Strontianite (
Sr C O3) is an important raw material for the extraction of
strontium
Strontium is the chemical element with the symbol Sr and atomic number 38. An alkaline earth metal, strontium is a soft silver-white yellowish metallic element that is highly chemically reactive. The metal forms a dark oxide layer when it is ...
. It is a rare
carbonate mineral
Carbonate minerals are those minerals containing the carbonate ion, .
Carbonate divisions Anhydrous carbonates
*Calcite group: trigonal
** Calcite CaCO3
** Gaspéite (Ni,Mg,Fe2+)CO3
**Magnesite MgCO3
** Otavite CdCO3
** Rhodochrosite MnCO3
* ...
and one of only a few strontium minerals. It is a member of the aragonite group.
Aragonite group members:
[ ]aragonite
Aragonite is a carbonate mineral, one of the three most common naturally occurring crystal forms of calcium carbonate, (the other forms being the minerals calcite and vaterite). It is formed by biological and physical processes, including pre ...
(CaCO3), witherite (BaCO3), strontianite (SrCO3), cerussite (PbCO3)
The ideal formula of strontianite is SrCO3, with molar mass
In chemistry, the molar mass of a chemical compound is defined as the mass of a sample of that compound divided by the amount of substance which is the number of moles in that sample, measured in moles. The molar mass is a bulk, not molecula ...
147.63 g,[ but ]calcium
Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar t ...
(Ca) can substitute for up to 27% of the strontium (Sr) cations, and barium (Ba) up to 3.3%.[
The mineral was named in 1791 for the locality, Strontian, Argyllshire, Scotland, where the element ]strontium
Strontium is the chemical element with the symbol Sr and atomic number 38. An alkaline earth metal, strontium is a soft silver-white yellowish metallic element that is highly chemically reactive. The metal forms a dark oxide layer when it is ...
had been discovered the previous year.[ Although good mineral specimens of strontianite are rare, strontium is a fairly common element, with abundance in the ]Earth's crust
Earth's crust is Earth's thin outer shell of rock, referring to less than 1% of Earth's radius and volume. It is the top component of the lithosphere, a division of Earth's layers that includes the crust and the upper part of the mantle. The ...
of 370 parts per million by weight, 87 parts per million by moles, much more common than copper
Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish ...
with only 60 parts per million by weight, 19 by moles.
Strontium is never found free in nature. The principal strontium ores are celestine SrSO4 and strontianite SrCO3. The main commercial process for strontium metal production is reduction of strontium oxide with aluminium
Aluminium (aluminum in AmE, American and CanE, Canadian English) is a chemical element with the Symbol (chemistry), symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately o ...
.[
]
Unit cell
Strontianite is an orthorhombic
In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic lattices result from stretching a cubic lattice along two of its orthogonal pairs by two different factors, resulting in a rectangular prism with ...
mineral, belonging to the most symmetrical class in this system, 2/m 2/m 2/m, whose general form is a rhombic
Rhombic may refer to:
* Rhombus, a quadrilateral whose four sides all have the same length (often called a diamond)
*Rhombic antenna, a broadband directional antenna most commonly used on shortwave frequencies
* polyhedra formed from rhombuses, suc ...
dipyramid
A (symmetric) -gonal bipyramid or dipyramid is a polyhedron formed by joining an -gonal pyramid and its mirror image base-to-base. An -gonal bipyramid has triangle faces, edges, and vertices.
The "-gonal" in the name of a bipyramid does not ...
. The space group
In mathematics, physics and chemistry, a space group is the symmetry group of an object in space, usually in three dimensions. The elements of a space group (its symmetry operations) are the rigid transformations of an object that leave it ...
is Pmcn. There are four formula units per unit cell
In geometry, biology, mineralogy and solid state physics, a unit cell is a repeating unit formed by the vectors spanning the points of a lattice. Despite its suggestive name, the unit cell (unlike a unit vector, for example) does not necessari ...
(Z = 4) and the unit cell parameters are a = 5.1 Å, b = 8.4 Å, c = 6.0 Å.
Structure
Strontianite is isostructural with aragonite
Aragonite is a carbonate mineral, one of the three most common naturally occurring crystal forms of calcium carbonate, (the other forms being the minerals calcite and vaterite). It is formed by biological and physical processes, including pre ...
.[Klein and Hurlbut (1993) Manual of Mineralogy 21st Edition. Wiley] When the CO3 group is combined with large divalent
In chemistry, the valence (US spelling) or valency (British spelling) of an element is the measure of its combining capacity with other atoms when it forms chemical compounds or molecules.
Description
The combining capacity, or affinity of a ...
cations with ionic radii greater than 1.0 Å, the radius ratios generally do not permit stable 6-fold coordination. For small cations the structure is rhombohedral
In geometry, a rhombohedron (also called a rhombic hexahedron or, inaccurately, a rhomboid) is a three-dimensional figure with six faces which are rhombi. It is a special case of a parallelepiped where all edges are the same length. It can be use ...
, but for large cations it is orthorhombic
In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic lattices result from stretching a cubic lattice along two of its orthogonal pairs by two different factors, resulting in a rectangular prism with ...
. This is the aragonite structure type with space group
In mathematics, physics and chemistry, a space group is the symmetry group of an object in space, usually in three dimensions. The elements of a space group (its symmetry operations) are the rigid transformations of an object that leave it ...
Pmcn. In this structure the CO3 groups lie perpendicular to the c axis, in two structural planes, with the CO3 triangular groups of one plane pointing in opposite directions to those of the other.[ These layers are separated by layers of cations.][
The CO3 group is slightly non-planar; the ]carbon
Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent—its atom making four electrons available to form covalent chemical bonds. It belongs to group 14 of the periodic table. Carbon makes ...
atom
Every atom is composed of a nucleus and one or more electrons bound to the nucleus. The nucleus is made of one or more protons and a number of neutrons. Only the most common variety of hydrogen has no neutrons.
Every solid, liquid, gas ...
lies 0.007 Å out of the plane of the oxygen
Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as we ...
atoms. The groups are tilted such that the angle between a plane drawn through the oxygen atoms and a plane parallel to the a-b unit cell plane is 2°40’.[De Villiers, Johan P R (1971) Crystal Structures of Aragonite, Strontianite and Witherite. The American Mineralogist 56:758]
Crystal form
Strontianite occurs in several different habits. Crystals are short prismatic
An optical prism is a transparent optical element with flat, polished surfaces that are designed to refract light. At least one surface must be angled — elements with two parallel surfaces are ''not'' prisms. The most familiar type of opti ...
parallel to the c axis and often acicular.[ ]Calcium
Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar t ...
-rich varieties often show steep pyramidal
A pyramid (from el, πυραμίς ') is a structure whose outer surfaces are triangular and converge to a single step at the top, making the shape roughly a pyramid in the geometric sense. The base of a pyramid can be trilateral, quadrilate ...
forms.[ Crystals may be pseudo ]hexagon
In geometry, a hexagon (from Greek , , meaning "six", and , , meaning "corner, angle") is a six-sided polygon. The total of the internal angles of any simple (non-self-intersecting) hexagon is 720°.
Regular hexagon
A ''regular hexagon'' h ...
al[ due to equal development of different forms.][ Prism faces are striated horizontally.][ The mineral also occurs as columnar to fibrous, granular or rounded masses.][
]
Optical properties
Strontianite is colourless, white, gray, light yellow, green or brown, colourless in transmitted light. It may be longitudinally zoned. It is transparent to translucent, with a vitreous (glassy) lustre, resinous on broken surfaces, and a white streak.
It is a biaxial(-) mineral. The direction perpendicular to the plane containing the two optic axes is called the optical direction Y. In strontianite Y is parallel to the b crystal axis. The optical direction Z lies in the plane containing the two optic axes and bisects the acute angle between them. In strontianite Z is parallel to the a crystal axis. The third direction X, perpendicular both to Y and to Z, is parallel to the c crystal axis.[ The refractive indices are close to nα = 1.52, nβ = 1.66, nγ = 1.67, with different sources quoting slightly different values:
*nα = 1.520, nβ = 1.667, nγ = 1.669][
*nα = 1.516 – 1.520, nβ = 1.664 – 1.667, nγ = 1.666 – 1.668][
*nα = 1.517, nβ = 1.663, nγ = 1.667 (synthetic material)][Speer, J A and Hensley-Dunn, M L (1976) Strontianite composition and physical properties. American Mineralogist 61:1001–1004]
The maximum birefringence
Birefringence is the optical property of a material having a refractive index that depends on the polarization and propagation direction of light. These optically anisotropic materials are said to be birefringent (or birefractive). The birefrin ...
δ is 0.15[ and the measured value of 2V is 7°, calculated 12° to 8°.][
If the colour of the incident light is changed, then the refractive indices are modified, and the value of 2V changes. This is known as dispersion of the optic axes. For strontianite the effect is weak, with 2V larger for violet light than for red light r < v.][
]
Luminescence
Strontianite is almost always fluorescent
Fluorescence is the emission of light by a substance that has absorbed light or other electromagnetic radiation. It is a form of luminescence. In most cases, the emitted light has a longer wavelength, and therefore a lower photon energy, th ...
.[ It fluoresces bright yellowish white under shortwave, mediumwave and longwave ]ultraviolet
Ultraviolet (UV) is a form of electromagnetic radiation with wavelength from 10 nm (with a corresponding frequency around 30 PHz) to 400 nm (750 THz), shorter than that of visible light, but longer than X-rays. UV radiati ...
radiation. If the luminescence persists after the ultraviolet source is switched off the sample is said to be phosphorescent. Most strontianite phosphoresces a strong, medium duration, yellowish white after exposure to all three wavelengths.[The Mineralogical Record (2006) 37-1:44] It is also fluorescent and phosphorescent in X-rays
X-rays (or rarely, ''X-radiation'') are a form of high-energy electromagnetic radiation. In many languages, it is referred to as Röntgen radiation, after the German scientist Wilhelm Conrad Röntgen, who discovered it in 1895 and named it ' ...
and electron beams. All materials will glow red hot if they are heated to a high enough temperature (provided they do not decompose first); some materials become luminescent at much lower temperatures, and this is known as thermoluminescence
Thermoluminescence is a form of luminescence that is exhibited by certain crystalline materials, such as some minerals, when previously absorbed energy from electromagnetic radiation or other ionizing radiation is re-emitted as light upon h ...
. Strontianite is sometimes thermoluminescent.[
]
Physical properties
Cleavage is nearly perfect parallel to one set of prism faces, , and poor on . Traces of cleavage have been observed on .[
Twinning is very common, with twin plane . The twins are usually contact twins; in a contact twin the two individuals appear to be reflections of each other in the twin plane. Penetration twins of strontainite are rarer; penetration twins are made up of interpenetrating individuals that are related to each other by rotation about a twin axis. Repeated twins are made up of three or more individuals twinned according to the same law. If all the twin planes are parallel then the twin is polysynthetic, otherwise it is cyclic.][ In strontianite repeated twinning forms cyclic twins with three or four individuals, or polysynthetic twins.][
The mineral is brittle, and breaks with a subconchoidal to uneven fracture. It is quite soft, with a ]Mohs hardness
The Mohs scale of mineral hardness () is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material.
The scale was introduced in 1812 by the ...
of ,[ between ]calcite
Calcite is a carbonate mineral and the most stable polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on the Mohs scale of mineral hardness, based on scra ...
and fluorite
Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon.
The Mohs sca ...
. The specific gravity
Relative density, or specific gravity, is the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for liquids is nearly always measured with respect to water (molecule), wa ...
of the pure endmember
An endmember (also end-member or end member) in mineralogy is a mineral that is at the extreme end of a mineral series in terms of purity of its chemical composition. Minerals often can be described as solid solutions with varying compositions of ...
with no calcium substituting for strontium is 3.78,[ but most samples contain some calcium, which is lighter than strontium, giving a lower specific gravity, in the range 3.74 to 3.78.][ Substitutions of the heavier ions barium and/or ]lead
Lead is a chemical element with the Symbol (chemistry), symbol Pb (from the Latin ) and atomic number 82. It is a heavy metals, heavy metal that is density, denser than most common materials. Lead is Mohs scale of mineral hardness#Intermediate ...
increase the specific gravity, although such substitutions are never very abundant.[ Strontianite is soluble in dilute ]hydrochloric acid
Hydrochloric acid, also known as muriatic acid, is an aqueous solution of hydrogen chloride. It is a colorless solution with a distinctive pungent smell. It is classified as a strong acid. It is a component of the gastric acid in the dig ...
HCl[ and it is not ]radioactive
Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is consi ...
.[
]
Environment and associations
Strontianite is an uncommon low-temperature hydrothermal
Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...
mineral formed in veins
Veins are blood vessels in humans and most other animals that carry blood towards the heart. Most veins carry deoxygenated blood from the tissues back to the heart; exceptions are the pulmonary and umbilical veins, both of which carry oxygenated ...
in limestone
Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms wh ...
, marl, and chalk
Chalk is a soft, white, porous, sedimentary carbonate rock. It is a form of limestone composed of the mineral calcite and originally formed deep under the sea by the compression of microscopic plankton that had settled to the sea floor. Cha ...
, and in geode
A geode (; ) is a geological secondary formation within sedimentary and volcanic rocks. Geodes are hollow, vaguely spherical rocks, in which masses of mineral matter (which may include crystals) are secluded. The crystals are formed by the fil ...
s and concretions
A concretion is a hard, compact mass of matter formed by the precipitation of mineral cement within the spaces between particles, and is found in sedimentary rock or soil. Concretions are often ovoid or spherical in shape, although irregular ...
. It occurs rarely in hydrothermal metallic veins but is common in carbonatite
Carbonatite () is a type of intrusive or extrusive igneous rock defined by mineralogic composition consisting of greater than 50% carbonate minerals. Carbonatites may be confused with marble and may require geochemical verification.
Carbonatit ...
s.[ It most likely crystallises at or near 100 °C. Its occurrence in open vugs and veins suggests crystallisation at very low pressures, probably at most equal to the ]hydrostatic pressure
Fluid statics or hydrostatics is the branch of fluid mechanics that studies the condition of the equilibrium of a floating body and submerged body " fluids at hydrostatic equilibrium and the pressure in a fluid, or exerted by a fluid, on an i ...
of the ground water
Groundwater is the water present beneath Earth's surface in rock and soil pore spaces and in the fractures of rock formations. About 30 percent of all readily available freshwater in the world is groundwater. A unit of rock or an unconsolidat ...
.[ Under appropriate conditions it alters to celestine SrSO4, and it is itself found as an alteration from celestine.][ These two minerals are often found in association, together with ]baryte
Baryte, barite or barytes ( or ) is a mineral consisting of barium sulfate ( Ba S O4). Baryte is generally white or colorless, and is the main source of the element barium. The ''baryte group'' consists of baryte, celestine (strontium sulfate), ...
, calcite
Calcite is a carbonate mineral and the most stable polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on the Mohs scale of mineral hardness, based on scra ...
, harmotome and sulfur
Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formul ...
.[
]
Occurrences
Type locality
The type locality
Type locality may refer to:
* Type locality (biology)
* Type locality (geology)
See also
* Local (disambiguation)
* Locality (disambiguation)
{{disambiguation ...
is Strontian, North West Highlands (Argyllshire
Argyll (; archaically Argyle, in modern Gaelic, ), sometimes called Argyllshire, is a historic county and registration county of western Scotland.
Argyll is of ancient origin, and corresponds to most of the part of the ancient kingdom of ...
), Scotland
Scotland (, ) is a country that is part of the United Kingdom. Covering the northern third of the island of Great Britain, mainland Scotland has a border with England to the southeast and is otherwise surrounded by the Atlantic Ocean to th ...
, UK. The type material occurred in veins
Veins are blood vessels in humans and most other animals that carry blood towards the heart. Most veins carry deoxygenated blood from the tissues back to the heart; exceptions are the pulmonary and umbilical veins, both of which carry oxygenated ...
in gneiss
Gneiss ( ) is a common and widely distributed type of metamorphic rock. It is formed by high-temperature and high-pressure metamorphic processes acting on formations composed of igneous or sedimentary rocks. Gneiss forms at higher temperatures a ...
.[
Other UK localities include Brownley Hill Mine (Bloomsberry Horse Level), Nenthead, Alston Moor District, North Pennines, North and Western Region (Cumberland), Cumbria, England, associated with a suite of primary minerals ( bournonite, millerite and ullmannite) which are not common in other Mississippi Valley-type deposits.][The Mineralogical Record (2010) 41-1:62 supplement]
Canada
The Francon quarry, Montréal
Montreal ( ; officially Montréal, ) is the second-most populous city in Canada and most populous city in the Canadian province of Quebec. Founded in 1642 as '' Ville-Marie'', or "City of Mary", it is named after Mount Royal, the triple- ...
, Québec.
Strontianite is very common at the Francon Quarry, in a great variety of habits. It is a late stage mineral, sometimes found as multiple generations. It is found as translucent to opaque, white to pale yellow or beige generally smooth surfaced spheroids, hemispheres and compact spherical and botryoidal aggregate
Aggregate or aggregates may refer to:
Computing and mathematics
* collection of objects that are bound together by a root entity, otherwise known as an aggregate root. The aggregate root guarantees the consistency of changes being made within the ...
s to 10 cm in diameter, and as spheres consisting of numerous radiating acicular crystals, up to 1 cm across. Also as tufts, parallel bundles, and sheaf-like clusters of fibrous to acicular crystals, and as white, finely granular porcelaneous and waxy globular aggregates. Transparent, pale pink, columnar to tabular sixling twins up to 1 cm in diameter have been found, and aggregates of stacked stellate sixling twins consisting of transparent, pale yellow tabular crystals.[
Another Canadian occurrence is at Nepean, Ontario, in vein deposits in ]limestone
Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms wh ...
.[
]
Germany
Commercially important deposits occur in marls in Westphalia
Westphalia (; german: Westfalen ; nds, Westfalen ) is a region of northwestern Germany and one of the three historic parts of the state of North Rhine-Westphalia. It has an area of and 7.9 million inhabitants.
The territory of the regi ...
,[ and it is also found with ]zeolites
Zeolites are microporous, crystalline aluminosilicate materials commonly used as commercial adsorbents and catalysts. They mainly consist of silicon, aluminium, oxygen, and have the general formula ・y where is either a metal ion or H+. These ...
at Oberschaffhausen, Bötzingen, Kaiserstuhl, Baden-Württemberg.[
]
India
In Trichy
Tiruchirappalli () ( formerly Trichinopoly in English), also called Tiruchi or Trichy, is a major tier II city in the Indian state of Tamil Nadu and the administrative headquarters of Tiruchirappalli district. The city is credited with bei ...
(Tiruchirappalli; Tiruchi), Tiruchirapalli District, Tamil Nadu, it occurs with celestine SrSO4, gypsum
Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, blackboard or sidewalk chalk, and dr ...
and phosphate nodules in clay
Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4).
Clays develop plasticity when wet, due to a molecular film of water surrounding the clay part ...
.[
]
Mexico
It occurs in the Sierra Mojada
Sierra Mojada is a city and seat of the municipality of Sierra Mojada, in the north-eastern Mexican state of Coahuila. Local oral tradition, documented by the priest James Lienert, states that Ambrose Bierce, who disappeared without a trace in 1 ...
District, with celestine in a lead
Lead is a chemical element with the Symbol (chemistry), symbol Pb (from the Latin ) and atomic number 82. It is a heavy metals, heavy metal that is density, denser than most common materials. Lead is Mohs scale of mineral hardness#Intermediate ...
-silver
Silver is a chemical element with the Symbol (chemistry), symbol Ag (from the Latin ', derived from the Proto-Indo-European wikt:Reconstruction:Proto-Indo-European/h₂erǵ-, ''h₂erǵ'': "shiny" or "white") and atomic number 47. A soft, whi ...
deposit.[
]
Russia
It occurs in the Kirovskii apatite
Apatite is a group of phosphate minerals, usually hydroxyapatite, fluorapatite and chlorapatite, with high concentrations of OH−, F− and Cl− ions, respectively, in the crystal. The formula of the admixture of the three most common ...
mine, Kukisvumchorr Mt, Khibiny Massif, Kola Peninsula
sjd, Куэлнэгк нёа̄ррк
, image_name= Kola peninsula.png
, image_caption= Kola Peninsula as a part of Murmansk Oblast
, image_size= 300px
, image_alt=
, map_image= Murmansk in Russia.svg
, map_caption = Location of Murmansk Oblast ...
, Murmanskaja Oblast', Northern Region, in late hydrothermal assemblages in cavities in pegmatites, associated with kukharenkoite-(La), microcline, albite
Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula . It is a tectosilica ...
, calcite
Calcite is a carbonate mineral and the most stable polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on the Mohs scale of mineral hardness, based on scra ...
, nenadkevichite
Nenadkevichite is a rare silicate mineral containing niobium with the chemical formula . It forms brown to yellow to rose colored orthorhombic dipyramidal crystals with a dull to earthy luster. It has a Mohs hardness of 5 and a specific gravit ...
, hilairite, catapleiite
Catapleiite (•2) is a dimorph of Gaidonnayite rarely found by itself. Its name derives from the Greek words “κατα” (kata) and “πλειον” (pleion) meaning “with more” as it is mostly accompanied by a number of rare mineral ...
, donnayite-(Y)
Donnayite-(Y) is a rare-earth carbonate mineral containing the rare-earth metal yttrium. It was first discovered in 1978 at Mont Saint-Hilaire, Quebec. Donnayite was subsequently identified and named after Joseph D. H. Donnay and his wife, Gabri ...
, synchysite-(Ce), pyrite
The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Fe S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral.
Pyrite's metallic luster and pale brass-yellow hue giv ...
and others.[The Mineralogical Record (2004) 35-4:355]
It also occurs at Yukspor Mountain, Khibiny Massif, Kola Peninsula, Murmanskaja Oblast', Northern Region, in an aegerine-natrolite
Natrolite is a tectosilicate mineral species belonging to the zeolite group. It is a hydrated sodium and aluminium silicate with the formula . The type locality is Hohentwiel, Hegau, Germany.
It was named natrolite by Martin Heinrich Klap ...
- microcline vein in foyaite, associated with aegirine
Aegirine is a member of the clinopyroxene group of inosilicate minerals. Aegirine is the sodium endmember of the aegirine-augite series. Aegirine has the chemical formula Na Fe Si2 O6 in which the iron is present as Fe3+. In the aegirine-augite ...
, anatase
Anatase is a metastable mineral form of titanium dioxide (TiO2) with a tetragonal crystal structure. Although colorless or white when pure, anatase in nature is usually a black solid due to impurities. Three other polymorphs (or mineral forms ...
, ancylite-(Ce)
Ancylite is a group of hydrous strontium carbonate minerals containing cerium, lanthanum and minor amounts of other rare-earth elements. The chemical formula is with ancylite-Ce enriched in cerium and ancylite-La in lanthanum.http://webmineral.c ...
, barylite, catapleiite
Catapleiite (•2) is a dimorph of Gaidonnayite rarely found by itself. Its name derives from the Greek words “κατα” (kata) and “πλειον” (pleion) meaning “with more” as it is mostly accompanied by a number of rare mineral ...
, cerite-(Ce)
Cerite is a complex silicate mineral group containing cerium, formula .http://rruff.geo.arizona.edu/doclib/hom/ceritece.pdf Handbook of Mineralogy The cerium and lanthanum content varies with the Ce rich species (cerite-(Ce)) and the La rich spe ...
, cerite-(La)
Cerite is a complex silicate mineral group containing cerium, formula .http://rruff.geo.arizona.edu/doclib/hom/ceritece.pdf Handbook of Mineralogy The cerium and lanthanum content varies with the Ce rich species (cerite-(Ce)) and the La rich spe ...
, chabazite-(Ca), edingtonite
Edingtonite is a white, gray, brown, colorless, pink or yellow zeolite mineral. Its chemical formula is Ba Al2 Si3 O10·4 H2O. It has varieties with tetragonal, orthorhombic or triclinic crystals.
The mineral occurs within cavities in nephelin ...
, fluorapatite
Fluorapatite, often with the alternate spelling of fluoroapatite, is a phosphate mineral with the formula Ca5(PO4)3F (calcium fluorophosphate). Fluorapatite is a hard crystalline solid. Although samples can have various color (green, brown, b ...
, galena
Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver.
Galena is one of the most abundant and widely distributed sulfide minerals. It cry ...
, ilmenite
Ilmenite is a titanium-iron oxide mineral with the idealized formula . It is a weakly magnetic black or steel-gray solid. Ilmenite is the most important ore of titanium and the main source of titanium dioxide, which is used in paints, printing ...
, microcline, natrolite
Natrolite is a tectosilicate mineral species belonging to the zeolite group. It is a hydrated sodium and aluminium silicate with the formula . The type locality is Hohentwiel, Hegau, Germany.
It was named natrolite by Martin Heinrich Klap ...
, sphalerite
Sphalerite (sometimes spelled sphaelerite) is a sulfide mineral with the chemical formula . It is the most important ore of zinc. Sphalerite is found in a variety of deposit types, but it is primarily in sedimentary exhalative, Mississippi-Va ...
and vanadinite.[The Mineralogical Record (2004) 35-2:176] At the same locality it was found in alkaline
In chemistry, an alkali (; from ar, القلوي, al-qaly, lit=ashes of the saltwort) is a basic, ionic salt of an alkali metal or an alkaline earth metal. An alkali can also be defined as a base that dissolves in water. A solution of a ...
pegmatite
A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic co ...
veins associated with clinobarylite, natrolite
Natrolite is a tectosilicate mineral species belonging to the zeolite group. It is a hydrated sodium and aluminium silicate with the formula . The type locality is Hohentwiel, Hegau, Germany.
It was named natrolite by Martin Heinrich Klap ...
, aegirine
Aegirine is a member of the clinopyroxene group of inosilicate minerals. Aegirine is the sodium endmember of the aegirine-augite series. Aegirine has the chemical formula Na Fe Si2 O6 in which the iron is present as Fe3+. In the aegirine-augite ...
, microcline, catapleiite
Catapleiite (•2) is a dimorph of Gaidonnayite rarely found by itself. Its name derives from the Greek words “κατα” (kata) and “πλειον” (pleion) meaning “with more” as it is mostly accompanied by a number of rare mineral ...
, fluorapatite
Fluorapatite, often with the alternate spelling of fluoroapatite, is a phosphate mineral with the formula Ca5(PO4)3F (calcium fluorophosphate). Fluorapatite is a hard crystalline solid. Although samples can have various color (green, brown, b ...
, titanite
Titanite, or sphene (from the Greek ''sphenos'' (σφηνώ), meaning wedge), is a calcium titanium nesosilicate mineral, Ca Ti Si O5. Trace impurities of iron and aluminium are typically present. Also commonly present are rare earth metals in ...
, fluorite
Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon.
The Mohs sca ...
, galena
Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver.
Galena is one of the most abundant and widely distributed sulfide minerals. It cry ...
, sphalerite
Sphalerite (sometimes spelled sphaelerite) is a sulfide mineral with the chemical formula . It is the most important ore of zinc. Sphalerite is found in a variety of deposit types, but it is primarily in sedimentary exhalative, Mississippi-Va ...
, annite, astrophyllite, lorenzenite, labuntsovite-Mn, kuzmenkoite-Mn, cerite-(Ce)
Cerite is a complex silicate mineral group containing cerium, formula .http://rruff.geo.arizona.edu/doclib/hom/ceritece.pdf Handbook of Mineralogy The cerium and lanthanum content varies with the Ce rich species (cerite-(Ce)) and the La rich spe ...
, edingtonite
Edingtonite is a white, gray, brown, colorless, pink or yellow zeolite mineral. Its chemical formula is Ba Al2 Si3 O10·4 H2O. It has varieties with tetragonal, orthorhombic or triclinic crystals.
The mineral occurs within cavities in nephelin ...
, ilmenite
Ilmenite is a titanium-iron oxide mineral with the idealized formula . It is a weakly magnetic black or steel-gray solid. Ilmenite is the most important ore of titanium and the main source of titanium dioxide, which is used in paints, printing ...
and calcite
Calcite is a carbonate mineral and the most stable polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on the Mohs scale of mineral hardness, based on scra ...
.[The Mineralogical Record 35-4:347 (2004)]
United States
In the Gulf coast
The Gulf Coast of the United States, also known as the Gulf South, is the coastline along the Southern United States where they meet the Gulf of Mexico. The coastal states that have a shoreline on the Gulf of Mexico are Texas, Louisiana, Missis ...
of Louisiana
Louisiana , group=pronunciation (French: ''La Louisiane'') is a U.S. state, state in the Deep South and South Central United States, South Central regions of the United States. It is the List of U.S. states and territories by area, 20th-smal ...
and Texas
Texas (, ; Spanish language, Spanish: ''Texas'', ''Tejas'') is a state in the South Central United States, South Central region of the United States. At 268,596 square miles (695,662 km2), and with more than 29.1 million residents in 2 ...
, strontianite occurs with celestine in calcite
Calcite is a carbonate mineral and the most stable polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on the Mohs scale of mineral hardness, based on scra ...
cap rock of salt domes.[
At the Minerva Number 1 Mine (Ozark-Mahoning Number 1 Mine) Ozark-Mahoning Group, Cave-in-Rock, Illinois, in the Kentucky Fluorspar District, Hardin County strontanite occurs as white, brown or rarely pink tufts and bowties of acicular crystals with slightly curved terminations.][Rocks & Minerals (2010) 85-3:212]
In the Silurian
The Silurian ( ) is a geologic period and system spanning 24.6 million years from the end of the Ordovician Period, at million years ago (Mya), to the beginning of the Devonian Period, Mya. The Silurian is the shortest period of the Paleozoi ...
Lockport Group, Central and Western New York
New York most commonly refers to:
* New York City, the most populous city in the United States, located in the state of New York
* New York (state), a state in the northeastern United States
New York may also refer to:
Film and television
* '' ...
strontianite is observed in cavities in eastern Lockport, where it occurs as small white radiating sprays of acicular crystals.[Rocks & Minerals (2009) 84-4:332]
In Schoharie County, New York, it occurs in geode
A geode (; ) is a geological secondary formation within sedimentary and volcanic rocks. Geodes are hollow, vaguely spherical rocks, in which masses of mineral matter (which may include crystals) are secluded. The crystals are formed by the fil ...
s and veins
Veins are blood vessels in humans and most other animals that carry blood towards the heart. Most veins carry deoxygenated blood from the tissues back to the heart; exceptions are the pulmonary and umbilical veins, both of which carry oxygenated ...
with celestine and calcite
Calcite is a carbonate mineral and the most stable polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on the Mohs scale of mineral hardness, based on scra ...
in limestone
Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms wh ...
,[ and in Mifflin County, Pennsylvania, it occurs with ]aragonite
Aragonite is a carbonate mineral, one of the three most common naturally occurring crystal forms of calcium carbonate, (the other forms being the minerals calcite and vaterite). It is formed by biological and physical processes, including pre ...
, again in limestone
Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms wh ...
.[
Strontianite-118172.jpg, Strontianite from Strontian, Scotland
Dresserite-Strontianite-lor03a.jpg, ]Dresserite
Dresserite is a mineral of the dresserite group, named in honor of John Alexander Dresser, geologist. It was approved by the IMA in 1968, but only a year after was it published. The rare mineral can only be found in Francon quarry, Canada. The qua ...
and Strontianite from the Francon quarry, Canada
Strontianite-Baryte-160390.jpg, Strontianite from the Dreislar Mine, North Rhine-Westphalia, Germany
Strontianite-170614.jpg, Strontianite from Texas, US
Strontianite-208781.jpg, Strontianite from Illinois, US
Strontianite Strontium carbonate Barstow San Bernardino County California 1845.jpg, Strontianite from California
See also
* Strontian process
References
External links
JMol
{{Authority control
Lochaber
Strontium minerals
Carbonate minerals
Aragonite group
Orthorhombic minerals
Minerals in space group 62
Luminescent minerals
Geology of Scotland