YBCO
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YBCO
Yttrium barium copper oxide (YBCO) is a family of crystalline chemical compounds that display high-temperature superconductivity; it includes the first material ever discovered to become superconducting above the boiling point of liquid nitrogen (77 K) at about 93 K. Many YBCO compounds have the general formula Y Ba2 Cu3 O7−''x'' (also known as Y123), although materials with other Y:Ba:Cu ratios exist, such as Y Ba2 Cu4 Oy (Y124) or Y2 Ba4 Cu7 Oy (Y247). At present, there is no singularly recognised theory for high-temperature superconductivity. It is part of the more general group of rare-earth barium copper oxides (ReBCO) in which, instead of yttrium, other rare earths are present. History In April 1986, Georg Bednorz and Karl Müller, working at IBM in Zurich, discovered that certain semiconducting oxides became superconducting at relatively high temperature, in particular, a lanthanum barium copper oxide becomes superconducting at 35 K. This oxide was an oxyg ...
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High-temperature Superconductor
High-temperature superconductors (abbreviated high-c or HTS) are defined as materials that behave as superconductors at temperatures above , the boiling point of liquid nitrogen. The adjective "high temperature" is only in respect to previously known superconductors, which function at even colder temperatures close to absolute zero. In absolute terms, these "high temperatures" are still far below ambient, and therefore require cooling. The first high-temperature superconductor was discovered in 1986, by IBM researchers Bednorz and Müller, who were awarded the Nobel Prize in Physics in 1987 "for their important break-through in the discovery of superconductivity in ceramic materials". Most high-c materials are type-II superconductors. The major advantage of high-temperature superconductors is that they can be cooled by using liquid nitrogen, as opposed to the previously known superconductors which require expensive and hard-to-handle coolants, primarily liquid helium. ...
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High-temperature Superconductivity
High-temperature superconductors (abbreviated high-c or HTS) are defined as materials that behave as superconductors at temperatures above , the boiling point of liquid nitrogen. The adjective "high temperature" is only in respect to previously known superconductors, which function at even colder temperatures close to absolute zero. In absolute terms, these "high temperatures" are still far below ambient, and therefore require cooling. The first high-temperature superconductor was discovered in 1986, by IBM researchers Bednorz and Müller, who were awarded the Nobel Prize in Physics in 1987 "for their important break-through in the discovery of superconductivity in ceramic materials". Most high-c materials are type-II superconductors. The major advantage of high-temperature superconductors is that they can be cooled by using liquid nitrogen, as opposed to the previously known superconductors which require expensive and hard-to-handle coolants, primarily liquid helium. ...
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Rare-earth Barium Copper Oxide
Rare-earth barium copper oxide (also referred to as ReBCO) is a family of chemical compounds known for exhibiting high temperature superconductivity (HTS). ReBCO superconductors have the potential to sustain stronger magnetic fields than other superconductor materials. Due to their stronger magnetic field and relatively high superconducting critical temperature, this materials are proposed for future use in technical applications. This includes magnetic confinement fusion reactors such as the ARC reactor, allowing a more compact and potentially more economical construction, and superconducting magnets to use in future particle accelerators to come after the LHC at CERN which utilizes low-temperature superconductors. The most famous of these is yttrium barium copper oxide, YBa2Cu3O7−x (or Y123), the first superconductor found with a critical temperature above the boiling point of liquid nitrogen. Its molar ratio is 1 to 2 to 3 for yttrium, barium, and copper and it has a unit c ...
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Yttrium
Yttrium is a chemical element with the symbol Y and atomic number 39. It is a silvery-metallic transition metal chemically similar to the lanthanides and has often been classified as a "rare-earth element". Yttrium is almost always found in combination with lanthanide elements in rare-earth minerals, and is never found in nature as a free element. 89Y is the only stable isotope, and the only isotope found in the Earth's crust. The most important uses of yttrium are LEDs and phosphors, particularly the red phosphors in television set cathode ray tube displays. Yttrium is also used in the production of electrodes, electrolytes, electronic filters, lasers, superconductors, various medical applications, and tracing various materials to enhance their properties. Yttrium has no known biological role. Exposure to yttrium compounds can cause lung disease in humans. The element is named after '' ytterbite'', a mineral first identified in 1787 by the chemist Carl Axel Arrhenius. He n ...
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Superconductivity
Superconductivity is a set of physical properties observed in certain materials where electrical resistance vanishes and magnetic flux fields are expelled from the material. Any material exhibiting these properties is a superconductor. Unlike an ordinary metallic conductor, whose resistance decreases gradually as its temperature is lowered even down to near absolute zero, a superconductor has a characteristic critical temperature below which the resistance drops abruptly to zero. An electric current through a loop of superconducting wire can persist indefinitely with no power source. The superconductivity phenomenon was discovered in 1911 by Dutch physicist Heike Kamerlingh Onnes. Like ferromagnetism and atomic spectral lines, superconductivity is a phenomenon which can only be explained by quantum mechanics. It is characterized by the Meissner effect, the complete ejection of magnetic field lines from the interior of the superconductor during its transitions into the sup ...
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Barium
Barium is a chemical element with the symbol Ba and atomic number 56. It is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element. The most common minerals of barium are baryte ( barium sulfate, BaSO4) and witherite (barium carbonate, BaCO3). The name ''barium'' originates from the alchemical derivative "baryta", from Greek (), meaning 'heavy'. ''Baric'' is the adjectival form of barium. Barium was identified as a new element in 1774, but not reduced to a metal until 1808 with the advent of electrolysis. Barium has few industrial applications. Historically, it was used as a getter for vacuum tubes and in oxide form as the emissive coating on indirectly heated cathodes. It is a component of YBCO (high-temperature superconductors) and electroceramics, and is added to steel and cast iron to reduce the size of carbon grains within the microstructure. Barium compounds ar ...
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Georg Bednorz
Johannes Georg Bednorz (; born 16 May 1950) is a German physicist who, together with K. Alex Müller, discovered high-temperature superconductivity in ceramics, for which they shared the 1987 Nobel Prize in Physics. Life and work Bednorz was born in Neuenkirchen, North Rhine-Westphalia, Germany to elementary-school teacher Anton and piano teacher Elisabeth Bednorz, as the youngest of four children. His parents were both from Silesia in Central Europe, but were forced to move westwards in turbulences of World War II. including the Nobel Lecture, December 8, 1987 ''Perovskite-Type Oxides – The New Approach to High-Tc Superconductivity'' As a child, his parents tried to get him interested in classical music, but he was more practically inclined, preferring to work on motorcycles and cars. (Although as a teenager he did eventually learn to play the violin and trumpet.) In high school he developed an interest in the natural sciences, focusing on chemistry, which he could learn in a ...
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Sintering
Clinker nodules produced by sintering Sintering or frittage is the process of compacting and forming a solid mass of material by pressure or heat without melting it to the point of liquefaction. Sintering happens as part of a manufacturing process used with metals, ceramics, plastics, and other materials. The atoms in the materials diffuse across the boundaries of the particles, fusing the particles together and creating one solid piece. Because the sintering temperature does not have to reach the melting point of the material, sintering is often chosen as the shaping process for materials with extremely high melting points such as tungsten and molybdenum. The study of sintering in metallurgical powder-related processes is known as powder metallurgy. An example of sintering can be observed when ice cubes in a glass of water adhere to each other, which is driven by the temperature difference between the water and the ice. Examples of pressure-driven sintering are the compact ...
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Tesla (unit)
The tesla (symbol: T) is the unit of magnetic flux density (also called magnetic B-field strength) in the International System of Units (SI). One tesla is equal to one weber per square metre. The unit was announced during the General Conference on Weights and Measures in 1960 and is named in honour of Serbian-American electrical and mechanical engineer Nikola Tesla, upon the proposal of the Slovenian electrical engineer France Avčin. Definition A particle, carrying a charge of one coulomb (C), and moving perpendicularly through a magnetic field of one tesla, at a speed of one metre per second (m/s), experiences a force with magnitude one newton (N), according to the Lorentz force law. That is, : \text = \dfrac. As an SI derived unit, the tesla can also be expressed in terms of other units. For example, a magnetic flux of 1 weber (Wb) through a surface of one square meter is equal to a magnetic flux density of 1 tesla.''The International System of Units (SI), 8th ...
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Liquid Helium
Liquid helium is a physical state of helium at very low temperatures at standard atmospheric pressures. Liquid helium may show superfluidity. At standard pressure, the chemical element helium exists in a liquid form only at the extremely low temperature of . Its boiling point and critical point depend on which isotope of helium is present: the common isotope helium-4 or the rare isotope helium-3. These are the only two stable isotopes of helium. See the table below for the values of these physical quantities. The density of liquid helium-4 at its boiling point and a pressure of one atmosphere (101.3 kilopascals) is about , or about one-eighth the density of liquid water. Liquefaction Helium was first liquefied on July 10, 1908, by the Dutch physicist Heike Kamerlingh Onnes at the University of Leiden in the Netherlands. At that time, helium-3 was unknown because the mass spectrometer had not yet been invented. In more recent decades, liquid helium has been used as a cryogenic ref ...
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Grain Boundary
In materials science, a grain boundary is the interface between two grains, or crystallites, in a polycrystalline material. Grain boundaries are two-dimensional defects in the crystal structure, and tend to decrease the electrical and thermal conductivity of the material. Most grain boundaries are preferred sites for the onset of corrosion and for the precipitation of new phases from the solid. They are also important to many of the mechanisms of creep. On the other hand, grain boundaries disrupt the motion of dislocations through a material, so reducing crystallite size is a common way to improve mechanical strength, as described by the Hall–Petch relationship. High and low angle boundaries It is convenient to categorize grain boundaries according to the extent of misorientation between the two grains. ''Low-angle grain boundaries'' (''LAGB'') or ''subgrain boundaries'' are those with a misorientation less than about 15 degrees. Generally speaking they are composed of a ...
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Lanthanum Barium Copper Oxide
Lanthanum barium copper oxide, or LBCO, is an inorganic compound with the formula CuBa0.15La1.85O4. It is a black solid produced by heating an intimate mixture of barium oxide, copper(II) oxide, and lanthanum oxide in the presence of oxygen. The material was discovered in 1986 and was the first high temperature superconductor. Johannes Georg Bednorz and K. Alex Müller shared the 1987 Nobel Prize in physics for the discovery that this material exhibits superconductivity at the then unusually high temperature. This finding led to intense and fruitful efforts to generate other cuprate superconductor Cuprate superconductors are a family of high-temperature superconducting materials made of layers of copper oxides (CuO2) alternating with layers of other metal oxides, which act as charge reservoirs. At ambient pressure, cuprate superconductor ...s. Lanthanum barium copper oxide is related to the far simpler compound lanthanum cuprate, which has a similar structure. In lan ...
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