is situated between the Baltic and North seas to the north, and the Alps to the south; it covers an area of , with a population of almost 84 million within its 16 constituent states. Germany borders Denmark to the north, Poland and the Czech Republic to the east, Austria and Switzerland to the south, and France, Luxembourg, Belgium, and the Netherlands to the west. The nation's capital and most populous city is Berlin and its financial centre is Frankfurt; the largest urban area is the Ruhr. Various Germanic tribes have inhabited the northern parts of modern Germany since classical antiquity. A region named Germania was documented before AD 100. In 962, the Kingdom of Germany formed the bulk of the Holy Roman Empire. During the 16th ce ...
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Camphor
Camphor () is a waxy, colorless solid with a strong aroma. It is classified as a terpenoid and a cyclic ketone. It is found in the wood of the camphor laurel ('' Cinnamomum camphora''), a large evergreen tree found in East Asia; and in the kapur tree ( ''Dryobalanops'' sp.), a tall timber tree from South East Asia. It also occurs in some other related trees in the laurel family, notably '' Ocotea usambarensis''. Rosemary leaves (''Rosmarinus officinalis'') contain 0.05 to 0.5% camphor, while camphorweed (''Heterotheca'') contains some 5%. A major source of camphor in Asia is camphor basil (the parent of African blue basil). Camphor can also be synthetically produced from oil of turpentine. The compound is chiral, existing in two possible enantiomers as shown in the structural diagrams. The structure on the left is the naturally occurring (+)-camphor ((1''R'',4''R'')-bornan-2-one), while its mirror image shown on the right is the (−)-camphor ((1''S'',4''S'')-bornan-2-one). ...
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Bredt's Rule
Bredt's rule is an empirical observation in organic chemistry that states that a double bond cannot be placed at the bridgehead of a bridged ring system, unless the rings are large enough. The rule is named after Julius Bredt, who first discussed it in 1902 and codified it in 1924. It primarily relates to bridgeheads with carbon-carbon and carbon-nitrogen double bonds. For example, two of the following isomers of norbornene violate Bredt's rule, which makes them too unstable to prepare: In the figure, the bridgehead atoms involved in Bredt's rule violation are highlighted in red. Bredt's rule is a consequence of the fact that having a double bond on a bridgehead, carbons from which three bonds radiate and which the rings share a single covalent bond, would be equivalent to having a trans double bond on a ring, which is not stable for small rings (fewer than eight atoms) due to a combination of ring strain, and angle strain (nonplanar alkene). The p orbitals of the bridgehead ...
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