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Imidogen
Imidogen is an inorganic compound with the chemical formula NH. Like other simple radicals, it is highly reactive and consequently short-lived except as a dilute gas. Its behavior depends on its spin multiplicity. Production and properties Imidogen can be generated by electrical discharge in an atmosphere of ammonia. Imidogen has a large rotational splitting and a weak spin–spin interaction, therefore it will be less likely to undergo collision-induced Zeeman transitions. Ground-state imidogen can be magnetically trapped using buffer-gas loading from a molecular beam. The ground state of imidogen is a triplet, with a singlet excited state only slightly higher in energy. The first excited state (a1Δ) has a long lifetime as its relaxation to ground state (X3Σ−) is spin-forbidden. Imidogen undergoes collision-induced intersystem crossing. Reactivity Ignoring hydrogen atoms, imidogen is isoelectronic with carbene (CH2) and oxygen (O) atoms, and it exhibits comparable ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
IUPAC Red Book
Nomenclature of Inorganic Chemistry, IUPAC Recommendations 2005 is the 2005 version of ''Nomenclature of Inorganic Chemistry'' (which is informally called the Red Book). It is a collection of rules for naming inorganic compounds, as recommended by the International Union of Pure and Applied Chemistry (IUPAC). Summary The 2005 edition replaces their previous recommendations ''Nomenclature The Red Book of Inorganic Chemistry, IUPAC Recommendations 1990 (Red Book I)'', and "where appropriate" (sic) ''Nomenclature of Inorganic Chemistry II, IUPAC Recommendations 2000 (Red Book II)''. The recommendations take up over 300 pages''Nomenclature of Inorganic Chemistry IUPAC Recommendations'' 2005 ed. N. G. Connelly et al. RSC Publishing https://iupac.org/what-we-do/books/redbook/ and the full text can be downloaded from IUPAC. Corrections have been issued. Apart from a reorganisation of the content, there is a new section on organometallics and a formal element list to be used in place o ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Laser-induced Fluorescence
Laser-induced fluorescence (LIF) or laser-stimulated fluorescence (LSF) is a spectroscopic method in which an atom or molecule is excited to a higher energy level by the absorption of laser light followed by spontaneous emission of light. It was first reported by Zare and coworkers in 1968. LIF is used for studying structure of molecules, detection of selective species and flow visualization and measurements. The wavelength is often selected to be the one at which the species has its largest cross section. The excited species will after some time, usually in the order of few nanoseconds to microseconds, spontaneously decay and emit a photon at a wavelength longer than the excitation wavelength. This fluorescent light is typically recorded with a photomultiplier tube (PMT), charged-coupled device (CCD), or filtered photodiodes. Types Two different kinds of spectra exist, disperse spectra and excitation spectra. The disperse spectra are performed with a fixed lasing wavelength, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Molecular Cloud
A molecular cloud—sometimes called a stellar nursery if star formation is occurring within—is a type of interstellar cloud of which the density and size permit absorption nebulae, the formation of molecules (most commonly molecular hydrogen, H2), and the formation of H II regions. This is in contrast to other areas of the interstellar medium that contain predominantly ionized gas. Molecular hydrogen is difficult to detect by infrared and radio observations, so the molecule most often used to determine the presence of H2 is carbon monoxide (CO). The ratio between CO luminosity and H2 mass is thought to be constant, although there are reasons to doubt this assumption in observations of some other galaxies. Within molecular clouds are regions with higher density, where much dust and many gas cores reside, called clumps. These clumps are the beginning of star formation if gravitational forces are sufficient to cause the dust and gas to collapse. Research and discovery The histo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Interstellar Medium
The interstellar medium (ISM) is the matter and radiation that exists in the outer space, space between the star systems in a galaxy. This matter includes gas in ionic, atomic, and molecular form, as well as cosmic dust, dust and cosmic rays. It fills interstellar space and blends smoothly into the surrounding intergalactic medium. The energy that occupies the same volume, in the form of electromagnetic radiation, is the interstellar radiation field. Although the density of atoms in the ISM is usually far below that in the best laboratory vacuums, the mean free path between collisions is short compared to typical interstellar lengths, so on these scales the ISM behaves as a gas (more precisely, as a Plasma (physics), plasma: it is everywhere at least slightly ionized), responding to pressure forces, and not as a collection of non-interacting particles. The interstellar medium is composed of multiple phases distinguished by whether matter is ionic, atomic, or molecular, and the temp ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Photoionization
Photoionization is the physical process in which an ion is formed from the interaction of a photon with an atom or molecule. Cross section Not every interaction between a photon and an atom, or molecule, will result in photoionization. The probability of photoionization is related to the photoionization cross section of the species – the probability of an ionization event conceptualized as a hypothetical cross-sectional area. This cross section depends on the energy of the photon (proportional to its wavenumber) and the species being considered i.e. it depends on the structure of the molecular species. In the case of molecules, the photoionization cross-section can be estimated by examination of Franck-Condon factors between a ground-state molecule and the target ion. This can be initialized by computing the vibrations of a molecule and associated cation (post ionization) using quantum chemical software e.g. QChem. For photon energies below the ionization threshold, the photoi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Photodissociation
Photodissociation, photolysis, photodecomposition, or photofragmentation is a chemical reaction in which molecules of a chemical compound are broken down by absorption of light or photons. It is defined as the interaction of one or more photons with one target molecule that dissociates into two fragments. Here, “light” is broadly defined as radiation spanning the vacuum ultraviolet (VUV), ultraviolet (UV), visible, and infrared (IR) regions of the electromagnetic spectrum. To break covalent bonds, photon energies corresponding to visible, UV, or VUV light are typically required, whereas IR photons may be sufficiently energetic to detach ligands from coordination complexes or to fragment supramolecular complexes. Photolysis in photosynthesis Photolysis is part of the light-dependent reaction, light phase, photochemical phase, or Hill reaction of photosynthesis. The general reaction of photosynthetic photolysis can be given in terms of photons as: :\ce + 2 \text \longrigh ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Monthly Notices Of The Royal Astronomical Society
''Monthly Notices of the Royal Astronomical Society'' (MNRAS) is a peer-reviewed scientific journal in astronomy, astrophysics and related fields. It publishes original research in two formats: papers (of any length) and letters (limited to five pages). MNRAS publishes more articles per year than any other astronomy journal. The learned society journal has been in continuous existence since 1827 and became online only in 2020. It operates as a partnership between the Royal Astronomical Society (RAS), who select and peer-review the contents, and Oxford University Press (OUP), who publish and market the journal. Despite its name, MNRAS is no longer monthly, nor does it carry the notices of the RAS. In 2024 MNRAS became a purely gold open access journal. History The first issue of MNRAS was published on 9 February 1827 as ''Monthly Notices of the Astronomical Society of London'' and it has been in continuous publication ever since. It took its current name from the second vo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Signal-to-noise
Signal-to-noise ratio (SNR or S/N) is a measure used in science and engineering that compares the level of a desired signal to the level of background noise. SNR is defined as the ratio of signal power to noise power, often expressed in decibels. A ratio higher than 1:1 (greater than 0 dB) indicates more signal than noise. SNR is an important parameter that affects the performance and quality of systems that process or transmit signals, such as communication systems, audio systems, radar systems, imaging systems, and data acquisition systems. A high SNR means that the signal is clear and easy to detect or interpret, while a low SNR means that the signal is corrupted or obscured by noise and may be difficult to distinguish or recover. SNR can be improved by various methods, such as increasing the signal strength, reducing the noise level, filtering out unwanted noise, or using error correction techniques. SNR also determines the maximum possible amount of data that can ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
ζ Persei
Zeta Persei (ζ Per, ζ Persei) is a star in the northern constellation of Perseus. With an apparent visual magnitude of 2.9, it can be readily seen with the naked eye. Parallax measurements place it at a distance of about from Earth, though measurements of its Ca II lines place it at . Description This is a lower luminosity supergiant star with a stellar classification of B1 Ib. This is an enormous star, with an estimated 26–27 times the Sun's radius and 13–16 times the Sun's mass. It has about 47,000 times the luminosity of the Sun and it is radiating this energy at an effective temperature of 20,800 K, giving it the blue-white hue of a B-type star. The spectrum displays anomalously high levels of carbon. Zeta Persei has a strong stellar wind that is expelling times the mass of the Sun per year, or the equivalent of the Sun's mass every 4.3 million years. Zeta Persei has a 9th magnitude companion at an angular separation of 12.9 arcseconds. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
IUPAC
The International Union of Pure and Applied Chemistry (IUPAC ) is an international federation of National Adhering Organizations working for the advancement of the chemical sciences, especially by developing nomenclature and terminology. It is a member of the International Science Council (ISC). IUPAC is registered in Zürich, Switzerland, and the administrative office, known as the "IUPAC Secretariat", is in Research Triangle Park, North Carolina, United States. IUPAC's executive director heads this administrative office, currently Greta Heydenrych. IUPAC was established in 1919 as the successor of the International Congress of Applied Chemistry for the advancement of chemistry. Its members, the National Adhering Organizations, can be national List of chemistry societies, chemistry societies, national Academy of Sciences, academies of sciences, or other bodies representing chemists. There are fifty-four National Adhering Organizations and three Associate National Adhering Organ ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Preferred IUPAC Name
In chemical nomenclature, a preferred IUPAC name (PIN) is a unique name, assigned to a chemical substance and preferred among all possible names generated by IUPAC nomenclature. The "preferred IUPAC nomenclature" provides a set of rules for choosing between multiple possibilities in situations where it is important to decide on a unique name. It is intended for use in legal and regulatory situations. Preferred IUPAC names are applicable only for organic compounds, to which the IUPAC (International Union of Pure and Applied Chemistry) has the definition as compounds which contain at least a single carbon atom but no alkali, alkaline earth or transition metals and can be named by the nomenclature of organic compounds (see below). Rules for the remaining organic and inorganic compounds are still under development. The concept of PINs is defined in the introductory chapter and chapter 5 of the ''"Nomenclature of Organic Chemistry: IUPAC Recommendations and Preferred Names 2013"'' ( ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
