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Dication
A dication is any cation, of general formula X2+, formed by the removal of two electrons from a neutral species. Diatomic dications corresponding to stable neutral species (e.g. formed by removal of two electrons from H2) often decay quickly into two singly charged particles (H+), due to the loss of electrons in bonding molecular orbitals. Energy levels of diatomic dications can be studied with good resolution by measuring the yield of pairs of zero-kinetic-energy electrons from double photoionization of a molecule as a function of the photoionizing wavelength (threshold photoelectrons coincidence spectroscopy – TPEsCO). The dication is kinetically stable. An example of a stable diatomic dication which is not formed by oxidation of a neutral diatomic molecule is the dimercury dication . An example of a polyatomic dication is , formed by oxidation of S8 and unstable with respect to further oxidation over time to form SO2. Many organic dications can be detected in mass spectro ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Adamantane
Adamantane is an organic compound with formula C10H16 or, more descriptively, (CH)4(CH2)6. Adamantane molecules can be described as the fusion of three cyclohexane rings. The molecule is both rigid and virtually stress-free. Adamantane is the most stable isomer of C10H16. The spatial arrangement of carbon atoms in the adamantane molecule is the same as in the diamond crystal. This similarity led to the name ''adamantane'', which is derived from the Greek ''adamantinos'' (relating to steel or diamond). It is a white solid with a camphor-like odor. It is the simplest diamondoid. The discovery of adamantane in petroleum in 1933 launched a new field of chemistry dedicated to the synthesis and properties of polyhedral organic compounds. Adamantane derivatives have found practical application as drugs, polymeric materials, and thermally stable lubricants. History and synthesis In 1924, H. Decker suggested the existence of adamantane, which he called decaterpene. The first attempted l ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cation
An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convention. The net charge of an ion is not zero because its total number of electrons is unequal to its total number of protons. A cation is a positively charged ion with fewer electrons than protons (e.g. K+ ( potassium ion)) while an anion is a negatively charged ion with more electrons than protons (e.g. Cl− ( chloride ion) and OH− ( hydroxide ion)). Opposite electric charges are pulled towards one another by electrostatic force, so cations and anions attract each other and readily form ionic compounds. Ions consisting of only a single atom are termed ''monatomic ions'', ''atomic ions'' or ''simple ions'', while ions consisting of two or more atoms are termed polyatomic ions or ''molecular ions''. If only a + or − is present, it indic ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Adamantane Dication
Adamantane is an organic compound with formula C10H16 or, more descriptively, (CH)4(CH2)6. Adamantane molecules can be described as the fusion of three cyclohexane rings. The molecule is both rigid and virtually stress-free. Adamantane is the most stable isomer of C10H16. The spatial arrangement of carbon atoms in the adamantane molecule is the same as in the diamond crystal. This similarity led to the name ''adamantane'', which is derived from the Greek ''adamantinos'' (relating to steel or diamond). It is a white solid with a camphor-like odor. It is the simplest diamondoid. The discovery of adamantane in petroleum in 1933 launched a new field of chemistry dedicated to the synthesis and properties of polyhedral organic compounds. Adamantane derivatives have found practical application as drugs, polymeric materials, and thermally stable lubricants. History and synthesis In 1924, H. Decker suggested the existence of adamantane, which he called decaterpene. The first attempted l ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Transition Metal
In chemistry, a transition metal (or transition element) is a chemical element in the d-block of the periodic table (groups 3 to 12), though the elements of group 12 (and less often group 3) are sometimes excluded. The lanthanide and actinide elements (the f-block) are called inner transition metals and are sometimes considered to be transition metals as well. They are lustrous metals with good electrical and thermal conductivity. Most (with the exception of group 11 and group 12) are hard and strong, and have high melting and boiling temperatures. They form compounds in any of two or more different oxidation states and bind to a variety of ligands to form coordination complexes that are often coloured. They form many useful alloys and are often employed as catalysts in elemental form or in compounds such as coordination complexes and oxides. Most are strongly paramagnetic because of their unpaired d electrons, as are many of their compounds. All of the elements that are ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Solar System
The Solar SystemCapitalization of the name varies. The International Astronomical Union, the authoritative body regarding astronomical nomenclature, specifies capitalizing the names of all individual astronomical objects but uses mixed "Solar System" and "solar system" structures in theinaming guidelines document. The name is commonly rendered in lower case ('solar system'), as, for example, in the ''Oxford English Dictionary'' an''Merriam-Webster's 11th Collegiate Dictionary''. is the gravitationally bound Planetary system, system of the Sun and the objects that orbit it. It Formation and evolution of the Solar System, formed about 4.6 billion years ago when a dense region of a molecular cloud collapsed, forming the Sun and a protoplanetary disc. The Sun is a typical star that maintains a hydrostatic equilibrium, balanced equilibrium by the thermonuclear fusion, fusion of hydrogen into helium at its stellar core, core, releasing this energy from its outer photosphere. As ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrons
The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary charge, elementary electric charge. It is a fundamental particle that comprises the ordinary matter that makes up the universe, along with up quark, up and down quark, down quarks. Electrons are extremely lightweight particles that orbit the positively charged atomic nucleus, nucleus of atoms. Their negative charge is balanced by the positive charge of protons in the nucleus, giving atoms their overall electric charge#Charge neutrality, neutral charge. Ordinary matter is composed of atoms, each consisting of a positively charged nucleus surrounded by a number of orbiting electrons equal to the number of protons. The configuration and energy levels of these orbiting electrons determine the chemical properties of an atom. Electrons are bound to the nucleus to different degrees. The outermost or valence electron, valence electrons are the least tightly bound and are responsible for th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Photoionization
Photoionization is the physical process in which an ion is formed from the interaction of a photon with an atom or molecule. Cross section Not every interaction between a photon and an atom, or molecule, will result in photoionization. The probability of photoionization is related to the photoionization cross section of the species – the probability of an ionization event conceptualized as a hypothetical cross-sectional area. This cross section depends on the energy of the photon (proportional to its wavenumber) and the species being considered i.e. it depends on the structure of the molecular species. In the case of molecules, the photoionization cross-section can be estimated by examination of Franck-Condon factors between a ground-state molecule and the target ion. This can be initialized by computing the vibrations of a molecule and associated cation (post ionization) using quantum chemical software e.g. QChem. For photon energies below the ionization threshold, the photoi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Spectroscopy
Spectroscopy is the field of study that measures and interprets electromagnetic spectra. In narrower contexts, spectroscopy is the precise study of color as generalized from visible light to all bands of the electromagnetic spectrum. Spectroscopy, primarily in the electromagnetic spectrum, is a fundamental exploratory tool in the fields of astronomy, chemistry, materials science, and physics, allowing the composition, physical structure and electronic structure of matter to be investigated at the atomic, molecular and macro scale, and over astronomical distances. Historically, spectroscopy originated as the study of the wavelength dependence of the absorption by gas phase matter of visible light dispersed by a prism. Current applications of spectroscopy include biomedical spectroscopy in the areas of tissue analysis and medical imaging. Matter waves and acoustic waves can also be considered forms of radiative energy, and recently gravitational waves have been associa ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dimercury
Mercury polycations are polyatomic cations that contain only mercury atoms. The best known example is the ion, found in mercury(I) (mercurous) compounds. The existence of the metal–metal bond in Hg(I) compounds was established using X-ray studies in 1927 and Raman spectroscopy in 1934 making it one of the earliest, if not the first, metal–metal covalent bonds to be characterised. Other mercury polycations are the linear and ions, and the triangular ion and a number of chain and layer polycations. Mercury(I) The best known polycation of mercury is , in which mercury has a formal oxidation state of +1. The ion was perhaps the first metal-metal bonded species confirmed. The presence of the ion in solution was shown by Ogg in 1898. In 1900, Baker showed the presence of HgCl dimers in the vapour phase. The presence of units in the solid state was first determined in 1926 using X-ray diffraction. The presence of the metal-metal bond in solution was confirmed using Raman ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mass Spectrometry
Mass spectrometry (MS) is an analytical technique that is used to measure the mass-to-charge ratio of ions. The results are presented as a ''mass spectrum'', a plot of intensity as a function of the mass-to-charge ratio. Mass spectrometry is used in many different fields and is applied to pure samples as well as complex mixtures. A mass spectrum is a type of plot of the ion signal as a function of the mass-to-charge ratio. These spectra are used to determine the elemental or isotopic signature of a sample, the masses of particles and of molecules, and to elucidate the chemical identity or structure of molecules and other chemical compounds. In a typical MS procedure, a sample, which may be solid, liquid, or gaseous, is ionization, ionized, for example by bombarding it with a Electron ionization, beam of electrons. This may cause some of the sample's molecules to break up into positively charged fragments or simply become positively charged without fragmenting. These ions (fragmen ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Alkaline Earth
The alkaline earth metals are six chemical elements in group 2 of the periodic table. They are beryllium (Be), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), and radium (Ra).. The elements have very similar properties: they are all shiny, silvery-white, somewhat reactive metals at standard temperature and pressure. Together with helium, these elements have in common an outer s orbital which is full —that is, this orbital contains its full complement of two electrons, which the alkaline earth metals readily lose to form cations with charge +2, and an oxidation state of +2. Helium is grouped with the noble gases and not with the alkaline earth metals, but it is theorized to have some similarities to beryllium when forced into bonding and has sometimes been suggested to belong to group 2. All the discovered alkaline earth metals occur in nature, although radium occurs only through the decay chain of uranium and thorium and not as a primordial element. There hav ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Group 12 Element
Group 12, by modern IUPAC numbering, is a group of chemical elements in the periodic table. It includes zinc (Zn), cadmium (Cd), mercury (Hg), and copernicium (Cn). Formerly this group was named ''IIB'' (pronounced as "group two B", as the "II" is a Roman numeral) by CAS and old IUPAC system. The three group 12 elements that occur naturally are zinc, cadmium and mercury. They are all widely used in electric and electronic applications, as well as in various alloys. The first two members of the group share similar properties as they are solid metals under standard conditions. Mercury is the only metal that is known to be a liquid at room temperature – as copernicium's boiling point has not yet been measured accurately enough, it is not yet known whether it is a liquid or a gas under standard conditions. While zinc is very important in the biochemistry of living organisms, cadmium and mercury are both highly toxic. As copernicium does not occur in nature, it has to be synthes ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
