Aimé Auguste Cotton (9 October 1869 – 16 April 1951) was a French physicist known for his studies of the interaction of light with
chiral
Chirality () is a property of asymmetry important in several branches of science. The word ''chirality'' is derived from the Greek language, Greek (''kheir''), "hand", a familiar chiral object.
An object or a system is ''chiral'' if it is dist ...
molecules. In the
absorption band
In spectroscopy, an absorption band is a range of wavelengths, frequency, frequencies or energies in the electromagnetic spectrum that are characteristic of a particular transition from initial to final state in a substance.
According to quantum ...
s of these molecules, he discovered large values of
optical rotatory dispersion (ORD), or variation of optical rotation as a function of wavelength (
Cotton effect), as well as
circular dichroism
Circular dichroism (CD) is dichroism involving circular polarization, circularly polarized light, i.e., the differential Absorption (electromagnetic radiation), absorption of left- and right-handed light. Left-hand circular (LHC) and right-hand ci ...
or differences of absorption between left and right
circularly polarized light.
Biography
Early years
Aimé Cotton was born in
Bourg-en-Bresse
Bourg-en-Bresse (; ) is the Prefectures in France, prefecture of the Ain department in the Auvergne-Rhône-Alpes region in Eastern France. Located northeast of Lyon, it is the capital of the ancient Provinces of France, province of Bresse (). I ...
,
Ain on 9 October 1869.
[ Nature website, ''Obituary'', 9 June 1951]
/ref> His grandfather was director of the École normale (teachers' college) of Bourg, and his father, Eugène Cotton, was a mathematics professor at the college of Bourg, the institution where physicist André-Marie Ampère
André-Marie Ampère (, ; ; 20 January 177510 June 1836) was a French physicist and mathematician who was one of the founders of the science of classical electromagnetism, which he referred to as ''electrodynamics''. He is also the inventor of ...
began his career. Aimé's brother Émile Cotton was a mathematician and academician.
Aimé Cotton attended a lycée (high school) in Bourg and then the special mathematics program at the Lycée Blaise Pascal
Blaise Pascal (19June 162319August 1662) was a French mathematician, physicist, inventor, philosopher, and Catholic Church, Catholic writer.
Pascal was a child prodigy who was educated by his father, a tax collector in Rouen. His earliest ...
in Clermont-Ferrand
Clermont-Ferrand (, , ; or simply ; ) is a city and Communes of France, commune of France, in the Auvergne-Rhône-Alpes regions of France, region, with a population of 147,284 (2020). Its metropolitan area () had 504,157 inhabitants at the 2018 ...
. He entered the École normale supérieure
École or Ecole may refer to:
* an elementary school in the French educational stages normally followed by Secondary education in France, secondary education establishments (collège and lycée)
* École (river), a tributary of the Seine flowing i ...
in 1889, and won the physical sciences prize on graduating in 1893.
Academic and scientific career
As a graduate student at the physics laboratory of the École normale supérieure, he then prepared his doctoral thesis in physical sciences. In this thesis he studied the interactions of polarized light
, or , is a property of transverse waves which specifies the geometrical orientation of the oscillations. In a transverse wave, the direction of the oscillation is perpendicular to the direction of motion of the wave. One example of a polarize ...
with optically active substances containing chiral
Chirality () is a property of asymmetry important in several branches of science. The word ''chirality'' is derived from the Greek language, Greek (''kheir''), "hand", a familiar chiral object.
An object or a system is ''chiral'' if it is dist ...
molecules. In absorption bands of these substances, he found large variations of optical rotation
Optical rotation, also known as polarization rotation or circular birefringence, is the rotation of the orientation of the plane of polarization about the optical axis of linearly polarized light as it travels through certain materials. Circul ...
as a function of wavelength, now known as optical rotatory dispersion (ORD) or as the Cotton effect.
He also discovered the related phenomenon of circular dichroism
Circular dichroism (CD) is dichroism involving circular polarization, circularly polarized light, i.e., the differential Absorption (electromagnetic radiation), absorption of left- and right-handed light. Left-hand circular (LHC) and right-hand ci ...
, or unequal absorption of left and right circularly polarized light.
These two phenomena were later used to determine the stereochemistries of chiral molecules in organic chemistry and in biochemistry.
He was appointed maître de conférences
The following summarizes basic academic ranks in the France, French higher education system. Most academic institutions are state-run and most academics with permanent positions are French Civil Service, civil servants, and thus are Academic tenur ...
in the science faculty at Toulouse
Toulouse (, ; ; ) is a city in southern France, the Prefectures in France, prefecture of the Haute-Garonne department and of the Occitania (administrative region), Occitania region. The city is on the banks of the Garonne, River Garonne, from ...
in 1895, and defended his doctoral thesis in 1896 before the science faculty of the University of Paris
The University of Paris (), known Metonymy, metonymically as the Sorbonne (), was the leading university in Paris, France, from 1150 to 1970, except for 1793–1806 during the French Revolution. Emerging around 1150 as a corporation associated wit ...
. His thesis was entitled "Research on the absorption and dispersion of light by substances capable of optical rotation". In 1900, he was appointed assistant professor as a temporary replacement for Jules Violle. In 1904 he was appointed instructor, and in 1910 assistant professor at the science faculty of the University of Paris, assigned to the École normale supérieure, where he remained until 1922.
During this period his research dealt with the interactions of light and magnetism
Magnetism is the class of physical attributes that occur through a magnetic field, which allows objects to attract or repel each other. Because both electric currents and magnetic moments of elementary particles give rise to a magnetic field, ...
. He worked first with Pierre Weiss on the Zeeman effect
The Zeeman effect () is the splitting of a spectral line into several components in the presence of a static magnetic field. It is caused by the interaction of the magnetic field with the magnetic moment of the atomic electron associated with ...
, the splitting of spectral lines in the presence of a magnetic field
A magnetic field (sometimes called B-field) is a physical field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular ...
. For this work he invented the Cotton balance to measure the magnetic field intensity precisely. With Weiss he studied the magnetic splitting of the blue lines of the zinc
Zinc is a chemical element; it has symbol Zn and atomic number 30. It is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic tabl ...
atom and in 1907 they were able to determine the ratio of the electron
The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary charge, elementary electric charge. It is a fundamental particle that comprises the ordinary matter that makes up the universe, along with up qua ...
's charge to its mass (e/m) with better precision than the method of J.J. Thomson
Sir Joseph John Thomson (18 December 1856 – 30 August 1940) was an English physicist who received the Nobel Prize in Physics in 1906 "in recognition of the great merits of his theoretical and experimental investigations on the conduction of ...
.
Cotton then became interested in the Faraday effect near absorption lines and demonstrated magnetic circular dichroism. At the same time, he worked with his former classmate Henri Mouton, a biologist at the Pasteur Institute
The Pasteur Institute (, ) is a French non-profit private foundation dedicated to the study of biology, micro-organisms, diseases, and vaccines. It is named after Louis Pasteur, who invented pasteurization and vaccines for anthrax and rabies. Th ...
, on magnetic birefringence in colloïdal solutions of magnetic particles. In 1907 the two discovered the Cotton-Mouton effect, an intense magnetic birefringence with optical axis perpendicular to the magnetic field lines.
In 1913 he married Eugénie Feytis, also a physicist; they had four children.
During World War I
World War I or the First World War (28 July 1914 – 11 November 1918), also known as the Great War, was a World war, global conflict between two coalitions: the Allies of World War I, Allies (or Entente) and the Central Powers. Fighting to ...
he and Pierre Weiss developed the Cotton–Weiss system, based on an acoustic method, for locating enemy artillery.
He supervised the thesis work of Georges Bruhat on circular dichroïsm and optical rotatory dispersion (1914). In 1917 he helped to found the Institut d'optique théorique et appliquée. In 1914, he proposed construction of a large electromagnet
An electromagnet is a type of magnet in which the magnetic field is produced by an electric current. Electromagnets usually consist of wire (likely copper) wound into a electromagnetic coil, coil. A current through the wire creates a magnetic ...
capable of producing intense magnetic fields. Work on the magnet finally started in 1924 in the Service des recherches et inventions at Bellevue, later the Laboratoire du magnétisme at Meudon-Bellevue, and finally the Laboratoire Aimé-Cotton in his honour. Magnetic fields as high as to 7 teslas were attained.
In 1919, he became chairman of the physics committee of the Direction des Inventions intéressant la défense nationale (Directorate of Inventions relevant to National Defense). In 1920 he was named professor of the new chair of theoretical physics and astrophysics at the Faculty of Sciences of the University of Paris
The University of Paris (), known Metonymy, metonymically as the Sorbonne (), was the leading university in Paris, France, from 1150 to 1970, except for 1793–1806 during the French Revolution. Emerging around 1150 as a corporation associated wit ...
. In 1922 he succeeded Gabriel Lippmann
Gabriel Lippmann ( ; 16 August 1845 – 12 July 1921) was a French physicist who received the Nobel Prize in Physics in 1908 "for his method of reproducing colours photographically based on the phenomenon of interference".
Early life and educa ...
in the chair of general physics, and at the same time became director of physics research in the faculty. In 1923 he was elected to the French Academy of Sciences
The French Academy of Sciences (, ) is a learned society, founded in 1666 by Louis XIV at the suggestion of Jean-Baptiste Colbert, to encourage and protect the spirit of French Scientific method, scientific research. It was at the forefron ...
, and in 1938 he was elected its president. The academy honored him three times.[
He was nominated for a ]Nobel Prize
The Nobel Prizes ( ; ; ) are awards administered by the Nobel Foundation and granted in accordance with the principle of "for the greatest benefit to humankind". The prizes were first awarded in 1901, marking the fifth anniversary of Alfred N ...
six times.
He retired in 1941 and was replaced by Jean Cabannes as professor and laboratory directory, although he retained the direction of the magneto-optics laboratory at Bellevue.
In 1941 he was imprisoned by the German occupiers at Fresnes for one and a half months and was later awarded the Rosette de la résistance. At the age of 81 years, 6 months and 7 days, he died on April 16, 1951, at Sèvres
Sèvres (, ) is a French Communes of France, commune in the southwestern suburbs of Paris. It is located from the Kilometre zero, centre of Paris, in the Hauts-de-Seine department of the Île-de-France region. The commune, which had a populatio ...
.
Publications
* ''Les Ultramicroscopes et les Objets Ultramicroscopiques'' Waterstones website, 'Les Ultramicroscopes et les Objets Ultramicroscopiques''
/ref>
References
External links
Bibliography (in French) of some 20th-century physicists. From the Centre d'initiation à l'Enseignement Supérieur (CIES) of Lyon
{{DEFAULTSORT:Cotton, Aime
1869 births
1951 deaths
People from Bourg-en-Bresse
French physicists
French Esperantists
Officers of the French Academy of Sciences