|
Photoionization
Photoionization is the physical process in which an ion is formed from the interaction of a photon with an atom or molecule. Cross section Not every interaction between a photon and an atom, or molecule, will result in photoionization. The probability of photoionization is related to the photoionization cross section of the species – the probability of an ionization event conceptualized as a hypothetical cross-sectional area. This cross section depends on the energy of the photon (proportional to its wavenumber) and the species being considered i.e. it depends on the structure of the molecular species. In the case of molecules, the photoionization cross-section can be estimated by examination of Franck-Condon factors between a ground-state molecule and the target ion. This can be initialized by computing the vibrations of a molecule and associated cation (post ionization) using quantum chemical software e.g. QChem. For photon energies below the ionization threshold, the photoi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ion Source
An ion source is a device that creates atomic and molecular ions. Ion sources are used to form ions for mass spectrometers, optical emission spectrometers, particle accelerators, ion implanters and ion engines. Electron ionization Electron ionization is widely used in mass spectrometry, particularly for organic molecules. The gas phase reaction producing electron ionization is :M + e^- -> M^ + 2e^- where M is the atom or molecule being ionized, e^- is the electron, and M^ is the resulting ion. The electrons may be created by an arc discharge between a cathode and an anode. An electron beam ion source (EBIS) is used in atomic physics to produce highly charged ions by bombarding atoms with a powerful electron beam. Its principle of operation is shared by the electron beam ion trap. Electron capture ionization Electron capture ionization (ECI) is the ionization of a gas phase atom or molecule by attachment of an electron to create an ion of the form A−•. The r ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hubble Green Filaments 20150402
The Hubble Space Telescope (HST or Hubble) is a space telescope that was launched into low Earth orbit in 1990 and remains in operation. It was not the Orbiting Solar Observatory, first space telescope, but it is one of the largest and most versatile, renowned as a vital research tool and as a public relations boon for astronomy. The Hubble Space Telescope is named after astronomer Edwin Hubble and is one of NASA's Great Observatories program, Great Observatories. The Space Telescope Science Institute (STScI) selects Hubble's targets and processes the resulting data, while the Goddard Space Flight Center (GSFC) controls the spacecraft. Hubble features a mirror, and its five main instruments observe in the ultraviolet, visible spectrum, visible, and near-infrared regions of the electromagnetic spectrum. Hubble's orbit outside the distortion of atmosphere of Earth, Earth's atmosphere allows it to capture extremely high-resolution images with substantially lower background lig ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Above-threshold Ionization
In atomic, molecular, and optical physics, above-threshold ionization (ATI) is a multi-photon effect where an atom is ionized with more than the energetically required number of photons. It was first observed in 1979 by Pierre Agostini and colleagues in xenon gas. Photoelectrons In the case of ATI the photoelectron peaks should appear at : E_s = (n + s) \hbar \omega - W, where the integer ''n'' represents the minimal number of photons absorbed, and the integer ''s'' represents the number of additional photons absorbed. ''W'' is the ionization energy, and E_s is the electron kinetic energy of the peak corresponding to ''s'' additional photons being absorbed. Structure It typically has a strong maximum at the minimal number of photons to ionize the system, with successive peaks (known as ATI peaks) separated by the photon energy and thus corresponding to higher numbers of photons being absorbed. In the non-perturbative regime the bound states are dressed with the electric ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Academic Press
Academic Press (AP) is an academic book publisher founded in 1941. It launched a British division in the 1950s. Academic Press was acquired by Harcourt, Brace & World in 1969. Reed Elsevier said in 2000 it would buy Harcourt, a deal completed the next year, after a regulatory review. Thus, Academic Press is now an imprint of Elsevier. Academic Press publishes reference books, serials and online products in the subject areas of: * Communications engineering * Economics * Environmental science * Finance * Food science and nutrition * Geophysics * Life sciences * Mathematics and statistics * Neuroscience * Physical sciences * Psychology Psychology is the scientific study of mind and behavior. Its subject matter includes the behavior of humans and nonhumans, both consciousness, conscious and Unconscious mind, unconscious phenomena, and mental processes such as thoughts, feel ... Well-known products include the '' Methods in Enzymology'' series and encyclopedias such ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
World Scientific
World Scientific Publishing is an academic publisher of scientific, technical, and medical books and journals headquartered in Singapore. The company was founded in 1981. It publishes about 600 books annually, with more than 170 journals in various fields. In 1995, World Scientific co-founded the London-based Imperial College Press together with the Imperial College of Science, Technology and Medicine. Company structure The company head office is in Singapore. The Chairman and Editor-in-Chief is Dr Phua Kok Khoo, while the Managing Director is Doreen Liu. The company was co-founded by them in 1981. Imperial College Press In 1995 the company co-founded Imperial College Press, specializing in engineering, medicine and information technology Information technology (IT) is a set of related fields within information and communications technology (ICT), that encompass computer systems, software, programming languages, data processing, data and information processing, a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Radiolysis
Radiolysis is the dissociation of molecules by ionizing radiation. It is the cleavage of one or several chemical bonds resulting from exposure to high-energy flux. The radiation in this context is associated with ionizing radiation; radiolysis is therefore distinguished from, for example, photolysis of the Cl2 molecule into two Cl- radicals, where (ultraviolet or visible spectrum) light is used. The chemistry of concentrated solutions under ionizing radiation is extremely complex. Radiolysis can locally modify redox conditions, and therefore the speciation and the solubility of the compounds. Water decomposition Of all the radiation-based chemical reactions that have been studied, the most important is the decomposition of water. When exposed to radiation, water undergoes a breakdown sequence into hydrogen peroxide, hydrogen radicals, and assorted oxygen compounds, such as ozone, which when converted back into oxygen releases great amounts of energy. Some of these are explosive ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tunnel Ionization
In physics, tunnel ionization is a process in which electrons in an atom (or a molecule) tunnel through the potential barrier and escape from the atom (or molecule). In an intense electric field, the potential barrier of an atom (molecule) is distorted drastically. Therefore, as the length of the barrier that electrons have to pass decreases, the electrons can escape from the atom's potential more easily. Tunneling ionization is a quantum mechanical phenomenon since in the classical picture an electron does not have sufficient energy to overcome the potential barrier of the atom. When the atom is in a DC external field, the Coulomb potential barrier is lowered and the electron has an increased, non-zero probability of tunnelling through the potential barrier. In the case of an alternating electric field, the direction of the electric field reverses after the half period of the field. The ionized electron may come back to its parent ion. The electron may recombine with the nucleus (n ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Quantum Tunnelling
In physics, quantum tunnelling, barrier penetration, or simply tunnelling is a quantum mechanical phenomenon in which an object such as an electron or atom passes through a potential energy barrier that, according to classical mechanics, should not be passable due to the object not having sufficient energy to pass or surmount the barrier. Tunneling is a consequence of the wave nature of matter, where the quantum wave function describes the state of a particle or other physical system, and wave equations such as the Schrödinger equation describe their behavior. The probability of transmission of a wave packet through a barrier decreases exponentially with the barrier height, the barrier width, and the tunneling particle's mass, so tunneling is seen most prominently in low-mass particles such as electrons or protons tunneling through microscopically narrow barriers. Tunneling is readily detectable with barriers of thickness about 1–3 nm or smaller for electrons, and abou ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bound State
A bound state is a composite of two or more fundamental building blocks, such as particles, atoms, or bodies, that behaves as a single object and in which energy is required to split them. In quantum physics, a bound state is a quantum state of a particle subject to a potential energy, potential such that the particle has a tendency to remain localized in one or more regions of space. The potential may be external or it may be the result of the presence of another particle; in the latter case, one can equivalently define a bound state as a state representing two or more particles whose interaction energy exceeds the total energy of each separate particle. One consequence is that, given a potential vanish at infinity, vanishing at infinity, negative-energy states must be bound. The energy spectrum of the set of bound states are most commonly discrete, unlike scattering states of Free particle, free particles, which have a continuous spectrum. Although not bound states in the stric ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Photoelectron Spectrum
Photoemission spectroscopy (PES), also known as photoelectron spectroscopy, refers to energy measurement of electrons emitted from solids, gases or liquids by the photoelectric effect, in order to determine the binding energies of electrons in the substance. The term refers to various techniques, depending on whether the ionization energy is provided by X-ray, EUV or UV photons. Regardless of the incident photon beam, however, all photoelectron spectroscopy revolves around the general theme of surface analysis by measuring the ejected electrons. Types X-ray photoelectron spectroscopy (XPS) was developed by Kai Siegbahn starting in 1957 and is used to study the energy levels of atomic core electrons, primarily in solids. Siegbahn referred to the technique as "electron spectroscopy for chemical analysis" (ESCA), since the core levels have small chemical shifts depending on the chemical environment of the atom that is ionized, allowing chemical structure to be determined. Siegba ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Kinetic Energy
In physics, the kinetic energy of an object is the form of energy that it possesses due to its motion. In classical mechanics, the kinetic energy of a non-rotating object of mass ''m'' traveling at a speed ''v'' is \fracmv^2.Resnick, Robert and Halliday, David (1960) ''Physics'', Section 7-5, Wiley International Edition The kinetic energy of an object is equal to the work, or force ( F) in the direction of motion times its displacement ( s), needed to accelerate the object from rest to its given speed. The same amount of work is done by the object when decelerating from its current speed to a state of rest. The SI unit of energy is the joule, while the English unit of energy is the foot-pound. In relativistic mechanics, \fracmv^2 is a good approximation of kinetic energy only when ''v'' is much less than the speed of light. History and etymology The adjective ''kinetic'' has its roots in the Greek word κίνησις ''kinesis'', meaning "motion". The dichoto ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
