
The sulfide minerals are a class of
minerals containing
sulfide
Sulfide (British English also sulphide) is an inorganic anion of sulfur with the chemical formula S2− or a compound containing one or more S2− ions. Solutions of sulfide salts are corrosive. ''Sulfide'' also refers to chemical compounds lar ...
(S
2−) or
disulfide (S
22−) as the major
anion. Some sulfide minerals are economically important as metal
ores. The sulfide class also includes the
selenides, the
tellurides, the
arsenides, the
antimonides, the bismuthinides, the
sulfarsenide The sulfarsenide minerals are a subgroup of the sulfide minerals which include arsenic replacing sulfur as an anion in the formula.Klein, Cornelis and Cornelius S. Hurlbut, 1985, ''Manual of Mineralogy,'' 20th ed., John Wiley and Sons, New York, p. ...
s and the
sulfosalts.
[http://www.minerals.net/mineral/sort-met.hod/group/sulfgrp.htm Minerals.net Dana Classification, Sulfides][Klein, Cornelis and Cornelius S. Hurlbut, Jr., 1986, ''Manual of Mineralogy'', Wiley, 20th ed., pp 269-293 ] Sulfide minerals are
inorganic compound
In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemi ...
s.
Minerals
Common or important examples include:
[
* Acanthite
* Chalcocite
* Bornite
* Galena
*]Sphalerite
Sphalerite (sometimes spelled sphaelerite) is a sulfide mineral with the chemical formula . It is the most important ore of zinc. Sphalerite is found in a variety of deposit types, but it is primarily in Sedimentary exhalative deposits, sedimen ...
* Chalcopyrite
* Pyrrhotite
* Millerite
* Pentlandite
* Covellite
*Cinnabar
Cinnabar (), or cinnabarite (), from the grc, κιννάβαρι (), is the bright scarlet to brick-red form of mercury(II) sulfide (HgS). It is the most common source ore for refining elemental mercury and is the historic source for the bri ...
* Realgar
* Orpiment
* Stibnite
* Pyrite
* Marcasite
* Molybdenite
Sulfarsenides:
* Cobaltite
* Arsenopyrite
* Gersdorffite
Sulfosalts:
* Pyrargyrite
* Proustite
* Tetrahedrite
* Tennantite
* Enargite
* Bournonite
* Jamesonite
* Cylindrite
Nickel–Strunz Classification -02- Sulfides
IMA-CNMNC proposes a new hierarchical scheme (Mills et al., 2009). This list uses the Classification of Nickel–Strunz (mindat.org
Mindat.org is a non-commercial online database, claiming to be the largest mineral database and mineralogy, mineralogical reference website on the Internet. It is used by professional mineralogists, geologists, and amateur mineral collecting, mi ...
, 10 ed, pending publication).
*Abbreviations:
**"*" - discredited (IMA/CNMNC status).
**"?" - questionable/doubtful (IMA/CNMNC status).
**"REE" - Rare-earth element (Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu)
**"PGE" - Platinum-group element (Ru, Rh, Pd, Os, Ir, Pt)
**03.C Aluminofluorides, 06 Borates, 08 Vanadates (04.H V ,6/sup> Vanadates), 09 Silicates:
***Neso: insular (from Greek
Greek may refer to:
Greece
Anything of, from, or related to Greece, a country in Southern Europe:
*Greeks, an ethnic group.
*Greek language, a branch of the Indo-European language family.
**Proto-Greek language, the assumed last common ancestor ...
νησος nēsos, island)
***Soro: grouping (from Greek
Greek may refer to:
Greece
Anything of, from, or related to Greece, a country in Southern Europe:
*Greeks, an ethnic group.
*Greek language, a branch of the Indo-European language family.
**Proto-Greek language, the assumed last common ancestor ...
σωροῦ sōros, heap, mound (especially of corn))
***Cyclo: ring
***Ino: chain (from Greek
Greek may refer to:
Greece
Anything of, from, or related to Greece, a country in Southern Europe:
*Greeks, an ethnic group.
*Greek language, a branch of the Indo-European language family.
**Proto-Greek language, the assumed last common ancestor ...
ις enitive: ινος ''inos'' fibre)
***Phyllo: sheet (from Greek
Greek may refer to:
Greece
Anything of, from, or related to Greece, a country in Southern Europe:
*Greeks, an ethnic group.
*Greek language, a branch of the Indo-European language family.
**Proto-Greek language, the assumed last common ancestor ...
φύλλον ''phyllon'', leaf)
***Tekto: three-dimensional framework
*Nickel–Strunz code scheme: NN.XY.##x
**NN: Nickel–Strunz mineral class number
**X: Nickel–Strunz mineral division letter
**Y: Nickel–Strunz mineral family letter
**##x: Nickel–Strunz mineral/group number, x add-on letter
Class: sulfides, selenides, tellurides
* 02.A Simple Sulfides, Selenides, etc.
** 02.AA Alloys of metalloids with Cu, Ag, Sn, Au: 10a Algodonite, 10b Domeykite
Domeykite is a copper arsenide mineral, Cu3As. It crystallizes in the isometric system, although crystals are very rare. It typically forms as irregular masses or botryoidal forms. It is an opaque, white to gray (weathers brassy) metallic mineral ...
, 10d Koutekite; 15 Novakite, 20 Cuprostibite, 25 Kutinaite, 30 Allargentum
Allargentum is a mineral from the class of antimonides, superclass of sulfides and sulfosalts (sometimes ascribed to the natural elements and alloys class), with formula written as Ag1−xSbx, where x = 0.09–0.16. This moderately rare mineral is ...
, 35 Dyscrasite, 40 Maldonite, 45 Stistaite
** 02.AB Ni-metalloid alloys: 10 Orcelite
Jean François Orcel (3 May 1896 – 27 March 1978) was a French mineralogist who contributed to the French nuclear energy program following the discovery of Uranium vanadate deposits in Morocco. He served as a mineralogist at the Muséum National ...
, 15 Maucherite, 20 Oregonite
Oregonite, Ni2 Fe As2 is a nickel iron arsenide mineral first described from Josephine Creek, Oregon, United States.
Oregonite crystallises in the hexagonal crystal system and has a Mohs hardness of 5.
Occurrence
Oregonite is known, apart from ...
** 02.AC Alloys of metalloids with PGE: 05a Atheneite
Atheneite is a rare palladium, mercury arsenide mineral with the chemical formula associated with palladium–gold deposits. Its composition parallels that of arsenopalladinite (), isomertieite () and meritieite-II () (Cabral, 2002).
Disco ...
, 05a Vincentite; 10a Stillwaterite
The palladium arsenide mineral Stillwaterite has a general formula of Pd8As3. Stillwaterite was first discovered in the Banded and Upper zones of the Stillwater igneous complex in Montana, United States, and has been reported in the Lac-des-Iles ...
, 10b Mertieite-II, 10c Arsenopalladinite; 15a Miessiite, 15a Isomertieite, 15b Mertieite-I; 20a Stibiopalladinite, 20b Palarstanide, 20c Menshikovite; 25a Palladoarsenide, 25b Rhodarsenide, 25c Palladodymite, 25d Naldretteite, 25e Majakite, 25f Palladobismutharsenide; 30 Polkanovite; 35a Genkinite, 35b Ungavaite, 40 Polarite; 45a Froodite, 45b Iridarsenite, 45c Borishanskiite
* 02.B Metal Sulfides, M:S > 1:1 (mainly 2:1)
** 02.BA With Cu, Ag, Au: 05a Chalcocite, 05b Djurleite, 05c Geerite, 05d Roxbyite, 05e Digenite, 05f Anilite; 10 Bornite; 15a Berzelianite, 15b Bellidoite, 15c Umangite, 15d Athabascaite; 20a Rickardite, 20b Weissite
Weissite is a telluride mineral, a copper telluride. Its chemical formula is . Weissite has hexagonal crystal structure. Its specific gravity is 6 and its Mohs hardness is 3. Occurrence is in Gunnison County, Colorado, Arizona and New Mexico in th ...
; 25a Stromeyerite
Stromeyerite is a sulfide mineral of copper and silver, with the chemical formula Ag Cu S. It forms opaque blue grey to dark blue orthorhombic crystals.
It was discovered in 1832 in Central Bohemia Region, Czech Republic, and named after the Ge ...
, 25b Mckinstryite, 25c Selenojalpaite, 25c Jalpaite, 25d Eucairite, 25e Henryite; 30a Acanthite, 30a Argentite*, 30b Aguilarite, 30b Naumannite, 30c Hessite, 30d Cervelleite, 30e Stutzite; 35 Argyrodite, 35 Putzite, 35 Canfieldite; 40a Fischesserite, 40a Petzite, 40b Uytenbogaardtite
The mineral uytenbogaardtite, Ag3AuS2, is a soft, greyish white sulfide mineral, occurring in hydrothermal Au-Ag-quartz veins. It occurs as tiny crystals, visible only with a microscope. It has a metallic luster and a hardness on the Mohs scale ...
, 40c Petrovskaite, 40d Penzhinite; 45 Bezsmertnovite, 50 Bogdanovite, 55 Bilibinskite, 60 Chenguodaite
** 02.BB With Ni, Fe: 05 Heazlewoodite; 10 Arsenohauchecornite, 10 Bismutohauchecornite, 10 Hauchecornite, 10 Tellurohauchecornite, 10 Tucekite; 15a Argentopentlandite, 15a Cobaltpentlandite, 15a Geffroyite, 15a Manganoshadlunite, 15a Pentlandite, 15a Shadlunite, 15b Godlevskite, 15c Sugakiite; 20 Vozhminite
** 02.BC With Rh, Pd, Pt, etc.: 05 Palladseite, 05 Miassite; 10 Oosterboschite
Oosterboschite is a rare selenide mineral with the formula . It crystallises in the orthorhombic crystal system. It has a creamy yellow colour and a Moh's hardness of 5. It is often found as grains with no clear shape. The crystals are opaque a ...
; 15 Jagueite, 15 Chrisstanleyite
Chrisstanleyite, Ag2Pd3Se4, is a selenide mineral that crystallizes in high saline, acidic hydrothermal solution at low temperatures as part of selenide vein inclusions in and alongside calcite veins. It tends to be found in assemblages of other ...
; 20 Keithconnite, 25 Vasilite, 30 Telluropalladinite, 35 Luberoite, 40 Oulankaite, 45 Telargpalite, 50 Temagamite, 55 Sopcheite, 60 Laflammeite, 65 Tischendorfite, 70 Kharaelakhite
** 02.BD With Hg, Tl: 05 Imiterite, 10 Gortdrumite; 15 Balkanite, 15 Danielsite; 20 Donharrisite, 25 Carlinite; 30 Bukovite, 30 Thalcusite, 30 Murunskite; 35 Rohaite, 40 Chalcothallite, 45 Sabatierite, 50 Crookesite, 55 Brodtkorbite
** 02.BE With Pb(Bi): 05 Betekhtinite, 10 Furutobeite; 15 Rhodplumsite, 15 Shandite; 20 Parkerite, 25 Schlemaite, 30 Pasavaite
* 02.C Metal Sulfides, M:S = 1:1 (and similar)
** 02.CA With Cu: 05a Covellite, 05b Klockmannite, 05c Spionkopite, 05d Yarrowite; 10 Nukundamite, 15 Calvertite
** 02.CB With Zn, Fe, Cu, Ag, Au, etc.: 05a Rudashevskyite, 05a Hawleyite, 05a Coloradoite, 05a Metacinnabar, 05a Sphalerite
Sphalerite (sometimes spelled sphaelerite) is a sulfide mineral with the chemical formula . It is the most important ore of zinc. Sphalerite is found in a variety of deposit types, but it is primarily in Sedimentary exhalative deposits, sedimen ...
, 05a Tiemannite, 05a Stilleite, 05b Sakuraiite, 05c Polhemusite; 07.0 Arsenosulvanite?; 10a Chalcopyrite, 10a Eskebornite, 10a Gallite, 10a Lenaite, 10a Roquesite, 10a Laforetite, 10b Haycockite, 10b Mooihoekite, 10b Putoranite, 10b Talnakhite; 15a Cernyite, 15a Hocartite, 15a Kuramite, 15a Pirquitasite, 15a Stannite, 15a Velikite, 15a Idaite, 15a Ferrokesterite, 15a Kesterite, 15b Mohite, 15c Stannoidite; 20 Chatkalite, 20 Mawsonite; 30 Colusite, 30 Germanite, 30 Germanocolusite, 30 Nekrasovite, 30 Stibiocolusite, 30 Maikainite, 30 Ovamboite; 35a Hemusite, 35a Kiddcreekite, 35a Renierite, 35a Polkovicite, 35a Morozeviczite, 35a Catamarcaite, 35a Vinciennite; 40 Lautite; 45 Cadmoselite, 45 Rambergite, 45 Greenockite, 45 Wurtzite; 55a Cubanite, 55b Isocubanite; 60 Picotpaulite, 60 Raguinite; 65 Argentopyrite, 65 Sternbergite; 70 Sulvanite, 75 Vulcanite, 80 Empressite, 85 Muthmannite
** 02.CC With Ni, Fe, Co, PGE, etc.: 05 Zlatogorite, 05 Breithauptite, 05 Freboldite, 05 Langisite, 05 Nickeline, 05 Sederholmite, 05 Stumpflite, 05 Sudburyite, 05 Sobolevskite, 05 Achavalite, 05 Jaipurite*, 05 Hexatestibiopanickelite, 05 Kotulskite; 10 Smythite, 10 Pyrrhotite, 10 Troilite; 15 Cherepanovite, 15 Modderite, 15 Ruthenarsenite, 15 Westerveldite; 20 Makinenite, 20 Millerite; 25 Mackinawite, 30 Vavrinite; 35a Braggite, 35a Cooperite (mineral), Cooperite, 35a Vysotskite
** 02.CD With Sn, Pb, Hg, etc.: 05 Herzenbergite, 05 Teallite; 10 Altaite, 10 Galena, 10 Clausthalite, 10 Alabandite, 10 Niningerite, 10 Oldhamite, 10 Keilite; 15a Cinnabar
Cinnabar (), or cinnabarite (), from the grc, κιννάβαρι (), is the bright scarlet to brick-red form of mercury(II) sulfide (HgS). It is the most common source ore for refining elemental mercury and is the historic source for the bri ...
, 15b Hypercinnabar
* 02.D Metal Sulfides, M:S = 3:4 and 2:3
** 02.DA M:S = 3:4: 05 Bornhardtite, 05 Florensovite, 05 Carrollite, 05 Fletcherite (mineral), Fletcherite, 05 Daubréelite, 05 Greigite, 05 Linnaeite, 05 Kalininite, 05 Polydymite, 05 Violarite, 05 Tyrrellite, 05 Siegenite, 05 Trustedtite, 05 Cadmoindite, 05 Cuproiridsite, 05 Cuprorhodsite, 05 Dayingite*, 05 Ferrorhodsite, 05 Indite, 05 Malanite, 05 Xingzhongite; 10 Rhodostannite, 10 Toyohaite; 15 Wilkmanite, 15 Brezinaite, 15 Heideite; 20 Inaglyite, 20 Konderite; 25 Kingstonite
** 02.DB M:S = 2:3 and similar: 05 Heklaite, 05a Antimonselite, 05a Guanajuatite, 05a Bismuthinite, 05a Stibnite, 05a Metastibnite, 05b Paakkonenite; 10 Ottemannite, 10 Suredaite; 15 Bowieite, 15 Kashinite; 20 Montbrayite, 25 Edgarite, 30 Tarkianite, 35 Cameronite
** 02.DC Variable M:S: 05 Platynite?, 05a Hedleyite, 05b Nevskite, 05b Telluronevskite, 05b Ingodite, 05b Sulphotsumoite, 05b Tsumoite, 05c Kawazulite, 05c Paraguanajuatite, 05c Skippenite, 05c Tetradymite, 05c Tellurantimony, 05c Tellurobismuthite, 05d Laitakarite, 05d Ikunolite, 05d Joseite, 05d Joseite-B, 05d Pilsenite, 05e Vihorlatite, 05e Baksanite, 05e Protojoseite*, 05e Sztrokayite*
* 02.E Metal Sulfides, M:S £1:2
** 02.EA M:S = 1:2: 05 Sylvanite, 10 Calaverite; 15 Krennerite, 15 Kostovite; 20 Berndtite, 20 Merenskyite, 20 Melonite, 20 Kitkaite, 20 Moncheite, 20 Sudovikovite, 20 Shuangfengite; 25 Verbeekite; 30 Drysdallite, 30 Jordisite, 30 Molybdenite, 30 Tungstenite
** 02.EB M:S = 1:2, with Fe, Co, Ni, PGE, etc.: 05a Aurostibite, 05a Cattierite, 05a Hauerite, 05a Fukuchilite, 05a Erlichmanite, 05a Geversite, 05a Insizwaite, 05a Laurite, 05a Krutaite, 05a Pyrite, 05a Penroseite, 05a Sperrylite, 05a Vaesite, 05a Villamaninite, 05a Trogtalite, 05a Dzharkenite, 05a Gaotaiite, 05b Bambollaite; 10a Frohbergite, 10a Hastite?, 10a Ferroselite, 10a Kullerudite, 10a Mattagamite, 10a Marcasite, 10b Alloclasite, 10c Glaucodot, 10d Costibite, 10e Pararammelsbergite, 10e Paracostibite, 10f Oenite; 15a Clinosafflorite, 15a Anduoite, 15a Omeiite, 15a Lollingite, 15a Nisbite, 15a Rammelsbergite, 15a Safflorite, 15b Seinajokite; 20 Paxite, 20 Arsenopyrite, 20 Gudmundite, 20 Ruarsite, 20 Osarsite; 25 Krutovite, 25 Cobaltite, 25 Changchengite, 25 Hollingworthite, 25 Gersdorffite, 25 Irarsite, 25 Jolliffeite, 25 Padmaite, 25 Platarsite, 25 Ullmannite, 25 Tolovkite, 25 Willyamite, 25 Milotaite, 25 Kalungaite, 25 Maslovite, 25 Testibiopalladite, 25 Michenerite, 25 Mayingite; 30 Urvantsevite, 35 Rheniite
** 02.EC M:S = 1:>2: 05 Ferroskutterudite, 05 Kieftite, 05 Dienerite?, 05 Nickelskutterudite, 05 Skutterudite; 10 Patronite
* 02.F Sulfides of Arsenic, Alkalies; Sulfides with Halide, Oxide, Hydroxide, O
** 02.FA With As, (Sb), S: 05 Duranusite, 10 Dimorphite, 15a Realgar, 15b Pararealgar, 20 Alacranite, 25 Uzonite; 30 Laphamite, 30 Orpiment; 35 Getchellite, 40 Wakabayashilite
** 02.FB With Alkalies (without Cl, etc.): 05 Cronusite, 05 Caswellsilverite, 05 Schollhornite; 10 Chvilevaite, 15 Orickite; 20 Rasvumite, 20 Pautovite; 25 Colimaite
** 02.FC With Cl, Br, I (halide-sulfides): 05 Djerfisherite, 05 Owensite, 05 Thalfenisite; 10 Bartonite, 10 Chlorbartonite; 15a Arzakite, 15a Corderoite, 15a Lavrentievite, 15b Kenhsuite, 15c Grechishchevite, 15d Radtkeite; 20a Capgaronnite, 20b Iltisite, 20c Perroudite; 25 Demicheleite-(Br), 25 Demicheleite-(Cl)
** 02.FD With O, OH, : 05 Kermesite, 10 Viaeneite, 20 Erdite, 25 Coyoteite; 30 Haapalaite, 30 Valleriite, 30 Yushkinite; 35 Tochilinite, 40 Wilhelmramsayite, 45 Vyalsovite, 50 Bazhenovite
* 02.X Unclassified Strunz Sulfides
** 02.XX Unknown: 00 Horsfordite?, 00 Imgreite?, 00 Bravoite?, 00 Isochalcopyrite?, 00 Bayankhanite?, 00 Dzhezkazganite*, 00 Matraite?, 00 Iridisite*, 00 Prassoite, 00 Samaniite, 00 Horomanite, 00 Jeromite?, 00 Dilithium*, 00 Kurilite?
See also
* Classification of non-silicate minerals
* Classification of silicate minerals
References
*
*
*
Webmineral New Dana Classification of Sulfide Minerals
External links
{{Strunz
Sulfide minerals,