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Litharge
Litharge (from Greek , 'stone' + 'silver' ) is one of the natural mineral forms of lead(II) oxide, PbO. Litharge is a secondary mineral which forms from the oxidation of galena ores. It forms as coatings and encrustations with internal tetragonal crystal structure. It is dimorphous with the yellow orthorhombic form massicot. It forms soft ( Mohs hardness of 2), red, greasy-appearing crusts with a very high specific gravity of 9.14–9.35. PbO may be prepared by heating lead metal in air at approximately 600 °C (lead melts at only 300 °C). At this temperature it is also the end product of heating of other lead oxides in air. This is often done with a set of bellows pumping air over molten lead and causing the oxidized product to slip or fall off the top into a receptacle, where it quickly solidifies in minute scales. :PbO2 –(293 °C)→ Pb12O19 –(351 °C)→ Pb12O17 –(375 °C)→ Pb3O4 –(605 °C)→ PbO Historical terminology Historically, the term ' ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lead(II) Oxide
Lead(II) oxide, also called lead monoxide, is the inorganic compound with the molecular formula Pb O. It occurs in two polymorphs: litharge having a tetragonal crystal structure, and massicot having an orthorhombic crystal structure. Modern applications for PbO are mostly in lead-based industrial glass and industrial ceramics, including computer components. Types Lead oxide exists in two polymorphs: * Red tetragonal (α-PbO), obtained at temperatures below * Yellow orthorhombic (β-PbO), obtained at temperatures above Synthesis PbO may be prepared by heating lead metal in air at approximately . At this temperature it is also the end product of decomposition of other oxides of lead in air: :PbO2->[] Pb12O19 ->[] Pb12O17 ->[] Pb3O4 ->[] PbO Thermal decomposition of lead(II) nitrate or lead carbonate, lead(II) carbonate also results in the formation of PbO: :2 → 2 PbO + 4 + : → PbO + PbO is produced on a large scale as an intermediate product in ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Massicot
Massicot is lead (II) oxide mineral with an orthorhombic lattice structure. Lead(II) oxide (formula: PbO) can occur in one of two lattice formats, orthorhombic and tetragonal. The red tetragonal form is called litharge. PbO can be changed from massicot to litharge (or vice versa) by controlled heating and cooling. At room temperature massicot forms soft (Mohs hardness of 2) yellow to reddish-yellow, earthy, scaley masses which are very dense, with a specific gravity of 9.64. Massicot can be found as a natural mineral, though it is only found in minor quantities. In bygone centuries it was mined. Nowadays massicot arises during industrial processing of lead and lead oxides, especially in the glass industry, which is the biggest user of PbO. The definition of massicot as orthorhombic PbO dates from the 1840s, but the substance massicot and the name massicot has been in use since the late medieval era. There is some evidence that the ancient Romans used the substance. [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lead Minerals
Lead () is a chemical element; it has symbol Pb (from Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cut, lead is a shiny gray with a hint of blue. It tarnishes to a dull gray color when exposed to air. Lead has the highest atomic number of any stable element and three of its isotopes are endpoints of major nuclear decay chains of heavier elements. Lead is a relatively unreactive post-transition metal. Its weak metallic character is illustrated by its amphoteric nature; lead and lead oxides react with acids and bases, and it tends to form covalent bonds. Compounds of lead are usually found in the +2 oxidation state rather than the +4 state common with lighter members of the carbon group. Exceptions are mostly limited to organolead compounds. Like the lighter members of the group, lead tends to bond with itself; it can form chains and polyhe ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lead Oxide (other)
Lead oxides are a group of inorganic compounds with formulas including lead (Pb) and oxygen (O). Common lead oxides include: * Lead(II) oxide, PbO, litharge (red), massicot (yellow) * Lead tetroxide Lead(II,IV) oxide, also called red lead or minium, is the inorganic compound with the formula . A bright red or orange solid, it is used as pigment, in the manufacture of batteries, and rustproof primer paints. It is an example of a mixed va ... or ''red lead'', , minium, which is a lead (II,IV) oxide and may be thought of as lead(II) orthoplumbate(IV) , vivid orange crystals * Lead dioxide (lead(IV) oxide), , dark-brown or black powder Less common lead oxides are: * Lead sesquioxide, , which is a lead (II,IV) oxide as well ( lead(II) metaplumbate(IV) ), reddish yellow * , monoclinic, dark-brown or black crystals * The so-called ''black lead oxide'', which is a mixture of PbO and fine-powdered Pb metal and used in the production of lead–acid batteries. {{Authority contr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Silver
Silver is a chemical element; it has Symbol (chemistry), symbol Ag () and atomic number 47. A soft, whitish-gray, lustrous transition metal, it exhibits the highest electrical conductivity, thermal conductivity, and reflectivity of any metal. Silver is found in the Earth's crust in the pure, free elemental form ("native metal, native silver"), as an alloy with gold and other metals, and in minerals such as argentite and chlorargyrite. Most silver is produced as a byproduct of copper, gold, lead, and zinc Refining (metallurgy), refining. Silver has long been valued as a precious metal. Silver metal is used in many bullion coins, sometimes bimetallism, alongside gold: while it is more abundant than gold, it is much less abundant as a native metal. Its purity is typically measured on a per-mille basis; a 94%-pure alloy is described as "0.940 fine". As one of the seven metals of antiquity, silver has had an enduring role in most human cultures. Other than in currency and as an in ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Oxide Mineral
The oxide mineral class includes those minerals in which the oxide anion (O2−) is bonded to one or more metal alloys. The hydroxide-bearing minerals are typically included in the oxide class. Minerals with complex anion groups such as the silicates, sulfates, carbonates and phosphates are classed separately. Simple oxides *XO form **Periclase group *** Periclase *** Manganosite **Zincite group *** Zincite *** Bromellite *** Tenorite *** Litharge * form ** Cuprite **Ice * form **Hematite group ***Corundum ***Hematite *** Ilmenite * form **Rutile group ***Rutile *** Pyrolusite *** Cassiterite ** Baddeleyite ** Uraninite ** Thorianite * form **Spinel group ***Spinel ***Gahnite ***Magnetite *** Franklinite ***Chromite ** Chrysoberyl ** Columbite *Hydroxide subgroup: **Brucite ** Manganite ** Romanèchite **Goethite group: *** Diaspore ***Goethite Nickel–Strunz class 4: oxides IMA-CNMNC proposes a new hierarchical scheme (Mills et al., 20 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
White Lead
White lead is the basic lead carbonate 2PbCO3·Pb(OH)2. It is a complex Salt (chemistry), salt, containing both carbonate and hydroxide ions. White lead occurs naturally as a mineral, in which context it is known as hydrocerussite, a hydrate of cerussite. It was formerly used as an ingredient for lead paint and a cosmetic called Venetian ceruse, because of its Opacity (optics), opacity and the satiny smooth mixture it made with dryable oils. However, it tended to cause lead poisoning, and its use has been banned in most countries. Basic lead carbonate is produced by treating lead acetate with carbon dioxide and air. In the laboratory procedure treats lead acetate with urea. It occurs naturally as the mineral cerussite. The compound has been characterized by X-ray crystallography, which confirms the formula. The structure is complicated, features two kinds of Pb(II) sites, those bonded to hydroxide and those bonded to carbonate and hydroxide. Related white lead compounds White ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Oxide Minerals
The oxide mineral class includes those minerals in which the oxide anion (O2−) is bonded to one or more metal alloys. The hydroxide-bearing minerals are typically included in the oxide class. Minerals with complex anion groups such as the Silicate mineral, silicates, Sulfate mineral, sulfates, carbonate mineral, carbonates and Phosphate mineral, phosphates are classed separately. Simple oxides *XO form **Periclase group ***Periclase ***Manganosite **Zincite group ***Zincite ***Bromellite ***Tenorite ***Litharge * form **Cuprite **Ice * form **Hematite group ***Corundum ***Hematite ***Ilmenite * form **Rutile group ***Rutile ***Pyrolusite ***Cassiterite **Baddeleyite **Uraninite **Thorianite * form **Spinel group ***Spinel ***Gahnite ***Magnetite ***Franklinite ***Chromite **Chrysoberyl **Columbite *Hydroxide subgroup: **Brucite **Manganite **Romanèchite **Goethite group: ***Diaspore ***Goethite Nickel–Strunz class 4: oxides Internationa ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bullion
Bullion is non-ferrous metal that has been refined to a high standard of elemental purity. The term is ordinarily applied to bulk metal used in the production of coins and especially to precious metals such as gold and silver. It comes from the Anglo-Norman term for a melting-house where metal was refined, and earlier from French , "boiling". Although precious metal bullion is no longer used to make coins for general circulation, it continues to be held as an investment with a reputation for stability in periods of economic uncertainty. To assess the purity of gold bullion, the centuries-old technique of fire assay is still employed, together with modern spectroscopic instrumentation, to accurately determine its quality. As investment The specifications of bullion are often regulated by market bodies or legislation. In the European Union, the minimum purity for gold to be referred to as "bullion", which is treated as investment gold with regard to taxation, is 99.5% for ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Metallurgical Furnace
A metallurgical furnace, often simply referred to as a furnace when the context is known, is an industrial furnace used to heat, melt, or otherwise process metals. Furnaces have been a central piece of equipment throughout the history of metallurgy; processing metals with heat is even its own engineering specialty known as pyrometallurgy. One important furnace application, especially in iron and steel production, is smelting, where metal ores are Redox, reduced under high heat to separate the metal content from mineral gangue. The heat energy to fuel a furnace may be supplied directly by fuel combustion or by electricity. Different processes and the unique properties of specific metals and ores have led to many different furnace types. Air blast furnaces Many furnace designs for smelting combine ore, fuel, and other reagents like flux in a single chamber. Mechanisms, such as bellows or motorized fans, then drive pressurized blasts of air into the chamber. These blasts make the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Clay
Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolinite, ). Most pure clay minerals are white or light-coloured, but natural clays show a variety of colours from impurities, such as a reddish or brownish colour from small amounts of iron oxide. Clays develop plasticity (physics), plasticity when wet but can be hardened through Pottery#Firing, firing. Clay is the longest-known ceramic material. Prehistoric humans discovered the useful properties of clay and used it for making pottery. Some of the earliest pottery shards have been radiocarbon dating, dated to around 14,000 BCE, and Clay tablet, clay tablets were the first known writing medium. Clay is used in many modern industrial processes, such as paper making, cement production, and chemical filtration, filtering. Between one-half and two-thirds of the world's population live or work in buildings made with clay, often baked into brick, as an essenti ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Smelting
Smelting is a process of applying heat and a chemical reducing agent to an ore to extract a desired base metal product. It is a form of extractive metallurgy that is used to obtain many metals such as iron-making, iron, copper extraction, copper, silver mining#Ore processing, silver, tin, lead smelting, lead and zinc smelting, zinc. Smelting uses heat and a chemical reducing agent to decompose the ore, driving off other elements as gases or slag and leaving the metal behind. The reducing agent is commonly a fossil-fuel source of carbon, such as carbon monoxide from incomplete combustion of coke (fuel), coke—or, in earlier times, of charcoal. The oxygen in the ore binds to carbon at high temperatures, as the Chemical energy, chemical potential energy of the bonds in carbon dioxide () is lower than that of the bonds in the ore. Sulfide ores such as those commonly used to obtain copper, zinc or lead, are roasting (metallurgy), roasted before smelting in order to convert the sulfid ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
