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Gran Plot
A Gran plot (also known as Gran titration or the Gran method) is a common means of standardizing a titrate or titrant by estimating the ''equivalence volume'' or '' end point'' in a strong acid-strong base titration or in a potentiometric titration. Such plots have been also used to calibrate glass electrodes, to estimate the carbonate content of aqueous solutions, and to estimate the ''K''a values (acid dissociation constants) of weak acids and bases from titration data. Gran plots use linear approximations of the ''a priori'' non-linear relationships between the measured quantity, pH or electromotive potential (emf), and the titrant volume. Other types of concentration measures, such as spectrophotometric absorbances or NMR chemical shifts, can in principle be similarly treated. These approximations are only valid near, but not at, the end point, and so the method differs from end point estimations by way of first- and second-derivative plots, which require data at the end p ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Titrate
Titration (also known as titrimetry and volumetric analysis) is a common laboratory method of quantitative chemical analysis to determine the concentration of an identified analyte (a substance to be analyzed). A reagent, termed the ''titrant'' or ''titrator'', is prepared as a standard solution of known concentration and volume. The titrant reacts with a solution of ''analyte'' (which may also be termed the ''titrand'') to determine the analyte's concentration. The volume of titrant that reacted with the analyte is termed the ''titration volume''. History and etymology The word "titration" descends from the French word ''titrer'' (1543), meaning the proportion of gold or silver in coins or in works of gold or silver; i.e., a measure of fineness or purity. ''Tiltre'' became ''titre'', which thus came to mean the "fineness of alloyed gold", and then the "concentration of a substance in a given sample". In 1828, the French chemist Joseph Louis Gay-Lussac first used ''titre'' as ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Equivalence Point
The equivalence point, or stoichiometric point, of a chemical reaction is the point at which chemically equivalent quantities of reactants have been mixed. For an acid-base reaction the equivalence point is where the moles of acid and the moles of base would neutralize each other according to the chemical reaction. This does not necessarily imply a 1:1 molar ratio of acid:base, merely that the ratio is the same as in the chemical reaction. It can be found by means of an indicator, for example phenolphthalein or methyl orange. The endpoint (related to, but not the same as the equivalence point) refers to the point at which the indicator changes color in a colorimetric titration. Methods to determine the equivalence point Different methods to determine the equivalence point include: ;pH indicator: A pH indicator is a substance that changes color in response to a chemical change. An acid-base indicator (e.g., phenolphthalein) changes color depending on the pH. Redox indicators ar ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Plots (graphics)
Plot or Plotting may refer to: Art, media and entertainment * Plot (narrative), the story of a piece of fiction Music * ''The Plot'' (album), a 1976 album by jazz trumpeter Enrico Rava * The Plot (band), a band formed in 2003 Other * ''Plot'' (film), a 1973 French-Italian film * ''Plotting'' (video game), a 1989 Taito puzzle video game, also called Flipull * ''The Plot'' (video game), a platform game released in 1988 for the Amstrad CPC and Sinclair Spectrum * ''Plotting'' (non-fiction), a 1939 book on writing by Jack Woodford * ''The Plot'' (novel), a 2021 mystery by Jean Hanff Korelitz Graphics * Plot (graphics), a graphical technique for representing a data set * Plot (radar), a graphic display that shows all collated data from a ship's on-board sensors * Plot plan, a type of drawing which shows existing and proposed conditions for a given area Land * Plot (land), a piece of land used for building on ** Burial plot, a piece of land a person is buried in * Quadrat, a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Solubility Product
Solubility equilibrium is a type of dynamic equilibrium that exists when a chemical compound in the solid state is in chemical equilibrium with a solution of that compound. The solid may dissolve unchanged, with dissociation, or with chemical reaction with another constituent of the solution, such as acid or alkali. Each solubility equilibrium is characterized by a temperature-dependent ''solubility product'' which functions like an equilibrium constant. Solubility equilibria are important in pharmaceutical, environmental and many other scenarios. Definitions A solubility equilibrium exists when a chemical compound in the solid state is in chemical equilibrium with a solution containing the compound. This type of equilibrium is an example of dynamic equilibrium in that some individual molecules migrate between the solid and solution phases such that the rates of dissolution and precipitation are equal to one another. When equilibrium is established and the solid has not all dissolv ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sample Gran Plot 3
Sample or samples may refer to: Base meaning * Sample (statistics), a subset of a population – complete data set * Sample (signal), a digital discrete sample of a continuous analog signal * Sample (material), a specimen or small quantity of something * Sample (graphics), an intersection of a color channel and a pixel * SAMPLE history, a mnemonic acronym for questions medical first responders should ask * Product sample, a sample of a consumer product that is given to the consumer so that he or she may try a product before committing to a purchase * Standard cross-cultural sample, a sample of 186 cultures, used by scholars engaged in cross-cultural studies People *Sample (surname) * Samples (surname) * Junior Samples (1926–1983), American comedian Places * Sample, Kentucky, unincorporated community, United States * Sampleville, Ohio, unincorporated community, United States * Hugh W. and Sarah Sample House, listed on the National Register of Historic Places in Iowa, United ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Determination Of Equilibrium Constants
Equilibrium constants are determined in order to quantify chemical equilibria. When an equilibrium constant is expressed as a concentration quotient, :K=\frac it is implied that the activity quotient is constant. For this assumption to be valid, equilibrium constants must be determined in a medium of relatively high ionic strength. Where this is not possible, consideration should be given to possible activity variation. The equilibrium expression above is a function of the concentrations etc. of the chemical species in equilibrium. The equilibrium constant value can be determined if any one of these concentrations can be measured. The general procedure is that the concentration in question is measured for a series of solutions with known analytical concentrations of the reactants. Typically, a titration is performed with one or more reactants in the titration vessel and one or more reactants in the burette. Knowing the analytical concentrations of reactants initially in ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Primary Standard
A primary standard in metrology is a standard that is sufficiently accurate such that it is not calibrated by or subordinate to other standards. Primary standards are defined via other quantities like length, mass and time. Primary standards are used to calibrate other standards referred to as working standards.Skoog, Douglas A., Donald M. West and F. James Holler. "Fundamentals of Analytical Chemistry 8th ed." Harcourt Brace College Publishers. 1995 ''Holt Science and Technology: Physical Science''. Ed. Rinehart and Winston, Inc. Holt. Holt McDougal (July 2000). . See Hierarchy of Standards. In chemistry Standards are used in analytical chemistry. Here, a primary standard is typically a reagent which can be weighed easily, and which is so pure that its weight is truly representative of the number of moles of substance contained. Features of a primary standard include: # High purity # Stability (low reactivity) # Low hygroscopicity (to minimize weight changes due to humidity) ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Carbonate Content
A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word ''carbonate'' may also refer to a carbonate ester, an organic compound containing the carbonate group C(=O)(O–)2. The term is also used as a verb, to describe carbonation: the process of raising the concentrations of carbonate and bicarbonate ions in water to produce carbonated water and other carbonated beverageseither by the addition of carbon dioxide gas under pressure or by dissolving carbonate or bicarbonate salts into the water. In geology and mineralogy, the term "carbonate" can refer both to carbonate minerals and carbonate rock (which is made of chiefly carbonate minerals), and both are dominated by the carbonate ion, . Carbonate minerals are extremely varied and ubiquitous in chemically precipitated sedimentary rock. The most common are calcite or calcium carbonate, CaCO3, the chief constituent of limestone (as well a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Titrating Strong Acid With Strong Base
Titration (also known as titrimetry and volumetric analysis) is a common laboratory method of quantitative chemical analysis to determine the concentration of an identified analyte (a substance to be analyzed). A reagent, termed the ''titrant'' or ''titrator'', is prepared as a standard solution of known concentration and volume. The titrant reacts with a solution of ''analyte'' (which may also be termed the ''titrand'') to determine the analyte's concentration. The volume of titrant that reacted with the analyte is termed the ''titration volume''. History and etymology The word "titration" descends from the French word ''titrer'' (1543), meaning the proportion of gold or silver in coins or in works of gold or silver; i.e., a measure of fineness or purity. ''Tiltre'' became ''titre'', which thus came to mean the "fineness of alloyed gold", and then the "concentration of a substance in a given sample". In 1828, the French chemist Joseph Louis Gay-Lussac first used ''titre'' as ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sample Gran Plot 2
Sample or samples may refer to: Base meaning * Sample (statistics), a subset of a population – complete data set * Sample (signal), a digital discrete sample of a continuous analog signal * Sample (material), a specimen or small quantity of something * Sample (graphics), an intersection of a color channel and a pixel * SAMPLE history, a mnemonic acronym for questions medical first responders should ask * Product sample, a sample of a consumer product that is given to the consumer so that he or she may try a product before committing to a purchase * Standard cross-cultural sample, a sample of 186 cultures, used by scholars engaged in cross-cultural studies People *Sample (surname) * Samples (surname) * Junior Samples (1926–1983), American comedian Places * Sample, Kentucky, unincorporated community, United States * Sampleville, Ohio, unincorporated community, United States * Hugh W. and Sarah Sample House, listed on the National Register of Historic Places in Iowa, United ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sample Gran Plot
Sample or samples may refer to: Base meaning * Sample (statistics), a subset of a population – complete data set * Sample (signal), a digital discrete sample of a continuous analog signal * Sample (material), a specimen or small quantity of something * Sample (graphics), an intersection of a color channel and a pixel * SAMPLE history, a mnemonic acronym for questions medical first responders should ask * Product sample, a sample of a consumer product that is given to the consumer so that he or she may try a product before committing to a purchase * Standard cross-cultural sample, a sample of 186 cultures, used by scholars engaged in cross-cultural studies People *Sample (surname) * Samples (surname) * Junior Samples (1926–1983), American comedian Places * Sample, Kentucky, unincorporated community, United States * Sampleville, Ohio, unincorporated community, United States * Hugh W. and Sarah Sample House, listed on the National Register of Historic Places in Iowa, United ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Activity Coefficient
In thermodynamics, an activity coefficient is a factor used to account for deviation of a mixture of chemical substances from ideal behaviour. In an ideal mixture, the microscopic interactions between each pair of chemical species are the same (or macroscopically equivalent, the enthalpy change of solution and volume variation in mixing is zero) and, as a result, properties of the mixtures can be expressed directly in terms of simple concentrations or partial pressures of the substances present e.g. Raoult's law. Deviations from ideality are accommodated by modifying the concentration by an ''activity coefficient''. Analogously, expressions involving gases can be adjusted for non-ideality by scaling partial pressures by a fugacity coefficient. The concept of activity coefficient is closely linked to that of activity in chemistry. Thermodynamic definition The chemical potential, \mu_\mathrm, of a substance B in an ideal mixture of liquids or an ideal solution is given by ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
