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Kipp's Apparatus
Kipp's apparatus, also called a Kipp generator, is an apparatus designed for preparation of small volumes of gases. It was invented around 1844 by the Dutch pharmacist Petrus Jacobus Kipp and widely used in chemical laboratories and for demonstrations in schools into the second half of the 20th century. It later fell out of use, at least in laboratories, because most gases then became available in small gas cylinders. These industrial gases are much purer and drier than those initially obtained from a Kipp apparatus without further processing. Design and operation The apparatus is usually made of glass, or sometimes of polyethylene, and consists of three vertically stacked chambers, roughly resembling a snowman. The upper chamber extends downward as a tube that passes through the middle chamber into the lower chamber. There is no direct path between the middle and upper chambers, but the middle chamber is separated from the lower chamber by a retention plate, such as a conical ...
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Kipp Apparat
The Knowledge is Power Program (KIPP) is a network of tuition-free, open-enrollment Education in the United States#Higher education, college-preparatory public charter schools serving students in historically underserved communities across the United States. Founded in 1994 by Mike Feinberg and Dave Levin, both former Teach For America corps members, KIPP has grown into one of the largest public charter school networks in the country. The organization's instructional model was influenced by educator Harriett Ball. , KIPP was the largest network of public charter schools in North America. The organization operates regional offices in San Francisco, Chicago, New York City, and Washington, D.C. KIPP has been involved in teacher training initiatives and was among the charter school organizations that helped establish the Relay Graduate School of Education. History KIPP was established in 1994 by Dave Levin and Mike Feinberg after completing their two-year commitment with Teach ...
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Iron(II) Sulfide
Iron(II) sulfide or ferrous sulfide (Br.E. sulphide) is one of a family of chemical compounds and minerals with the approximate chemical formula, formula . Iron sulfides are often iron-deficient non-stoichiometric. All are black, water-insoluble solids. Preparation and structure FeS can be obtained by the heating of iron and sulfur: :Fe + S → FeS FeS adopts the nickel arsenide structure, featuring octahedral molecular geometry, octahedral Fe centers and trigonal prismatic sulfide sites. Reactions Iron sulfide reacts with hydrochloric acid, releasing hydrogen sulfide: :FeS + 2 HCl → FeCl2 + H2S :FeS + H2SO4 → FeSO4 + H2S In moist air, iron sulfides oxidize to hydrated ferrous sulfate. Biology and biogeochemistry Iron sulfides occur widely in nature in the form of iron–sulfur proteins. As organic matter decays under low-oxygen (or Hypoxia (environmental), hypoxic) conditions such as in swamps or Dead zone (ecology), dead zones of lakes and oceans, sul ...
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Oxygen
Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), nonmetal, and a potent oxidizing agent that readily forms oxides with most elements as well as with other chemical compound, compounds. Oxygen is abundance of elements in Earth's crust, the most abundant element in Earth's crust, making up almost half of the Earth's crust in the form of various oxides such as water, carbon dioxide, iron oxides and silicates.Atkins, P.; Jones, L.; Laverman, L. (2016).''Chemical Principles'', 7th edition. Freeman. It is abundance of chemical elements, the third-most abundant element in the universe after hydrogen and helium. At standard temperature and pressure, two oxygen atoms will chemical bond, bind covalent bond, covalently to form dioxygen, a colorless and odorless diatomic gas with the chemical formula ...
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Barium Ferrate
Barium ferrate is the chemical compound of formula BaFeO4. This is a rare compound containing iron in the +6 oxidation state. The ferrate(VI) ion has two unpaired electrons, making it paramagnetic. It is isostructural with BaSO4, and contains the tetrahedral FeO4/nowiki>">/nowiki>FeO4/nowiki>2− anion. Structure The ferrate(VI) anion is paramagnetic due to its two unpaired electrons and it has a tetrahedral molecular geometry. X-ray diffraction has been used to determine the orthorhombic unit cell structure (lattice vectors a ≠ b ≠ c, interaxial angles α=β=γ=90°) of nanocrystalline BaFeO4. It crystallized in the Pnma space group (point group: D2h) with lattice parameters ''a'' = 0.8880 nm, ''b'' = 0.5512 nm and ''c'' = 0.7214 nm. The accuracy of the X-Ray diffraction data has been verified by the lattice fringe intervals from High-Resolution Transmission Electron Microscopy (HRTEM) and cell parameters calculated from Selected Area Diffraction (SAED). ...
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Manganese Dioxide
Manganese dioxide is the inorganic compound with the formula . This blackish or brown solid occurs naturally as the mineral pyrolusite, which is the main ore of manganese and a component of manganese nodules. The principal use for is for dry-cell batteries, such as the alkaline battery and the zinc–carbon battery, although it is also used for other battery chemistries such as aqueous zinc-ion batteries.. is also used as a pigment and as a precursor to other manganese compounds, such as . It is used as a reagent in organic synthesis, for example, for the oxidation of allylic alcohols. has an α- polymorph that can incorporate a variety of atoms (as well as water molecules) in the "tunnels" or "channels" between the manganese oxide octahedra. There is considerable interest in as a possible cathode for lithium-ion batteries. Structure Several polymorphs of are claimed, as well as a hydrated form. Like many other dioxides, crystallizes in the rutile crystal structure (t ...
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Calcium Hypochlorite
Calcium hypochlorite is an inorganic compound with chemical formula , also written as . It is a white solid, although commercial samples appear yellow. It strongly smells of chlorine, owing to its slow decomposition in moist air. This compound is relatively stable as a solid and solution and has greater available chlorine than sodium hypochlorite. "Pure" samples have 99.2% active chlorine. Given common industrial purity, an active chlorine content of 65-70% is typical. It is the main active ingredient of commercial products called bleaching powder, used for water treatment and as a bleaching agent. History Charles Tennant and Charles Macintosh developed an industrial process in the late 18th century for the manufacture of chloride of lime, patenting it in 1799. Tennant's process is essentially still used today, and became of military importance during World War I, because calcium hypochlorite was the active ingredient in trench disinfectant. Uses Sanitation Calcium hypochlor ...
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Potassium Permanganate
Potassium permanganate is an inorganic compound with the chemical formula KMnO4. It is a purplish-black crystalline salt, which dissolves in water as K+ and ions to give an intensely pink to purple solution. Potassium permanganate is widely used in the chemical industry and laboratories as a strong oxidizing agent, and also as a medication for dermatitis, for cleaning wounds, and general disinfection. It is commonly used as a biocide for water treatment purposes. It is on the World Health Organization's List of Essential Medicines. In 2000, worldwide production was estimated at 30,000 tons. Properties Potassium permanganate is the potassium salt of the tetrahedral transition metal oxo complex permanganate, in which four ligands are bound to a manganese(VII) center. Structure forms orthorhombic crystals with constants: ''a'' = 910.5  pm, ''b'' = 572.0 pm, ''c'' = 742.5 pm. The overall motif is similar to that for barium sulfate, with which it forms solid so ...
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Chlorine
Chlorine is a chemical element; it has Symbol (chemistry), symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between them. Chlorine is a yellow-green gas at room temperature. It is an extremely reactive element and a strong oxidizing agent, oxidising agent: among the elements, it has the highest electron affinity and the third-highest electronegativity on the revised Electronegativity#Pauling electronegativity, Pauling scale, behind only oxygen and fluorine. Chlorine played an important role in the experiments conducted by medieval Alchemy, alchemists, which commonly involved the heating of chloride Salt (chemistry), salts like ammonium chloride (sal ammoniac) and sodium chloride (common salt), producing various chemical substances containing chlorine such as hydrogen chloride, mercury(II) chloride (corrosive sublimate), and . However, the nature of fre ...
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Heavy Water
Heavy water (deuterium oxide, , ) is a form of water (molecule), water in which hydrogen atoms are all deuterium ( or D, also known as ''heavy hydrogen'') rather than the common hydrogen-1 isotope (, also called ''protium'') that makes up most of the hydrogen in normal water. The presence of the heavier isotope gives the water different nuclear properties, and the increase in mass gives it slightly different physical and chemical properties when compared to normal water. Deuterium is a heavy Isotopes of hydrogen, hydrogen isotope. Heavy water contains deuterium atoms and is used in nuclear reactors. Semiheavy water (HDO) is more common than pure heavy water, while heavy-oxygen water is denser but lacks unique properties. Tritiated water is radioactive due to tritium content. Heavy water has different physical properties from regular water, such as being 10.6% denser and having a higher melting point. Heavy water is less Dissociation (chemistry), dissociated at a given temperatur ...
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Deuterium
Deuterium (hydrogen-2, symbol H or D, also known as heavy hydrogen) is one of two stable isotopes of hydrogen; the other is protium, or hydrogen-1, H. The deuterium nucleus (deuteron) contains one proton and one neutron, whereas the far more common H has no neutrons. The name ''deuterium'' comes from Greek '' deuteros'', meaning "second". American chemist Harold Urey discovered deuterium in 1931. Urey and others produced samples of heavy water in which the H had been highly concentrated. The discovery of deuterium won Urey a Nobel Prize in 1934. Nearly all deuterium found in nature was synthesized in the Big Bang 13.8 billion years ago, forming the primordial ratio of H to H (~26 deuterium nuclei per 10 hydrogen nuclei). Deuterium is subsequently produced by the slow stellar proton–proton chain, but rapidly destroyed by exothermic fusion reactions. The deuterium–deuterium reaction has the second-lowest energy threshold, and is the most astrophysically acce ...
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Aluminium Carbide
Aluminium carbide is a chemical compound with the chemical formula . It is a carbide of aluminium. It has the appearance of pale yellow to brown crystals. It is stable up to 1400 °C. It decomposes in water with the production of methane. Structure Aluminium carbide has an unusual crystal structure that consists of alternating layers of Al2C and Al2C2. Each aluminium atom is coordinated to 4 carbon atoms to give a tetrahedral arrangement. Carbon atoms exist in 2 different binding environments; one is a deformed octahedron of 6 Al atoms at a distance of 217 pm. The other is a distorted trigonal bipyramidal structure of 4 Al atoms at 190–194 pm and a fifth Al atom at 221 pm. Other carbides (IUPAC nomenclature: methides) also exhibit complex structures. Reactions Aluminium carbide hydrolyses with evolution of methane. The reaction proceeds at room temperature but is rapidly accelerated by heating. : Al4C3 + 12 H2O → 4 Al(OH)3 + 3 CH4 Similar reactions occur with other pr ...
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Methane
Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The abundance of methane on Earth makes it an economically attractive fuel, although capturing and storing it is difficult because it is a gas at standard temperature and pressure. In the Earth's atmosphere methane is transparent to visible light but absorbs infrared radiation, acting as a greenhouse gas. Methane is an Organic chemistry, organic Organic compound, compound, and among the simplest of organic compounds. Methane is also a hydrocarbon. Naturally occurring methane is found both below ground and under the seafloor and is formed by both geological and biological processes. The largest reservoir of methane is under the seafloor in the form of methane clathrates. When methane reaches the surface and the Atmosphere of Earth, atmosphere, it is known as atmospheric methane. ...
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