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Camphor
Camphor () is a waxy, colorless solid with a strong aroma. It is classified as a terpenoid and a cyclic ketone. It is found in the wood of the camphor laurel ('' Cinnamomum camphora''), a large evergreen tree found in East Asia; and in the kapur tree ( ''Dryobalanops'' sp.), a tall timber tree from South East Asia. It also occurs in some other related trees in the laurel family, notably '' Ocotea usambarensis''. Rosemary leaves ('' Rosmarinus officinalis'') contain 0.05 to 0.5% camphor, while camphorweed ('' Heterotheca'') contains some 5%. A major source of camphor in Asia is camphor basil (the parent of African blue basil). Camphor can also be synthetically produced from oil of turpentine. The compound is chiral, existing in two possible enantiomers as shown in the structural diagrams. The structure on the left is the naturally occurring (+)-camphor ((1''R'',4''R'')-bornan-2-one), while its mirror image shown on the right is the (−)-camphor ((1''S'',4''S'')-bornan-2-o ...
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Cinnamomum Camphora
''Camphora officinarum'' is a species of evergreen tree that is commonly known under the names camphor tree, camphorwood or camphor laurel. Description ''Camphora officinarum'' is native to China south of the Yangtze River, Taiwan, southern Japan, Korea, India and Vietnam, and has been introduced to many other countries. It grows up to tall. In Japan, where the tree is called ''kusunoki'', five camphor trees are known with a trunk circumference above , with the largest individual, , reaching 24.22 m. The leaves have a glossy, waxy appearance and smell of camphor when crushed. In spring, it produces bright green foliage with masses of small white flowers. It produces clusters of black, berry-like fruit around in diameter. Its pale bark is very rough and fissured vertically. Certain trees in Japan are considered sacred. An example of the importance of a sacred tree is the 700-year old camphor growing in the middle of Kayashima Station. Locals protested against movin ...
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Borneol
Borneol is a bicyclic organic compound and a terpene derivative. The hydroxyl group in this compound is placed in an '' endo'' position. The exo diastereomer is called isoborneol. Being chiral, borneol exists as enantiomers, both of which are found in nature. Reactions Borneol is oxidized to the ketone (camphor). Occurrence The compound was named in 1842 by the French chemist Charles Frédéric Gerhardt. Borneol can be found in several species of ''Heterotheca'', '' Artemisia'', ''Rosmarinus officinalis'' (rosemary) '' Dipterocarpaceae'', '' Blumea balsamifera'' and '' Kaempferia galanga''. It is one of the chemical compounds found in castoreum. This compound is gathered from the beaver's plant food. Synthesis Borneol can be synthesized by reduction of camphor by the Meerwein–Ponndorf–Verley reduction (a reversible process). Reduction of camphor with sodium borohydride (fast and irreversible) gives instead the diastereomer isoborneol. : Uses Whereas ''d''-borneo ...
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Dryobalanops Aromatica
''Dryobalanops aromatica'', commonly known as Borneo camphor, camphor tree, Malay camphor, or Sumatran camphor, is a species of critically endangered plant in the family Dipterocarpaceae. The species name ''aromatica'' is derived from Latin (''aromaticus'' meaning spice-like) and refers to the smell of the dammar (resin). This species was one of the main sources of camphor and attracted early Arab traders to Borneo, at that time being worth more than gold, and used for incense and perfumes. It is found in Sumatra, peninsular Malaysia, and Borneo. It is a large emergent tree, up to 65 m or even 75 m tall, found in mixed dipterocarp forests on deep humic yellow sandy soils. It is a heavy hardwood sold under the trade names of Kapur. It is recorded from at least two protected areas ( Lambir and Gunung Mulu National Parks). Bergenin, malaysianol A, laevifonol, ampelopsin E, α-viniferin, ε-viniferin and diptoindonesin A can be isolated from the stem bark of ''D. aromatica ...
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Barus
Barus is a town and '' kecamatan'' (district) in Central Tapanuli Regency, North Sumatra Province, Sumatra, Indonesia. Historically, Barus was well known as a port town or kingdom on the western coast of Sumatra where it was a regional trade center from around the 7th or earlier until the 17th century. It was also known by other names, namely Fansur and possibly Barusai. The name Fansur or Pansur means "spring of water" in the local Batak language. Barus was well known for its produce camphor. In the 16th century, Barus came under attack from the rising power of Aceh, and became absorbed into the Aceh Sultanate. The earliest known Malay poet Hamzah Fansuri may be from Barus as indicated by his name. Historical records Barus was a significant settlement on the west coast of Sumatra widely recorded in many historical documents. Other related sites in Sumatra includes Lamuri in Aceh and Pannai in North Sumatra. The second century Greek geographer Claudius Ptolemy in his ...
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African Blue Basil
African blue basil ('' Ocimum kilimandscharicum'' × ''basilicum'' ' Dark Opal') is a hybrid basil variety, a cross between camphor basil and dark opal basil. It is one of a few types of basil that are perennial. African blue basil plants are sterile, unable to produce seeds of their own, and can only be propagated by cuttings. This particular breed of basil has a strong camphor scent, inherited from ''Ocimum kilimandscharicum'' (camphor basil), Gives as its source '' Econ Bot'' 28:63 (1974). its East African parent. The concentration of camphor is 22% (compared with 61% for ''O. kilimandscharicum''). The concentration of the other major aroma compounds, linalool (55%), and 1,8-cineole (15%) is comparable to many basil cultivars."Basil: A Source of Aroma Compounds and a Popular Culinary and Ornamental Herb" reprinted from: ''Perspectives on new crops and new uses'' (1999), ASHS Press, Alexandria, VA, . All parts of the flower, leaves and stems are edible; although some migh ...
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Heterotheca
''Heterotheca'', (common names goldenasters, camphorweed, or telegraph weed) are North American plants in the family Asteraceae. Etymology ''Heterotheca'' comes from Ancient Greek "other, different" and "case, chest", and refers to the fact that, in some species in the genus, the cypselae ( achenes containing seed) of the disk and ray florets have different shapes. Description, biology These are annual and perennial herbs bearing daisy-like flower heads with yellow disc florets and usually yellow ray florets, associated with mesic to xeric habitats across North America. Several species now included in ''Heterotheca'' were previously classified in the genus '' Chrysopsis'' ''Heterotheca'' species are often used as food plants by the larvae of some Lepidoptera species including '' Schinia lynx'', ''Schinia nubila'' and '' Schinia saturata'' (all of which have been recorded on ''Heterotheca subaxillaris''). Chemistry The leaf volatiles from which the name "camphorweed" ...
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Camphorsulfonic Acid
Camphorsulfonic acid, sometimes abbreviated CSA or 10-CSA is an organosulfur compound. Like typical sulfonic acids, it is a relatively strong acid that is a colorless solid at room temperature and is soluble in water and a wide variety of organic substances. This compound is commercially available. It can be prepared by sulfonation of camphor with sulfuric acid and acetic anhydride: : Although this reaction appears to be a sulfonation of an unactivated methyl group, the actual mechanism is believed to involve a retro- semipinacol rearrangement, deprotonation next to the tertiary carbocation to form an alkene, sulfonation of the alkene intermediate, and finally, semipinacol rearrangement to re-establish the ketone function. In organic synthesis, CSA and its derivatives can be used as resolving agents for chiral amines and other cations. The synthesis of osanetant was an example of this. 3-bromocamphor-8-sulfonic acid was used in the synthesis of enantiopure devazepide. Ca ...
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Lauraceae
Lauraceae, or the laurels, is a plant family that includes the true laurel and its closest relatives. This family comprises about 2850 known species in about 45 genera worldwide (Christenhusz & Byng 2016 ). They are dicotyledons, and occur mainly in warm temperate and tropical regions, especially Southeast Asia and South America. Many are aromatic evergreen trees or shrubs, but some, such as ''Sassafras'', are deciduous, or include both deciduous and evergreen trees and shrubs, especially in tropical and temperate climates. The genus '' Cassytha'' is unique in the Lauraceae in that its members are parasitic vines. Most laurels are highly-poisonous. Overview The family has a worldwide distribution in tropical and warm climates. The Lauraceae are important components of tropical forests ranging from low-lying to montane. In several forested regions, Lauraceae are among the top five families in terms of the number of species present. The Lauraceae give their name to habitats ...
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Rosmarinus Officinalis
''Salvia rosmarinus'' (), commonly known as rosemary, is a shrub with fragrant, evergreen, needle-like leaves and white, pink, purple, or blue flowers, native to the Mediterranean region. Until 2017, it was known by the scientific name ''Rosmarinus officinalis'' (), now a synonym. It is a member of the sage family Lamiaceae, which includes many other medicinal and culinary herbs. The name "rosemary" derives from Latin ("dew of the sea"). Rosemary has a fibrous root system. Description Rosemary is an aromatic evergreen shrub with leaves similar to hemlock needles. It is native to the Mediterranean and Asia, but is reasonably hardy in cool climates. Special cultivars like 'Arp' can withstand winter temperatures down to about . It can withstand droughts, surviving a severe lack of water for lengthy periods. In some parts of the world, it is considered a potentially invasive species. The seeds are often difficult to start, with a low germination rate and relatively slow growth, ...
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Ocotea Usambarensis
''Ocotea usambarensis'' is a species of '' Ocotea'' (family Lauraceae), native to eastern Africa in Kenya, Tanga Region of Tanzania, and locally in Uganda, where it occurs at 1600–2600 m altitude in high rainfall montane cloud forest. Common names include East African camphorwood, mkulo (Tanzania), mwiha (Uganda), muwong, muzaiti, and maasi. It is a large evergreen tree growing to 35 m (exceptionally 45 m) tall, with fast growth (up to 2 m per year) when young. The leaves are opposite (sometimes alternate on fast-growing stems), elliptic to oval, 4–16 cm long and 2.5–9 cm wide, dark green above, pale below, with an entire margin and an acuminate apex. The foliage has a distinct scent of camphor. The flowers are inconspicuous, greenish-yellow; the fruit is a small drupe In botany, a drupe (or stone fruit) is an indehiscent fruit in which an outer fleshy part (exocarp, or skin, and mesocarp, or flesh) surrounds a single shell (the ''pit'', ''stone'', o ...
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Rosemary
''Salvia rosmarinus'' (), commonly known as rosemary, is a shrub with fragrant, evergreen, needle-like leaves and white, pink, purple, or blue flowers, native to the Mediterranean region. Until 2017, it was known by the scientific name ''Rosmarinus officinalis'' (), now a synonym. It is a member of the sage family Lamiaceae, which includes many other medicinal and culinary herbs. The name "rosemary" derives from Latin ("dew of the sea"). Rosemary has a fibrous root system. Description Rosemary is an aromatic evergreen shrub with leaves similar to hemlock needles. It is native to the Mediterranean and Asia, but is reasonably hardy in cool climates. Special cultivars like 'Arp' can withstand winter temperatures down to about . It can withstand droughts, surviving a severe lack of water for lengthy periods. In some parts of the world, it is considered a potentially invasive species. The seeds are often difficult to start, with a low germination rate and relatively slow grow ...
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Turpentine
Turpentine (which is also called spirit of turpentine, oil of turpentine, terebenthene, terebinthine and (colloquially) turps) is a fluid obtained by the distillation of resin harvested from living trees, mainly pines. Mainly used as a specialized solvent, it is also a source of material for organic syntheses. Turpentine is composed of terpenes, primarily the monoterpenes alpha- and beta-pinene, with lesser amounts of carene, camphene, dipentene, and terpinolene.Kent, James A. ''Riegel's Handbook of Industrial Chemistry'' (Eighth Edition) Van Nostrand Reinhold Company (1983) p.569 Mineral turpentine or other petroleum distillates are used to replace turpentine – although the constituent chemicals are very different. Etymology The word ''turpentine'' derives (via French and Latin), from the Greek word τερεβινθίνη ''terebinthine'', in turn the feminine form (to conform to the feminine gender of the Greek word, which means "resin") of an adjective (τερ ...
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