Topic summary

Tetramethylsilane

Tetramethylsilane
Names Preferred IUPAC name
Tetramethylsilane
Identifiers
3D model (JSmol)
Abbreviations TMS 1696908 ChEBIChEMBLChemSpiderECHA InfoCard100.000.818EC Number
  • 200-899-1
MeSHTetramethylsilaneRTECS number
  • VV5705400
UNIIUN number2749
  • InChI=1S/C4H12Si/c1-5(2,3)4/h1-4H3
    Key: CZDYPVPMEAXLPK-UHFFFAOYSA-N
  • C[Si](C)(C)C
Properties C4H12SiMolar mass88.225 g·mol Appearance Colourless liquid Density0.648 g cm Melting point−99 to −102 °C (−146 to −152 °F; 174 to 171 K) Boiling point26 to 28 °C (79 to 82 °F; 299 to 301 K) Solubilityorganic solvents Structure Tetrahedral at carbon and silicon 0 D Hazards GHS labelling: DangerH224, H302, H411P210, P233, P240, P241, P242, P243, P264, P270, P273, P280, P301+P312, P303+P361+P353, P330, P370+P378, P391, P403+P235, P501NFPA 704 (fire diamond) Flash point−28 to −27 °C (–18 to –16 °F), vapor may be pyrophoric Related compounds
Related silanes
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Tetramethylsilane (abbreviated as TMS) is the organosilicon compound with the formula Si(CH3)4. It is a colorless liquid. It is the simplest tetraorganosilane. Like all silanes, the TMS framework is tetrahedral. TMS is a building block in organometallic chemistry but also finds use in diverse niche applications.