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Iodal
Iodal, or triiodoacetaldehyde, is a halogenated derivative of acetaldehyde with the chemical formula , it is analogous to chloral and bromal. It is described as a pale yellow liquid with a pungent odour by Leopold Gmelin. It is decomposed to iodoform by potash.''Iodal'', Gmelin, L. (1855). Hand-book of Chemistry: Organic chemistry. UK: Cavendish Societypages 186-187/ref> Iodal was discovered and named in 1837. Iodal is synthesised from ethanol and iodine with concentrated nitric acid as the catalyst. Its hydrate was described as water-soluble, white silky crystals.''Iodal'' in ''Chemical Notices from Foreign Sources'', The Chemical News: With which is Incorporated the Chemical Gazette: a Journal of Practical Chemistry in All Its Applications to Pharmacy, Arts, and Manufactures. (1862). UK: C. Mitchell and Company. Like most iodine compounds Iodine compounds are compounds containing the element iodine. Iodine can form compounds using multiple oxidation states. Iodine is qu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chloral
Chloral, also known as trichloroacetaldehyde or trichloroethanal, is the organic compound with the formula Cl3CCHO. This aldehyde is a colourless liquid that is soluble in a wide range of solvents. It reacts with water to form chloral hydrate, a once widely used sedative and hypnotic substance. Production Chloral was first prepared, and named, by the German chemist Justus von Liebig in 1832. Liebig treated anhydrous ethanol with dry chlorine gas. Chloral is produced commercially by the chlorination of acetaldehyde in the presence of hydrochloric acid, producing chloral hydrate. Ethanol can also be used as a feedstock. This reaction is catalyzed by antimony trichloride: :H3CCHO + 3 Cl2 + H2O → Cl3CCH(OH)2 + 3 HCl The chloral hydrate is distilled from the reaction mixture. The distillate is then dehydrated with concentrated sulfuric acid, after which the heavier acid layer (containing the water) is drawn off: :Cl3CCH(OH)2 → Cl3CCHO + H2O The resulting product is p ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bromal
Bromal (tribromoacetaldehyde) is a brominated aldehyde. It reacts with water to form bromal hydrate. See also *Chloral *Chloral hydrate Chloral hydrate is a geminal diol with the formula . It was first used as a sedative and hypnotic in Germany in the 1870s. Over time it was replaced by safer and more effective alternatives but it remained in use in the United States until at ... References Aldehydes Tribromomethyl compounds {{Organohalide-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Acetaldehyde
Acetaldehyde (IUPAC systematic name ethanal) is an organic compound, organic chemical compound with the chemical formula, formula , sometimes abbreviated as . It is a colorless liquid or gas, boiling near room temperature. It is one of the most important aldehydes, occurring widely in nature and being produced on a large scale in industry. Acetaldehyde occurs naturally in coffee, bread, and ripe fruit, and is produced by plants. It is also produced by the partial oxidation of ethanol by the liver enzyme alcohol dehydrogenase and is a contributing cause of hangover after alcohol (drug), alcohol consumption. Pathways of exposure include air, water, land, or groundwater, as well as drink and smoke. Consumption of disulfiram inhibits acetaldehyde dehydrogenase, the enzyme responsible for the metabolism of acetaldehyde, thereby causing it to build up in the body. International Agency for Research on Cancer, The International Agency for Research on Cancer (IARC) has listed acetaldehyde ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Formula
A chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, such as parentheses, dashes, brackets, commas and ''plus'' (+) and ''minus'' (−) signs. These are limited to a single typographic line of symbols, which may include subscripts and superscripts. A chemical formula is not a chemical name since it does not contain any words. Although a chemical formula may imply certain simple chemical structures, it is not the same as a full chemical structural formula. Chemical formulae can fully specify the structure of only the simplest of molecules and chemical substances, and are generally more limited in power than chemical names and structural formulae. The simplest types of chemical formulae are called '' empirical formulae'', which use letters and numbers indicating the numerical ''proportions'' of atoms ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Leopold Gmelin
Leopold Gmelin (2 August 1788 – 13 April 1853) was a German chemist. Gmelin was a professor at the University of Heidelberg. He worked on the Potassium ferricyanide, red prussiate and created Gmelin's test, and wrote his ''Handbook of Chemistry'', which over successive editions became a standard reference work still in use. Life Gmelin was a son of the physician, botanist and chemist Johann Friedrich Gmelin and his wife Rosine Schott. Due to his family he early came in contact with medicine and the natural sciences, in 1804 he attended the chemical lectures of his father. In the same year Gmelin moved to Tübingen to work in the family pharmacy, he also studied at the University of Tübingen among other relatives including Ferdinand Gottlieb Gmelin (a cousin) and Carl Friedrich Kielmeyer (husband of a cousin). Supported by Kielmeyer, Gmelin moved to the University of Göttingen in 1805 and later he worked as assistant in the laboratory of Friedrich Stromeyer, by whom he suc ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Iodoform
Iodoform (also known as triiodomethane) is the organoiodine compound with the chemical formula . It is a pale yellow, crystalline, volatile substance, with a penetrating and distinctive odor (in older chemistry texts, the smell is sometimes referred to as that of hospitals, where the compound is still commonly used) and, analogous to chloroform, sweetish taste. It is occasionally used as a disinfectant. Naming The name iodoform originates with the "formyle radical," an archaic term for the HC moiety, and is retained for historical consistency. A full, modern name is triiodomethane. Another possible name is "carbon hydride triiodide". The "hydride" in the latter is sometimes omitted, though the IUPAC recommends against doing so, as "carbon triiodide" could also mean (hexaiodoethane, a highly unstable compound). Structure The molecule adopts a tetrahedral molecular geometry, tetrahedral geometry with C3v symmetry group, symmetry. Synthesis and reactions The synthesis of iodofo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Potash
Potash ( ) includes various mined and manufactured salts that contain potassium in water- soluble form.Potash , USGS 2008 Minerals Yearbook The name derives from ''pot ash'', plant ashes or soaked in water in a pot, the primary means of manufacturing potash before the Industrial Era. The word '''' is derived from ''potash''. Potash is produced worldwide in amounts exceeding 71.9 million |
Ethanol
Ethanol (also called ethyl alcohol, grain alcohol, drinking alcohol, or simply alcohol) is an organic compound with the chemical formula . It is an Alcohol (chemistry), alcohol, with its formula also written as , or EtOH, where Et is the pseudoelement symbol for ethyl group, ethyl. Ethanol is a Volatility (chemistry), volatile, flammable, colorless liquid with a characteristic wine-like odor and pungent taste. As a psychoactive depressant, it is the active ingredient in alcoholic beverages, and the second most consumed drug globally behind caffeine. Ethanol is naturally produced by the fermentation process of sugars by yeasts or via petrochemical processes such as ethylene hydration. Historically it was used as a general anesthetic, and has modern medical applications as an antiseptic, disinfectant, solvent for some medications, and antidote for methanol poisoning and ethylene glycol poisoning. It is used as a chemical solvent and in the Chemical synthesis, synthesis of orga ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Iodine
Iodine is a chemical element; it has symbol I and atomic number 53. The heaviest of the stable halogens, it exists at standard conditions as a semi-lustrous, non-metallic solid that melts to form a deep violet liquid at , and boils to a violet gas at . The element was discovered by the French chemist Bernard Courtois in 1811 and was named two years later by Joseph Louis Gay-Lussac, after the Ancient Greek , meaning 'violet'. Iodine occurs in many oxidation states, including iodide (I−), iodate (), and the various periodate anions. As the heaviest essential mineral nutrient, iodine is required for the synthesis of thyroid hormones. Iodine deficiency affects about two billion people and is the leading preventable cause of intellectual disabilities. The dominant producers of iodine today are Chile and Japan. Due to its high atomic number and ease of attachment to organic compounds, it has also found favour as a non-toxic radiocontrast material. Because of the spec ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nitric Acid
Nitric acid is an inorganic compound with the formula . It is a highly corrosive mineral acid. The compound is colorless, but samples tend to acquire a yellow cast over time due to decomposition into nitrogen oxide, oxides of nitrogen. Most commercially available nitric acid has a concentration of 68% in water. When the solution contains more than 86% , it is referred to as ''fuming nitric acid''. Depending on the amount of nitrogen dioxide present, fuming nitric acid is further characterized as red fuming nitric acid at concentrations above 86%, or white fuming nitric acid at concentrations above 95%. Nitric acid is the primary reagent used for nitration – the addition of a nitro group, typically to an organic molecule. While some resulting nitro compounds are shock- and thermally-sensitive explosives, a few are stable enough to be used in munitions and demolition, while others are still more stable and used as synthetic dyes and medicines (e.g. metronidazole). Nitric acid is ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Iodine Compounds
Iodine compounds are compounds containing the element iodine. Iodine can form compounds using multiple oxidation states. Iodine is quite reactive, but it is much less reactive than the other halogens. For example, while chlorine gas will halogenate carbon monoxide, nitric oxide, and sulfur dioxide (to phosgene, nitrosyl chloride, and sulfuryl chloride respectively), iodine will not do so. Furthermore, iodination of metals tends to result in lower oxidation states than chlorination or bromination; for example, rhenium metal reacts with chlorine to form rhenium hexachloride, but with bromine it forms only rhenium pentabromide and iodine can achieve only rhenium tetraiodide.Greenwood and Earnshaw, pp. 800–4 By the same token, however, since iodine has the lowest ionisation energy among the halogens and is the most easily oxidised of them, it has a more significant cationic chemistry and its higher oxidation states are rather more stable than those of bromine and chlorine, for exampl ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
