Acenes General Structure
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Acenes General Structure
In organic chemistry, the acenes or polyacenes are a class of organic compounds and polycyclic aromatic hydrocarbons made up of benzene () Ring (chemistry), rings which have been linearly fused-ring compound, fused. They follow the general molecular formula . The larger representatives have potential interest in optoelectronic applications and are actively researched in chemistry and electrical engineering. Pentacene has been incorporated into organic field-effect transistors, reaching charge carrier mobilities as high as 5 cm2/Vs. The first 5 unsubstituted members are listed in the following table: Hexacene is not stable in air, and Dimer (chemistry), dimerises upon isolation. Heptacene (and larger acenes) is very Reactivity (chemistry), reactive and has only been isolated in a matrix. However, bis(trialkylsilylethynylated) versions of heptacene have been isolated as crystalline solids. Larger acenes Due to their increased conjugated system, conjugation length the larg ...
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Azene
Azo compounds are organic compounds bearing the functional group diazenyl (, in which R and R′ can be either aryl or alkyl groups). IUPAC defines azo compounds as: "Derivatives of diazene (diimide), , wherein both hydrogens are substituted by hydrocarbyl groups, e.g. azobenzene or diphenyldiazene.", where Ph stands for phenyl group. The more stable derivatives contain two aryl groups. The group is called an ''azo group'' (, ). Many textile and leather articles are dyed with azo dyes and pigments. Aryl azo compounds urinary tract infections">Phenazopyridine, an aryl azo compound, is used to treat urinary tract infections">150px Aryl azo compounds are usually stable, crystalline species. Azobenzene is the prototypical aromatic azo compound. It exists mainly as the Cis-trans isomerism, ''trans'' isomer, but upon illumination, converts to the Cis-trans isomerism, ''cis'' isomer. Aromatic azo compounds can be synthesized by azo coupling, which entails an electrophilic subst ...
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