Cadmium zinc telluride, (CdZnTe) or CZT, is a compound of
cadmium
Cadmium is a chemical element with the symbol Cd and atomic number 48. This soft, silvery-white metal is chemically similar to the two other stable metals in group 12, zinc and mercury. Like zinc, it demonstrates oxidation state +2 in most of ...
,
zinc
Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic t ...
and
tellurium
Tellurium is a chemical element with the symbol Te and atomic number 52. It is a brittle, mildly toxic, rare, silver-white metalloid. Tellurium is chemically related to selenium and sulfur, all three of which are chalcogens. It is occasionally fo ...
or, more strictly speaking, an alloy of
cadmium telluride and
zinc telluride. A
direct bandgap semiconductor
A semiconductor is a material which has an electrical conductivity value falling between that of a conductor, such as copper, and an insulator, such as glass. Its resistivity falls as its temperature rises; metals behave in the opposite way. ...
, it is used in a variety of applications, including
semiconductor radiation detectors,
photorefractive gratings,
electro-optic modulators,
solar cell
A solar cell, or photovoltaic cell, is an electronic device that converts the energy of light directly into electricity by the photovoltaic effect, which is a physical and chemical phenomenon.[terahertz
Terahertz or THz may refer to:
* Terahertz (unit), a unit of frequency, defined as one trillion (1012) cycles per second or 1012 hertz
* Terahertz radiation, electromagnetic waves within the ITU-designated band of frequencies from 0.3 to 3 terahe ...]
generation and detection. The band gap varies from approximately 1.4 to 2.2
eV, depending on composition.

Radiation detectors using CZT can operate in direct-conversion (or photoconductive) mode at room temperature, unlike some other materials (particularly
germanium
Germanium is a chemical element with the symbol Ge and atomic number 32. It is lustrous, hard-brittle, grayish-white and similar in appearance to silicon. It is a metalloid in the carbon group that is chemically similar to its group neighbo ...
) which require cooling. Their relative advantages include high sensitivity for X-rays and gamma rays, due to the high atomic numbers of Cd and Te, and better energy resolution than
scintillator detectors
A scintillator is a material that exhibits scintillation, the property of luminescence, when excited by ionizing radiation. Luminescent materials, when struck by an incoming particle, absorb its energy and scintillate (i.e. re-emit the absorbed ...
. CZT can be formed into different shapes for different radiation-detecting applications, and a variety of electrode geometries, such as coplanar grids and
small pixel detectors, have been developed to provide unipolar (electron-only) operation, thereby improving energy resolution. A 1 cm
3 CZT crystal has a sensitivity range of 30 keV to 3 MeV with a 2.5%
FWHM energy resolution at 662 keV. Pixelated CZT with a volume of 6 cm
3 can achieve 0.71%
FWHM energy resolution at 662 keV and perform
Compton imaging.
References
External links
National Pollutant Inventory - Cadmium and compounds
{{Authority control
Cadmium compounds
Zinc compounds
Tellurides
II-VI semiconductors
Nonlinear optical materials
Terahertz technology
Electro-optical materials
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