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Germanite
Germanite is a rare copper iron germanium sulfide mineral, Cu26Fe4Ge4S32. It was first discovered in 1922, and named for its germanium content. It is only a minor source of this important semiconductor element, which is mainly derived from the processing of the zinc sulfide mineral sphalerite.U.S. Geological Survey (2008), "Germanium—Statistics and Information", U.S. Geological Survey, Mineral Commodity Summaries http://minerals.usgs.gov/minerals/pubs/commodity/germanium/ Germanite contains gallium, zinc, molybdenum, arsenic, and vanadium as impurities. Its type locality is the Tsumeb Mine in Namibia where it occurs in a hydrothermal polymetallic ore deposit in dolomite in association with renierite, pyrite, tennantite, enargite, galena, sphalerite, digenite, bornite and chalcopyrite. It has also been reported from Argentina, Armenia, Bulgaria, Cuba, Democratic Republic of Congo (Zaire), Finland, France, Greece, Japan, Republic of Congo (Brazzaville), Russia and the United ...
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Sulfide Mineral
The sulfide minerals are a class of minerals containing sulfide (S2−) or disulfide () as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenide mineral, selenides, the telluride mineral, tellurides, the arsenide mineral, arsenides, the antimonide mineral, antimonides, the bismuthinides, the sulfarsenides and the sulfosalts.http://www.minerals.net/mineral/sort-met.hod/group/sulfgrp.htm Minerals.net Dana Classification, SulfidesKlein, Cornelis and Cornelius S. Hurlbut, Jr., 1986, ''Manual of Mineralogy'', Wiley, 20th ed., pp 269-293 Sulfide minerals are inorganic compounds. Minerals Common or important examples include: * Acanthite *Chalcocite *Bornite *Galena *Sphalerite *Chalcopyrite *Pyrrhotite *Millerite *Pentlandite *Covellite *Cinnabar *Realgar *Orpiment *Stibnite *Pyrite *Marcasite *Molybdenite Sulfarsenides: *Cobaltite *Arsenopyrite *Gersdorffite Sulfosalts: *Pyrargyrite *Pro ...
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Hydrothermal
Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with the assistance of. Roderick McKenzie.'' Oxford: Clarendon Press. and θέρμη, ''heat'' ). Hydrothermal circulation occurs most often in the vicinity of sources of heat within the Earth's crust. In general, this occurs near volcanic activity, but can occur in the shallow to mid crust along deeply penetrating fault irregularities or in the deep crust related to the intrusion of granite, or as the result of orogeny or metamorphism. Hydrothermal circulation often results in hydrothermal mineral deposits. Seafloor hydrothermal circulation Hydrothermal circulation in the oceans is the passage of the water through mid-oceanic ridge systems. The term includes both the circulation of the well-known, high-temperature vent waters near the ridge c ...
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Armenia
Armenia, officially the Republic of Armenia, is a landlocked country in the Armenian Highlands of West Asia. It is a part of the Caucasus region and is bordered by Turkey to the west, Georgia (country), Georgia to the north and Azerbaijan to the east, and Iran and the Azerbaijani exclave of Nakhchivan Autonomous Republic, Nakhchivan to the south. Yerevan is the Capital city, capital, largest city and Economy of Armenia, financial center. The Armenian Highlands has been home to the Hayasa-Azzi, Shupria and Nairi. By at least 600 BC, an archaic form of Proto-Armenian language, Proto-Armenian, an Indo-European languages, Indo-European language, had diffused into the Armenian Highlands.Robert Drews (2017). ''Militarism and the Indo-Europeanizing of Europe''. Routledge. . p. 228: "The vernacular of the Great Kingdom of Biainili was quite certainly Armenian. The Armenian language was obviously the region's vernacular in the fifth century BC, when Persian commanders and Greek writers ...
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Argentina
Argentina, officially the Argentine Republic, is a country in the southern half of South America. It covers an area of , making it the List of South American countries by area, second-largest country in South America after Brazil, the fourth-largest country in the Americas, and the List of countries and dependencies by area, eighth-largest country in the world. Argentina shares the bulk of the Southern Cone with Chile to the west, and is also bordered by Bolivia and Paraguay to the north, Brazil to the northeast, Uruguay and the South Atlantic Ocean to the east, and the Drake Passage to the south. Argentina is a Federation, federal state subdivided into twenty-three Provinces of Argentina, provinces, and one autonomous city, which is the federal capital and List of cities in Argentina by population, largest city of the nation, Buenos Aires. The provinces and the capital have their own constitutions, but exist under a Federalism, federal system. Argentina claims sovereignty ov ...
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Chalcopyrite
Chalcopyrite ( ) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a Mohs scale, hardness of 3.5 to 4 on the Mohs scale. Its Streak (mineralogy), streak is diagnostic as green-tinged black. On exposure to air, chalcopyrite tarnishes to a variety of oxides, hydroxides, and sulfates. Associated copper minerals include the sulfides bornite (Cu5FeS4), chalcocite (Cu2S), covellite (CuS), digenite (Cu9S5); carbonates such as malachite and azurite, and rarely oxides such as cuprite (Cu2O). It is rarely found in association with native copper. Chalcopyrite is a conductor of electricity. Copper can be extracted from chalcopyrite ore using various methods. The two predominant methods are pyrometallurgy and hydrometallurgy, the former being the most commercially viable. Etymology The name chalcopyrite comes from the Greek words , which means cop ...
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Bornite
Bornite, also known as peacock ore, is a sulfide mineral with chemical composition that crystallizes in the orthorhombic system (pseudo-cubic). It is an important copper ore. Appearance Bornite has a brown to copper-red color on fresh surfaces that tarnishes to various iridescent shades of blue to purple in places. Its striking iridescence gives it the nickname ''peacock copper'' or ''peacock ore''. Mineralogy Bornite is an important copper ore mineral and occurs widely in porphyry copper deposits along with the more common chalcopyrite. Chalcopyrite and bornite are both typically replaced by chalcocite and covellite in the supergene enrichment zone of copper deposits. Bornite is also found as disseminations in mafic igneous rocks, in contact metamorphic skarn deposits, in pegmatites and in sedimentary cupriferous shales. It is important as an ore for its copper content of about 63 percent by mass. Structure At temperatures above , the structure is isometric with a un ...
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Digenite
Digenite is a copper sulfide mineral with formula: Cu9S5. Digenite is a black to dark blue opaque mineral that crystallizes with a trigonal–hexagonal scalenohedral structure. In habit it is usually massive, but does often show pseudo-cubic forms. It has poor to indistinct cleavage and a brittle fracture. It has a Mohs hardness of 2.5 to 3 and a specific gravity of 5.6. It is found in copper sulfide deposits of both primary and supergene occurrences. It is typically associated with and often intergrown with chalcocite, covellite, djurleite, bornite, chalcopyrite and pyrite. The type locality is Sangerhausen, Thuringia, Germany, in copper slate deposits. Occurrence Digenite occurs in the transitional zone of supergene oxidation of primary sulfide ore deposits, at the interface between the upper and lower saprolite ore zones. It is rarely an important mineral for copper ores, as it is more usually replaced by chalcocite further up in the weathering profile, and is a ...
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Galena
Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver. Galena is one of the most abundant and widely distributed sulfide minerals. It crystallizes in the Cubic (crystal system), cubic crystal system often showing octahedral forms. It is often associated with the minerals sphalerite, calcite and fluorite. As a pure specimen held in the hand, under standard temperature and pressure, galena is insoluble in water and so is almost non-toxic. Handling galena under these specific conditions (such as in a museum or as part of geology instruction) poses practically no risk; however, as lead(II) sulfide is reasonably reactive in a variety of environments, it can be highly toxic if swallowed or inhaled, particularly under prolonged or repeated exposure. Occurrence Galena is the main ore of lead, used since ancient times, since lead can be smelted from galena in an ordinary wood fire. G ...
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Enargite
Enargite is a copper arsenic sulfosalt mineral with formula Cu3AsS4. It takes its name from the Greek word , "distinct". Enargite is a steel gray, blackish gray, to violet black mineral with metallic luster. It forms slender orthorhombic prisms as well as massive aggregates. It has a hardness of 3 and a specific gravity of 4.45. Enargite is dimorph of the tetragonal luzonite. Occurrence It is a medium to low temperature hydrothermal mineral occurring with quartz, pyrite, sphalerite, galena, bornite, tetrahedrite–tennantite, chalcocite, covellite and baryte. It occurs in the mineral deposits at Butte, Montana, San Juan Mountains, Colorado and at both Bingham Canyon and Tintic, Utah. It is also found in the copper mines of Canada, Mexico, Argentina, Chile, Peru, and the Philippines. Enargite was originally described as a new species from the copper mines of the San Francisco vein, Junin Department, Peru Peru, officially the Republic of Peru, is a country in west ...
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Tennantite
Tennantite is a copper arsenic sulfosalt mineral with an ideal formula . Due to variable substitution of the copper by iron and zinc the formula is . It is gray-black, steel-gray, iron-gray or black in color. A closely related mineral, tetrahedrite ) has antimony substituting for arsenic and the two form a solid solution series. The two have very similar properties and is often difficult to distinguish between tennantite and tetrahedrite. Iron, zinc, and silver substitute up to about 15% for the copper site. The mineral was first described for an occurrence in Cornwall, England in 1819, where it occurs as small crystals of cubic or dodecahedral form, and was named after the English chemist Smithson Tennant (1761–1815). It is found in hydrothermal veins and contact metamorphic deposits in association with other Cu–Pb–Zn–Ag sulfides and sulfosalts, pyrite, calcite, dolomite, siderite, barite, fluorite and quartz. The arsenic component of tennantite causes the metal ...
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Pyrite
The mineral pyrite ( ), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Fe S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic luster and pale brass-yellow hue give it a superficial resemblance to gold, hence the well-known nickname of ''fool's gold''. The color has also led to the nicknames ''brass'', ''brazzle'', and ''brazil'', primarily used to refer to pyrite found in coal. The name ''pyrite'' is derived from the Greek (), 'stone or mineral which strikes fire', in turn from (), 'fire'. In ancient Roman times, this name was applied to several types of stone that would create sparks when struck against steel; Pliny the Elder described one of them as being brassy, almost certainly a reference to what is now called pyrite. By Georgius Agricola's time, , the term had become a generic term for all of the sulfide minerals. Pyrite is usually found associated with other sulfides or oxides in ...
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