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Lead Oxide
Lead oxides are a group of inorganic compounds with formulas including lead (Pb) and oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ... (O). Common lead oxides include: * Lead(II) oxide, PbO, litharge (red), massicot (yellow) * Lead tetroxide or ''red lead'', , minium, which is a lead (II,IV) oxide and may be thought of as lead(II) orthoplumbate(IV) , vivid orange crystals * Lead dioxide (lead(IV) oxide), , dark-brown or black powder Less common lead oxides are: * Lead sesquioxide, , which is a lead (II,IV) oxide as well ( lead(II) metaplumbate(IV) ), reddish yellow * , monoclinic, dark-brown or black crystals * The so-called ''black lead oxide'', which is a mixture of PbO and fine-powdered Pb metal and used in the production of lead–acid batteries. {{Authority ...
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Inorganic Compound
An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds⁠that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''. Inorganic compounds comprise most of the Earth's crust, although the compositions of the deep Mantle (geology), mantle remain active areas of investigation. All allotropes (structurally different pure forms of an element) and some simple carbon compounds are often considered inorganic. Examples include the allotropes of carbon (graphite, diamond, buckminsterfullerene, graphene, etc.), carbon monoxide , carbon dioxide , carbides, and salt (chemistry), salts of inorganic anions such as carbonates, cyanides, cyanates, thiocyanates, isothiocyanates, etc. Many of these are normal parts of mostly organic systems, including organisms; describing a chemical as inorganic does not necessarily mean that it cannot occur within life, living things. History ...
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Chemical Formula
A chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, such as parentheses, dashes, brackets, commas and ''plus'' (+) and ''minus'' (−) signs. These are limited to a single typographic line of symbols, which may include subscripts and superscripts. A chemical formula is not a chemical name since it does not contain any words. Although a chemical formula may imply certain simple chemical structures, it is not the same as a full chemical structural formula. Chemical formulae can fully specify the structure of only the simplest of molecules and chemical substances, and are generally more limited in power than chemical names and structural formulae. The simplest types of chemical formulae are called '' empirical formulae'', which use letters and numbers indicating the numerical ''proportions'' of atoms ...
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Lead
Lead () is a chemical element; it has Chemical symbol, symbol Pb (from Latin ) and atomic number 82. It is a Heavy metal (elements), heavy metal that is density, denser than most common materials. Lead is Mohs scale, soft and Ductility, malleable, and also has a relatively low melting point. When freshly cut, lead is a shiny gray with a hint of blue. It tarnishes to a dull gray color when exposed to air. Lead has the highest atomic number of any stable nuclide, stable element and three of its isotopes are endpoints of major nuclear decay chains of heavier elements. Lead is a relatively unreactive post-transition metal. Its weak metallic character is illustrated by its Amphoterism, amphoteric nature; lead and lead oxides react with acids and base (chemistry), bases, and it tends to form covalent bonds. Lead compounds, Compounds of lead are usually found in the +2 oxidation state rather than the +4 state common with lighter members of the carbon group. Exceptions are mostly limited ...
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Oxygen
Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), nonmetal, and a potent oxidizing agent that readily forms oxides with most elements as well as with other chemical compound, compounds. Oxygen is abundance of elements in Earth's crust, the most abundant element in Earth's crust, making up almost half of the Earth's crust in the form of various oxides such as water, carbon dioxide, iron oxides and silicates.Atkins, P.; Jones, L.; Laverman, L. (2016).''Chemical Principles'', 7th edition. Freeman. It is abundance of chemical elements, the third-most abundant element in the universe after hydrogen and helium. At standard temperature and pressure, two oxygen atoms will chemical bond, bind covalent bond, covalently to form dioxygen, a colorless and odorless diatomic gas with the chemical formula ...
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Lead(II) Oxide
Lead(II) oxide, also called lead monoxide, is the inorganic compound with the molecular formula Pb O. It occurs in two polymorphs: litharge having a tetragonal crystal structure, and massicot having an orthorhombic crystal structure. Modern applications for PbO are mostly in lead-based industrial glass and industrial ceramics, including computer components. Types Lead oxide exists in two polymorphs: * Red tetragonal (α-PbO), obtained at temperatures below * Yellow orthorhombic (β-PbO), obtained at temperatures above Synthesis PbO may be prepared by heating lead metal in air at approximately . At this temperature it is also the end product of decomposition of other oxides of lead in air: :PbO2->[] Pb12O19 ->[] Pb12O17 ->[] Pb3O4 ->[] PbO Thermal decomposition of lead(II) nitrate or lead carbonate, lead(II) carbonate also results in the formation of PbO: :2  → 2 PbO + 4  + : → PbO + PbO is produced on a large scale as an intermediate product in ...
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Litharge
Litharge (from Greek , 'stone' + 'silver' ) is one of the natural mineral forms of lead(II) oxide, PbO. Litharge is a secondary mineral which forms from the oxidation of galena ores. It forms as coatings and encrustations with internal tetragonal crystal structure. It is dimorphous with the yellow orthorhombic form massicot. It forms soft ( Mohs hardness of 2), red, greasy-appearing crusts with a very high specific gravity of 9.14–9.35. PbO may be prepared by heating lead metal in air at approximately 600 °C (lead melts at only 300 °C). At this temperature it is also the end product of heating of other lead oxides in air. This is often done with a set of bellows pumping air over molten lead and causing the oxidized product to slip or fall off the top into a receptacle, where it quickly solidifies in minute scales. :PbO2 –(293 °C)→ Pb12O19 –(351 °C)→ Pb12O17 –(375 °C)→ Pb3O4 –(605 °C)→ PbO Historical terminology Historically, the term ' ...
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Massicot
Massicot is lead (II) oxide mineral with an orthorhombic lattice structure. Lead(II) oxide (formula: PbO) can occur in one of two lattice formats, orthorhombic and tetragonal. The red tetragonal form is called litharge. PbO can be changed from massicot to litharge (or vice versa) by controlled heating and cooling. At room temperature massicot forms soft (Mohs hardness of 2) yellow to reddish-yellow, earthy, scaley masses which are very dense, with a specific gravity of 9.64. Massicot can be found as a natural mineral, though it is only found in minor quantities. In bygone centuries it was mined. Nowadays massicot arises during industrial processing of lead and lead oxides, especially in the glass industry, which is the biggest user of PbO. The definition of massicot as orthorhombic PbO dates from the 1840s, but the substance massicot and the name massicot has been in use since the late medieval era. There is some evidence that the ancient Romans used the substance.
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Lead Tetroxide
Lead(II,IV) oxide, also called red lead or minium, is the inorganic compound with the formula . A bright red or orange solid, it is used as pigment, in the manufacture of batteries, and rustproof primer paints. It is an example of a mixed valence compound, being composed of both Pb(II) and Pb(IV) in the ratio of two to one. Structure Lead(II,IV) oxide is lead(II) orthoplumbate(IV) . It has a tetragonal crystal structure at room temperature, which then transforms to an orthorhombic ( Pearson symbol ''oP''28, Space group Pbam, No. 55) form at temperature . This phase transition only changes the symmetry of the crystal and slightly modifies the interatomic distances and angles. File:Red-lead-unit-cell-3D-balls.png, Unit cell of tetragonal (Key: Pb O) File:Red-lead-3D-balls.png, Part of tetragonal red lead's crystal structure Preparation Lead(II,IV) oxide is prepared by calcination of lead(II) oxide (PbO; also called litharge) in air at about 450–480 °C: : ...
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Minium (mineral)
Minium is the naturally occurring form of lead tetroxide, Pb2+2Pb4+O4 also known as red lead. Minium is a light-to-vivid red and may have brown-to-yellow tints. It typically occurs in scaly-to-earthy masses. It crystallizes in the tetragonal crystal system. Minium is rare and occurs in lead-mineral deposits that have been subjected to severe oxidizing conditions. It also occurs as a result of mine fires. It is associated with cerussite, galena, litharge, massicot, mimetite, native lead, and wulfenite. It occurs in relatively small amounts throughout the world: , Hesse; Badenweiler, Baden-Württemberg; Bleialf, Eifel district; Horhausen (), Rhineland-Palatinate in Germany. It occurs at Mies, Slovenia; Leadhills, Lanarkshire, Scotland; Castelberg St. Avold, Moselle, France; from Langban, Varmland, Sweden; Sarrabus, Sardinia, Italy; near Anarak, Iran; and Tsumeb, Namibia. In the US, mines include the Jay Gould mine, Alturas County, Idaho; the Leadville district, Lake County, C ...
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Lead Dioxide
Lead(IV) oxide, commonly known as lead dioxide, is an inorganic compound with the chemical formula . It is an oxide where lead is in an oxidation state of +4. It is a dark-brown solid which is insoluble in water. It exists in two crystalline forms. It has several important applications in electrochemistry, in particular as the positive plate of lead acid batteries. Properties Physical Lead dioxide has two major polymorphs, alpha and beta, which occur naturally as rare minerals scrutinyite and plattnerite, respectively. Whereas the beta form had been identified in 1845, α- was first identified in 1946 and found as a naturally occurring mineral 1988. The alpha form has orthorhombic symmetry, space group Pbcn (No. 60), Pearson symbol ''oP''12, lattice constants ''a'' = 0.497 nm, ''b'' = 0.596 nm, ''c'' = 0.544 nm, ''Z'' = 4 (four formula units per unit cell). The lead atoms are six-coordinate. The symmetry of the beta form is tetragonal, space group P42/mnm ...
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Sesquioxide
A sesquioxide is an oxide of an element (or radical), where the ratio between the number of atoms of that element and the number of atoms of oxygen is 2:3. For example, aluminium oxide and phosphorus(III) oxide are sesquioxides. Many sesquioxides contain a metal in the +3 oxidation state and the oxide ion , e.g., aluminium oxide , lanthanum(III) oxide and iron(III) oxide . Sesquioxides of iron and aluminium are found in soil. The alkali metal sesquioxides are exceptions because they contain both peroxide and superoxide ions, e.g., rubidium sesquioxide is formulated . Sesquioxides of metalloids and nonmetals are better formulated as covalent, e.g. boron trioxide , dinitrogen trioxide and phosphorus(III) oxide ; chlorine trioxide and bromine trioxide do not have oxidation state +3 on the halogen. Many transition metal oxides crystallize in the corundum structure type, with space group Rc. Sesquioxides of rare earth elements crystalize into one or more of three crystal ...
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