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Octasulfur
Octasulfur is an inorganic substance with the chemical formula . It is an odourless and tasteless yellow solid, and is a major industrial chemical. It is the most common allotrope of sulfur and occurs widely in nature.Steudel, R., "Homocyclic Sulfur Molecules", Topics Curr. Chem. 1982, 102, 149. Nomenclature The name octasulfur is the most commonly used for this chemical. It is systematically named ''cyclo''-octasulfur (which is the preferred IUPAC name) and cyclooctasulfane. It is also the final member of the thiocane heterocylic series, where every carbon atom is substituted with a sulfur atom, thus this sulfur allotrope is systematically named octathiocane as well. Structure The chemical consists of rings of 8 sulfur atoms. It adopts a crown conformation with D4d point group symmetry. The S–S bond lengths are equal, at about 2.05 Å. Octasulfur crystallizes in three distinct polymorphs: rhombohedral, and two monoclinic forms, of which only two are stable at standard ...
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Hexathiane
Hexasulfur is an inorganic chemical with the chemical formula . Nomenclature The name hexasulfur is the most commonly used and preferred IUPAC name and is constructed according to the compositional nomenclature, and cyclohexasulfane. It is also the final member of the thiane heterocyclic series, where every carbon atom is substituted with a sulfur atom, thus the systematic name hexathiane, a valid IUPAC name, is constructed according to the substitutive nomenclature. Another valid IUPAC systematic name ''cyclo''-hexasulfur is constructed according to the additive nomenclature. Structure This chemical consists of rings of 6 sulfur atoms. It is thus a simple cyclosulfane and an allotrope of sulfur. Hexasulfur adopts a chair configuration In organic chemistry, cyclohexane conformations are any of several three-dimensional shapes adopted by molecules of cyclohexane. Because many compounds feature structurally similar six-membered rings, the structure and dynamics of cyclohe ...
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Allotrope
Allotropy or allotropism () is the property of some chemical elements to exist in two or more different forms, in the same physical State of matter, state, known as allotropes of the elements. Allotropes are different structural modifications of an element: the atoms of the element are Chemical bond, bonded together in a different manner. For example, the allotropes of carbon include diamond (the carbon atoms are bonded together to form a Cubic crystal system, cubic lattice of Tetrahedral molecular geometry, tetrahedra), graphite (the carbon atoms are bonded together in sheets of a hexagonal lattice), graphene (single sheets of graphite), and fullerenes (the carbon atoms are bonded together in spherical, tubular, or ellipsoidal formations). The term ''allotropy'' is used for elements only, not for Chemical compound, compounds. The more general term, used for any compound, is Polymorphism (materials science), polymorphism, although its use is usually restricted to solid materials ...
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Sulfur
Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula S8. Elemental sulfur is a bright yellow, crystalline solid at room temperature. Sulfur is the tenth most abundant element by mass in the universe and the fifth most on Earth. Though sometimes found in pure, native form, sulfur on Earth usually occurs as sulfide and sulfate minerals. Being abundant in native form, sulfur was known in ancient times, being mentioned for its uses in ancient India, ancient Greece, China, and ancient Egypt. Historically and in literature sulfur is also called brimstone, which means "burning stone". Today, almost all elemental sulfur is produced as a byproduct of removing sulfur-containing contaminants from natural gas and petroleum.. Downloahere The greatest commercial use of the element is the production ...
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Claus Process
The Claus process is the most significant gas desulfurizing process, recovering elemental sulfur from gaseous hydrogen sulfide. First patented in 1883 by the chemist Carl Friedrich Claus, the Claus process has become the industry standard. The multi-step Claus process recovers sulfur from the gaseous hydrogen sulfide found in raw natural gas and from the by-product gases containing hydrogen sulfide derived from refining crude oil and other industrial processes. The by-product gases mainly originate from physical and chemical gas treatment units ( Selexol, Rectisol, Purisol and amine scrubbers) in refineries, natural gas processing plants and gasification or synthesis gas plants. These by-product gases may also contain hydrogen cyanide, hydrocarbons, sulfur dioxide or ammonia. Gases with an H2S content of over 25% are suitable for the recovery of sulfur in straight-through Claus plants while alternate configurations such as a split-flow set up or feed and air preheating ...
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Native Element Minerals
Native element minerals are those chemical element, elements that occur in nature in Free element, uncombined form with a distinct mineral structure. The elemental class includes native metal, metals, intermetallic compounds, alloys, metalloids, and nonmetals. The Nickel–Strunz classification system also includes the naturally occurring phosphides, silicides, nitrides, carbides, and arsenides. Elements The following elements occur as native element minerals or alloys: Nickel–Strunz Classification -01- Native elements This list uses the Strunz classification, Classification of Nickel–Strunz (mindat.org, 10 ed, pending publication). ;Abbreviations: * "*" – discredited (IMA/CNMNC status). * "?" – questionable/doubtful (IMA/CNMNC status). * "REE" – Rare-earth element (Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) * "PGE" – Platinum group, Platinum-group element (Ru, Rh, Pd, Os, Ir, Pt) * 03.C Aluminofluorides, 06 Borates, 08 Vanadates (04. ...
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Dietary Minerals
In the context of nutrition, a mineral is a chemical element required as an essential nutrient by organisms to perform functions necessary for life. However, the four major structural elements in the human body by weight (oxygen, hydrogen, carbon, and nitrogen), are usually not included in lists of major nutrient minerals (nitrogen is considered a "mineral" for plants, as it often is included in fertilizers). These four elements compose about 96% of the weight of the human body, and major minerals (macrominerals) and minor minerals (also called trace elements) compose the remainder. Nutrient minerals, being elements, cannot be synthesized biochemically by living organisms. Plants get minerals from soil. Most of the minerals in a human diet come from eating plants and animals or from drinking water. As a group, ''minerals'' are one of the four groups of essential nutrients, the others of which are vitamins, essential fatty acids, and essential amino acids. The five major minerals ...
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Biology And Pharmacology Of Chemical Elements
Biology is the scientific study of life. It is a natural science with a broad scope but has several unifying themes that tie it together as a single, coherent field. For instance, all organisms are made up of cells that process hereditary information encoded in genes, which can be transmitted to future generations. Another major theme is evolution, which explains the unity and diversity of life. Energy processing is also important to life as it allows organisms to move, grow, and reproduce. Finally, all organisms are able to regulate their own internal environments. Biologists are able to study life at multiple levels of organization, from the molecular biology of a cell to the anatomy and physiology of plants and animals, and evolution of populations.Based on definition from: Hence, there are multiple subdisciplines within biology, each defined by the nature of their research questions and the tools that they use. Like other scientists, biologists use the scientific me ...
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Agricultural Chemicals
An agrochemical or agrichemical, a contraction of ''agricultural chemical'', is a chemical product used in industrial agriculture. Agrichemical refers to biocides (pesticides including insecticides, herbicides, fungicides and nematicides) and synthetic fertilizers. It may also include hormones and other chemical growth agents. Agrochemicals are counted among speciality chemicals. Categories Biological action In most of the cases, agrochemicals refer to pesticides. *Pesticides **Insecticides **Herbicides **Fungicides **Algaecides ** Rodenticides **Molluscicides ** Nematicides * Fertilisers *Soil conditioners * Liming and acidifying agents * Plant growth regulators Application method *Fumigants * Penetrant Ecology Many agrochemicals are toxic, and agrichemicals in bulk storage may pose significant environmental and/or health risks, particularly in the event of accidental spills. In many countries, use of agrichemicals is highly regulated. Government-issued permits for purch ...
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Sulfur (pharmacy)
Sulfur is used in pharmaceutical skin preparations for the treatment of acne and other conditions. it acts as a keratolytic agent and also kills bacteria, fungi, scabies mites and other parasites. Chemically, it is the naturally occurring octasulfur (S8). Forms and uses * ''Flower of sulfur'' or ''sublimed sulfur'' (Latin: ''sulfur sublimatum'') is the naturally occurring, unpurified form. It comes in yellow flakes and has been used in traditional and alternative medicine for humans and animals, as well as in alchemy and sulfuring fruit before drying. * ''Purified sulfur'' (''sulfur depuratum'') is prepared by washing sublimed sulfur with ammonia. It is a fine yellow powder. It was formerly used as a laxative, but this application is rare today. * ''Precipitated sulfur'' (''sulfur praecipitatum'') is prepared by boiling sulfur and calcium oxide in water and then precipitating with hydrochloric acid. It, too, is a fine yellow powder. * ''Colloidal sulfur'' (''sulfur colloidale'' ...
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Polymorphism (materials Science)
In materials science, polymorphism describes the existence of a solid material in more than one form or crystal structure. Polymorphism is a form of isomerism. Any crystalline material can exhibit the phenomenon. Allotropy refers to polymorphism for chemical elements. Polymorphism is of practical relevance to pharmaceuticals, agrochemicals, pigments, dyestuffs, foods, and explosives. According to IUPAC, a polymorphic transition is "A reversible transition of a solid crystalline phase at a certain temperature and pressure (the inversion point) to another phase of the same chemical composition with a different crystal structure." According to McCrone, polymorphs are "different in crystal structure but identical in the liquid or vapor states." Materials with two polymorphs are called dimorphic, with three polymorphs, trimorphic, etc. Examples Many compounds exhibit polymorphism. It has been claimed that "every compound has different polymorphic forms, and that, in general, th ...
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Standard State
In chemistry, the standard state of a material (pure substance, mixture or solution) is a reference point used to calculate its properties under different conditions. A superscript circle ° (degree symbol) or a Plimsoll (⦵) character is used to designate a thermodynamic quantity in the standard state, such as change in enthalpy (Δ''H''°), change in entropy (Δ''S''°), or change in Gibbs free energy (Δ''G''°). The degree symbol has become widespread, although the Plimsoll is recommended in standards, see discussion about typesetting below. In principle, the choice of standard state is arbitrary, although the International Union of Pure and Applied Chemistry (IUPAC) recommends a conventional set of standard states for general use. The standard state should not be confused with standard temperature and pressure (STP) for gases, nor with the standard solutions used in analytical chemistry. STP is commonly used for calculations involving gases that approximate an ideal ...
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Inorganic Chemistry
Inorganic chemistry deals with synthesis and behavior of inorganic and organometallic compounds. This field covers chemical compounds that are not carbon-based, which are the subjects of organic chemistry. The distinction between the two disciplines is far from absolute, as there is much overlap in the subdiscipline of organometallic chemistry. It has applications in every aspect of the chemical industry, including catalysis, materials science, pigments, surfactants, coatings, medications, fuels, and agriculture. Key concepts Many inorganic compounds are ionic compounds, consisting of cations and anions joined by ionic bonding. Examples of salts (which are ionic compounds) are magnesium chloride MgCl2, which consists of magnesium cations Mg2+ and chloride anions Cl−; or sodium oxide Na2O, which consists of sodium cations Na+ and oxide anions O2−. In any salt, the proportions of the ions are such that the electric charges cancel out, so that the bulk compound is ele ...
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