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Phosphorescence
Phosphorescence is a type of photoluminescence related to fluorescence. When exposed to light (radiation) of a shorter wavelength, a phosphorescent substance will glow, absorbing the light and reemitting it at a longer wavelength. Unlike fluorescence, a phosphorescent material does not immediately reemit the radiation it absorbs. Instead, a phosphorescent material absorbs some of the radiation energy and reemits it for a much longer time after the radiation source is removed. In a general sense, there is no distinct boundary between the emission times of fluorescence and phosphorescence (i.e.: if a substance glows under a black light it is generally considered fluorescent, and if it glows in the dark it is often simply called phosphorescent). In a modern, scientific sense, the phenomena can usually be classified by the three different mechanisms that produce the light, and the typical timescales during which those mechanisms emit light. Whereas fluorescent materials stop emitti ...
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Fluorescence
Fluorescence is one of two kinds of photoluminescence, the emission of light by a substance that has absorbed light or other electromagnetic radiation. When exposed to ultraviolet radiation, many substances will glow (fluoresce) with colored visible light. The color of the light emitted depends on the chemical composition of the substance. Fluorescent materials generally cease to glow nearly immediately when the radiation source stops. This distinguishes them from the other type of light emission, phosphorescence. Phosphorescent materials continue to emit light for some time after the radiation stops. This difference in duration is a result of quantum spin effects. Fluorescence occurs when a photon from incoming radiation is absorbed by a molecule, exciting it to a higher energy level, followed by the emission of light as the molecule returns to a lower energy state. The emitted light may have a longer wavelength and, therefore, a lower photon energy than the absorbed radi ...
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Persistent Luminescence
Commonly referred to as phosphorescence, persistent luminescence is the emission of light by a phosphorescent material after an excitation by ultraviolet or visible light. Mechanism The mechanism underlying this phenomenon is not fully understood. It is neither fluorescence nor phosphorescence Phosphorescence is a type of photoluminescence related to fluorescence. When exposed to light (radiation) of a shorter wavelength, a phosphorescent substance will glow, absorbing the light and reemitting it at a longer wavelength. Unlike fluor .... In fluorescence, the lifetime of the excited state lasts a few nanoseconds. In phosphorescence, even if the emission lives several seconds, this is due to deexcitation between two electronic states of different spin multiplicity. Persistent luminescence involves energy traps (such as electron or hole traps) in a material, which are filled during the excitation. Afterward, the stored energy is gradually released to light emitter centers, usu ...
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Phosphorus
Phosphorus is a chemical element; it has Chemical symbol, symbol P and atomic number 15. All elemental forms of phosphorus are highly Reactivity (chemistry), reactive and are therefore never found in nature. They can nevertheless be prepared artificially, the two most common allotropes being white phosphorus and red phosphorus. With as its only stable isotope, phosphorus has an occurrence in Earth's crust of about 0.1%, generally as phosphate rock. A member of the pnictogen family, phosphorus readily forms a wide variety of organic compound, organic and inorganic compound, inorganic compounds, with as its main oxidation states +5, +3 and −3. The isolation of white phosphorus in 1669 by Hennig Brand marked the scientific community's first discovery since Antiquity of an element. The name phosphorus is a reference to the Phosphorus (morning star), god of the Morning star in Greek mythology, inspired by the faint glow of white phosphorus when exposed to oxygen. This property is ...
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Radioactive Decay
Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is considered ''radioactive''. Three of the most common types of decay are Alpha decay, alpha, Beta decay, beta, and Gamma ray, gamma decay. The weak force is the Fundamental interactions, mechanism that is responsible for beta decay, while the other two are governed by the electromagnetic force, electromagnetic and nuclear forces. Radioactive decay is a randomness, random process at the level of single atoms. According to quantum mechanics, quantum theory, it is impossible to predict when a particular atom will decay, regardless of how long the atom has existed. However, for a significant number of identical atoms, the overall decay rate can be expressed as a decay constant or as a half-life. The half-lives of radioactive atoms have a huge range: f ...
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Photoluminescence
Photoluminescence (abbreviated as PL) is light emission from any form of matter after the absorption of photons (electromagnetic radiation). It is one of many forms of luminescence (light emission) and is initiated by photoexcitation (i.e. photons that excite electrons to a higher energy level in an atom), hence the prefix ''photo-''. Following excitation, various relaxation processes typically occur in which other photons are re-radiated. Time periods between absorption and emission may vary: ranging from short femtosecond-regime for emission involving free-carrier plasma in inorganic semiconductorsHayes, G.R.; Deveaud, B. (2002). "Is Luminescence from Quantum Wells Due to Excitons?". ''Physica Status Solidi A'' 190 (3): 637–640doi:10.1002/1521-396X(200204)190:33.0.CO;2-7/ref> up to milliseconds for phosphoresence processes in molecular systems; and under special circumstances delay of emission may even span to minutes or hours. Observation of photoluminescence at a certain ...
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Fluorspar
Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon. The Mohs scale of mineral hardness, based on scratch hardness comparison, defines value 4 as fluorite. Pure fluorite is colourless and transparent, both in visible and ultraviolet light, but impurities usually make it a colorful mineral and the stone has ornamental and lapidary uses. Industrially, fluorite is used as a flux for smelting, and in the production of certain glasses and enamels. The purest grades of fluorite are a source of fluoride for hydrofluoric acid manufacture, which is the intermediate source of most fluorine-containing fine chemicals. Optically clear transparent fluorite has anomalous partial dispersion, that is, its refractive index varies with the wavelength of light in a manner that differs from that of commonly used glasses, s ...
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Sir George Stokes, 1st Baronet
Sir George Gabriel Stokes, 1st Baronet, (; 13 August 1819 – 1 February 1903) was an Irish mathematician and physicist. Born in County Sligo, Ireland, Stokes spent his entire career at the University of Cambridge, where he served as the Lucasian Professor of Mathematics for 54 years, from 1849 until his death in 1903, the longest tenure held by the Lucasian Professor. As a physicist, Stokes made seminal contributions to fluid mechanics, including the Navier–Stokes equations; and to physical optics, with notable works on polarisation and fluorescence. As a mathematician, he popularised "Stokes' theorem" in vector calculus and contributed to the theory of asymptotic expansions. Stokes, along with Felix Hoppe-Seyler, first demonstrated the oxygen transport function of haemoglobin, and showed colour changes produced by the aeration of haemoglobin solutions. Stokes was made a baronet by the British monarch in 1889. In 1893 he received the Royal Society's Copley Medal, then the mo ...
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Forbidden Mechanism
In spectroscopy, a forbidden mechanism (forbidden transition or forbidden line) is a spectral line associated with absorption or emission of photons by atomic nuclei, atoms, or molecules which undergo a transition that is not allowed by a particular selection rule but is allowed if the approximation associated with that rule is not made. For example, in a situation where, according to usual approximations (such as the electric dipole moment, electric dipole approximation for the interaction with light), the process cannot happen, but at a higher level of approximation (e.g. magnetic dipole moment, magnetic dipole, or electric quadrupole) the process is allowed but at a low rate. An example is phosphorescence, phosphorescent materials, which absorb light and form an excited state whose decay involves a Spin (physics), spin flip, and is therefore forbidden by electric dipole transitions. The result is emission of light slowly over minutes or hours. Should an atomic nucleus, atom or ...
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Opalescence
Opalescence or play of color is an optical phenomenon associated with the mineraloid gemstone opal,opalescent. 2019. In Noah Webster's 1828 American Dictionary of the English Language. Retrieved January 7, 2019, from https://1828.mshaffer.com/d/word/opalescent a hydrated silicon dioxide. This effect appears as a milky, translucent glow that changes with the angle of light, often creating a soft, pearly sheen that can display various colors or hues. Opalescence can be seen in materials like certain minerals, glass, and even fluids. Definition Each of the three notable types of opalprecious, common, and fireDouma, M., curator. 2008. Opal. In Cause of Color. Retrieved January 8, 2019, from https://webexhibits.org/causesofcolor/15F.htmldisplay different optical effects; therefore, the intended meaning varies depending on context. * The general definition of ''opalescence'' is a milky iridescence displayed by an opal, which describes the visual effect of precious opal very well ...
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Prism (optics)
An optical prism is a transparent optical element with flat, polished surfaces that are designed to refract light. At least one surface must be angled—elements with two parallel surfaces are ''not'' prisms. The most familiar type of optical prism is the triangular prism, which has a triangular base and rectangular sides. Not all optical prisms are geometric prisms, and not all geometric prisms would count as an optical prism. Prisms can be made from any material that is transparent to the wavelengths for which they are designed. Typical materials include glass, acrylic and fluorite. A dispersive prism can be used to break white light up into its constituent spectral colors (the colors of the rainbow) to form a spectrum as described in the following section. Other types of prisms noted below can be used to reflect light, or to split light into components with different polarizations. Types Dispersive ''Dispersive prisms'' are used to break up light into its ...
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Quinine Sulfate
Quinine is a medication used to treat malaria and babesiosis. This includes the treatment of malaria due to ''Plasmodium falciparum'' that is resistant to chloroquine when artesunate is not available. While sometimes used for nocturnal leg cramps, quinine is not recommended for this purpose due to the risk of serious side effects. It can be taken by mouth or intravenously. Malaria resistance to quinine occurs in certain areas of the world. Quinine is also used as an ingredient in tonic water and other beverages to impart a bitter taste. Common side effects include headache, ringing in the ears, vision issues, and sweating. More severe side effects include deafness, low blood platelets, and an irregular heartbeat. Use can make one more prone to sunburn. While it is unclear if use during pregnancy carries potential for fetal harm, treating malaria during pregnancy with quinine when appropriate is still recommended. Quinine is an alkaloid, a naturally occurring chemical c ...
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