NUCLEAR FUEL is a substance that is used in nuclear power stations to
produce heat to power turbines .
Most nuclear fuels contain heavy fissile elements that are capable of nuclear fission, such as uranium-235 or plutonium-239. When the unstable nuclei of these atoms are hit by a slow-moving neutron, they split, creating two daughter nuclei and two or three more neutrons . These neutrons then go on to split more nuclei. This creates a self-sustaining chain reaction that is controlled in a nuclear reactor , or uncontrolled in a nuclear weapon .
The processes involved in mining, refining, purifying, using, and disposing of nuclear fuel are collectively known as the nuclear fuel cycle .
Not all types of nuclear fuels create power from nuclear fission; plutonium-238 and some other elements are used to produce small amounts of nuclear power by radioactive decay in radioisotope thermoelectric generators and other types of atomic batteries .
* 1 Oxide fuel
* 1.1 UOX * 1.2 MOX
* 2 Metal fuel
* 3 Ceramic fuels
* 4 Liquid fuels
* 4.1 Molten salts * 4.2 Aqueous solutions of uranyl salts
* 5 Common physical forms of nuclear fuel
* 5.1 PWR fuel * 5.2 BWR fuel * 5.3 CANDU fuel
* 6 Less-common fuel forms
* 7.1 Oxide fuel under accident conditions
* 8 Fuel behavior and post-irradiation examination
* 9 Radioisotope decay fuels
* 10 Fusion fuels
* 10.1 First-generation fusion fuel * 10.2 Second-generation fusion fuel * 10.3 Third-generation fusion fuel
* 11 See also * 12 References
* 13 External links
For fission reactors, the fuel (typically based on uranium) is usually based on the metal oxide; the oxides are used rather than the metals themselves because the oxide melting point is much higher than that of the metal and because it cannot burn, being already in the oxidized state. The thermal conductivity of zirconium metal and uranium dioxide as a function of temperature
The thermal conductivity of uranium dioxide is very low compared with that of zirconium metal, and it goes down as the temperature goes up.
MIXED OXIDE, or MOX FUEL, is a blend of plutonium and natural or
depleted uranium which behaves similarly (though not identically) to
the enriched uranium feed for which most nuclear reactors were
Some concern has been expressed that used MOX cores will introduce new disposal challenges, though MOX is itself a means to dispose of surplus plutonium by transmutation .
Reprocessing of commercial nuclear fuel to make MOX was done in the
Sellafield MOX Plant (England). As of 2015,
The Global Nuclear Energy Partnership , was a U.S. proposal in the George W. Bush Administration to form an international partnership to see spent nuclear fuel reprocessed in a way that renders the plutonium in it usable for nuclear fuel but not for nuclear weapons . Reprocessing of spent commercial-reactor nuclear fuel has not been permitted in the United States due to nonproliferation considerations. All of the other reprocessing nations have long had nuclear weapons from military-focused "research"-reactor fuels except for Japan.Normally, with the fuel being changed every three years or so, about half of the Pu-239 is 'burned' in the reactor, providing about one third of the total energy. It behaves like U-235 and its fission releases a similar amount of energy. The higher the burn-up, the more plutonium in the spent fuel, but the lower the fraction of fissile plutonium. Typically about one percent of the used fuel discharged from a reactor is plutonium, and some two thirds of this is fissile (c. 50% Pu-239, 15% Pu-241). Worldwide, some 70 tonnes of plutonium contained in used fuel is removed when refueling reactors each year.
Metal fuels have the advantage of a much higher heat conductivity than oxide fuels but cannot survive equally high temperatures. Metal fuels have a long history of use, stretching from the Clementine reactor in 1946 to many test and research reactors. Metal fuels have the potential for the highest fissile atom density. Metal fuels are normally alloyed, but some metal fuels have been made with pure uranium metal. Uranium alloys that have been used include uranium aluminum, uranium zirconium, uranium silicon, uranium molybdenum, and uranium zirconium hydride. Any of the aforementioned fuels can be made with plutonium and other actinides as part of a closed nuclear fuel cycle. Metal fuels have been used in water reactors and liquid metal fast breeder reactors, such as EBR-II .
TRIGA fuel is used in TRIGA (Training, Research, Isotopes, General Atomics ) reactors. The TRIGA reactor uses UZrH fuel, which has a prompt negative fuel temperature coefficient of reactivity , meaning that as the temperature of the core increases, the reactivity decreases—so it is highly unlikely for a meltdown to occur. Most cores that use this fuel are "high leakage" cores where the excess leaked neutrons can be utilized for research. TRIGA fuel was originally designed to use highly enriched uranium, however in 1978 the U.S. Department of Energy launched its Reduced Enrichment for Research Test Reactors program, which promoted reactor conversion to low-enriched uranium fuel. A total of 35 TRIGA reactors have been installed at locations across the USA. A further 35 reactors have been installed in other countries.
In a fast neutron reactor , the minor actinides produced by neutron capture of uranium and plutonium can be used as fuel. Metal actinide fuel is typically an alloy of zirconium, uranium, plutonium, and minor actinides . It can be made inherently safe as thermal expansion of the metal alloy will increase neutron leakage.
Molten plutonium, alloyed with other metals to lower its melting point and encapsulated in tantalum, was tested in two experimental reactors, LAMPRE I and LAMPRE II, at LANL in the 1960s. "LAMPRE experienced three separate fuel failures during operation."
Ceramic fuels other than oxides have the advantage of high heat conductivities and melting points, but they are more prone to swelling than oxide fuels and are not understood as well.
Main article: Uranium nitride
This is often the fuel of choice for reactor designs that NASA produces, one advantage is that UN has a better thermal conductivity than UO2. Uranium nitride has a very high melting point. This fuel has the disadvantage that unless 15N was used (in place of the more common 14N ) that a large amount of 14C would be generated from the nitrogen by the (n,p) reaction . As the nitrogen required for such a fuel would be so expensive it is likely that the fuel would have to be reprocessed by pyroprocessing to enable the 15N to be recovered. It is likely that if the fuel was processed and dissolved in nitric acid that the nitrogen enriched with 15N would be diluted with the common 14N.
Main article: Uranium carbide
Much of what is known about uranium carbide is in the form of pin-type fuel elements for liquid metal fast reactors during their intense study during the 1960s and 1970s. However, recently there has been a revived interest in uranium carbide in the form of plate fuel and most notably, micro fuel particles (such as TRISO particles).
The high thermal conductivity and high melting point makes uranium carbide an attractive fuel. In addition, because of the absence of oxygen in this fuel (during the course of irradiation, excess gas pressure can build from the formation of O2 or other gases) as well as the ability to complement a ceramic coating (a ceramic-ceramic interface has structural and chemical advantages), uranium carbide could be the ideal fuel candidate for certain Generation IV reactors such as the gas-cooled fast reactor .
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Liquid fuels are liquids containing dissolved nuclear fuel and have been shown to offer numerous operational advantages compared to traditional solid fuel approaches.
Liquid-fuel reactors offer significant safety advantages due to their inherently stable "self-adjusting" reactor dynamics. This provides two major benefits: - virtually eliminating the possibility of a run-away reactor meltdown, - providing an automatic load-following capability which is well suited to electricity generation and high temperature industrial heat applications.
Another major advantage of the liquid core is its ability to be drained rapidly into a passively safe dump-tank. This advantage was conclusively demonstrated repeatedly as part of a weekly shutdown procedure during the highly successful 4 year ORNL MSRE program.
Another huge advantage of the liquid core is its ability to release xenon gas which normally acts as a neutron absorber and causes structural occlusions in solid fuel elements (leading to early replacement of solid fuel rods with over 98% of the nuclear fuel unburned, including many long lived actinides). In contrast Molten Salt Reactors (MSR) are capable of retaining the fuel mixture for significantly extended periods, which not only increases fuel efficiency dramatically, but also incinerates the vast majority of its own waste as part of the normal operational characteristics.
Molten salt fuels have nuclear fuel dissolved directly in the molten salt coolant. Molten salt-fueled reactors , such as the liquid fluoride thorium reactor (LFTR), are different from molten salt-cooled reactors that do not dissolve nuclear fuel in the coolant.
Molten salt fuels were used in the LFTR known as the Molten Salt Reactor Experiment , as well as other liquid core reactor experiments. The liquid fuel for the molten salt reactor was a mixture of lithium, beryllium, thorium and uranium fluorides: LiF-BeF2-ThF4-UF4 (72-16-12-0.4 mol%). It had a peak operating temperature of 705 °C in the experiment, but could have operated at much higher temperatures, since the boiling point of the molten salt was in excess of 1400 °C.
AQUEOUS SOLUTIONS OF URANYL SALTS
The aqueous homogeneous reactors (AHRs) use a solution of uranyl sulfate or other uranium salt in water. Historically, AHRs have all been small research reactors , not large power reactors. An AHR known as the Medical Isotope Production System is being considered for production of medical isotopes.
COMMON PHYSICAL FORMS OF NUCLEAR FUEL
See also: Active fuel length
Cladding is the outer layer of the fuel rods, standing between the
coolant and the nuclear fuel. It is made of a corrosion -resistant
material with low absorption cross section for thermal neutrons ,
Nuclear Regulatory Commission
NRC photo of fresh fuel pellets ready for assembly. *
NRC photo of fresh fuel being inspected.
PWR FUEL ASSEMBLY (also known as a fuel bundle) This fuel assembly is from a pressurized water reactor of the nuclear-powered passenger and cargo ship NS Savannah . Designed and built by the Babcock "> CANDU FUEL BUNDLES Two CANDU ("CANada Deuterium Uranium") fuel bundles, each about 50 cm long, 10 cm in diameter.
CANDU fuel bundles are about a half meter long and 10 cm in diameter. They consist of sintered (UO2) pellets in zirconium alloy tubes, welded to zirconium alloy end plates. Each bundle is roughly 20 kg, and a typical core loading is on the order of 4500-6500 bundles, depending on the design. Modern types typically have 37 identical fuel pins radially arranged about the long axis of the bundle, but in the past several different configurations and numbers of pins have been used. The CANFLEX bundle has 43 fuel elements, with two element sizes. It is also about 10 cm (4 inches) in diameter, 0.5 m (20 in) long and weighs about 20 kg (44 lb) and replaces the 37-pin standard bundle. It has been designed specifically to increase fuel performance by utilizing two different pin diameters. Current CANDU designs do not need enriched uranium to achieve criticality (due to their more efficient heavy water moderator ), however, some newer concepts call for low enrichment to help reduce the size of the reactors.
LESS-COMMON FUEL FORMS
Various other nuclear fuel forms find use in specific applications, but lack the widespread use of those found in BWRs, PWRs, and CANDU power plants. Many of these fuel forms are only found in research reactors, or have military applications. A magnox fuel rod
Magnox reactors are pressurised, carbon dioxide –cooled, graphite -moderated reactors using natural uranium (i.e. unenriched) as fuel and Magnox alloy as fuel cladding. Working pressure varies from 6.9 to 19.35 bar for the steel pressure vessels, and the two reinforced concrete designs operated at 24.8 and 27 bar. Magnox alloy consists mainly of magnesium with small amounts of aluminium and other metals—used in cladding unenriched uranium metal fuel with a non-oxidising covering to contain fission products. MAGNOX is short for MAGnesium Non-OXidising. This material has the advantage of a low neutron capture cross-section, but has two major disadvantages:
* It limits the maximum temperature, and hence the thermal efficiency, of the plant. * It reacts with water, preventing long-term storage of spent fuel under water.
Magnox fuel incorporated cooling fins to provide maximum heat transfer despite low operating temperatures, making it expensive to produce. While the use of uranium metal rather than oxide made reprocessing more straightforward and therefore cheaper, the need to reprocess fuel a short time after removal from the reactor meant that the fission product hazard was severe. Expensive remote handling facilities were required to address this danger. TRISO fuel particle which has been cracked, showing the multiple coating layers
TRIstructural-ISOtropic (TRISO) fuel is a type of micro fuel particle. It consists of a fuel kernel composed of UOX (sometimes UC or UCO) in the center, coated with four layers of three isotropic materials. The four layers are a porous buffer layer made of carbon, followed by a dense inner layer of pyrolytic carbon (PyC), followed by a ceramic layer of SiC to retain fission products at elevated temperatures and to give the TRISO particle more structural integrity, followed by a dense outer layer of PyC. TRISO fuel particles are designed not to crack due to the stresses from processes (such as differential thermal expansion or fission gas pressure) at temperatures up to and beyond 1600 °C, and therefore can contain the fuel in the worst of accident scenarios in a properly designed reactor. Two such reactor designs are the pebble-bed reactor (PBR), in which thousands of TRISO fuel particles are dispersed into graphite pebbles, and the prismatic-block gas-cooled reactor (such as the GT-MHR ), in which the TRISO fuel particles are fabricated into compacts and placed in a graphite block matrix. Both of these reactor designs are high temperature gas reactors (HTGRs). These are also the basic reactor designs of very-high-temperature reactors (VHTRs), one of the six classes of reactor designs in the Generation IV initiative that is attempting to reach even higher HTGR outlet temperatures.
TRISO fuel particles were originally developed in the United Kingdom as part of the Dragon reactor project. The inclusion of the SiC as diffusion barrier was first suggested by D. T. Livey. The first nuclear reactor to use TRISO fuels was the Dragon reactor and the first powerplant was the THTR-300 . Currently, TRISO fuel compacts are being used in the experimental reactors, the HTR-10 in China, and the HTTR in Japan. Spherical fuel elements utilizing a TRISO particle with a UO2 and UC solid solution kernel are being used in the Xe-100 in the United States. QUADRISO Particle
In QUADRISO particles a burnable neutron poison (europium oxide or erbium oxide or carbide ) layer surrounds the fuel kernel of ordinary TRISO particles to better manage the excess of reactivity. If the core is equipped both with TRISO and QUADRISO fuels, at beginning of life neutrons do not reach the fuel of the QUADRISO particles because they are stopped by the burnable poison. After irradiation, the poison depletes and neutrons stream into the fuel kernel of QUADRISO particles inducing fission reactions. This mechanism compensates fuel depletion of ordinary TRISO fuel. In the generalized QUADRISO fuel concept the poison can eventually be mixed with the fuel kernel or the outer pyrocarbon. The QUADRISO concept has been conceived at Argonne National Laboratory . RBMK REACTOR FUEL ROD HOLDER 1 – distancing armature; 2 – fuel rods shell; 3 – fuel tablets.
RBMK reactor fuel was used in Soviet -designed and built
reactors. This is a low-enriched uranium oxide fuel. The fuel elements
RBMK are 3 m long each, and two of these sit back-to-back on
each fuel channel, pressure tube.
Reprocessed uranium from Russian
CerMet fuel consists of ceramic fuel particles (usually uranium
oxide) embedded in a metal matrix. It is hypothesized that this type
of fuel is what is used in United States Navy reactors. This fuel has
high heat transport characteristics and can withstand a large amount
of expansion. ATR CORE The
Advanced Test Reactor
Plate-type fuel has fallen out of favor over the years. Plate-type fuel is commonly composed of enriched uranium sandwiched between metal cladding. Plate-type fuel is used in several research reactors where a high neutron flux is desired, for uses such as material irradiation studies or isotope production, without the high temperatures seen in ceramic, cylindrical fuel. It is currently used in the Advanced Test Reactor (ATR) at Idaho National Laboratory , and the nuclear research reactor at the University of Massachusetts Lowell Radiation Laboratory .
Sodium-bonded fuel consists of fuel that has liquid sodium in the gap between the fuel slug (or pellet) and the cladding. This fuel type is often used for sodium-cooled liquid metal fast reactors. It has been used in EBR-I, EBR-II, and the FFTF. The fuel slug may be metallic or ceramic. The sodium bonding is used to reduce the temperature of the fuel.
SPENT NUCLEAR FUEL
Spent nuclear fuel
Used nuclear fuel is a complex mixture of the fission products , uranium , plutonium , and the transplutonium metals . In fuel which has been used at high temperature in power reactors it is common for the fuel to be heterogeneous; often the fuel will contain nanoparticles of platinum group metals such as palladium . Also the fuel may well have cracked, swollen, and been heated close to its melting point. Despite the fact that the used fuel can be cracked, it is very insoluble in water, and is able to retain the vast majority of the actinides and fission products within the uranium dioxide crystal lattice .
OXIDE FUEL UNDER ACCIDENT CONDITIONS
Main article: Behavior of nuclear fuel during a reactor accident
Two main modes of release exist, the fission products can be vaporised or small particles of the fuel can be dispersed.
FUEL BEHAVIOR AND POST-IRRADIATION EXAMINATION
Main article: Post Irradiation Examination
Post-Irradiation Examination (PIE) is the study of used nuclear materials such as nuclear fuel. It has several purposes. It is known that by examination of used fuel that the failure modes which occur during normal use (and the manner in which the fuel will behave during an accident) can be studied. In addition information is gained which enables the users of fuel to assure themselves of its quality and it also assists in the development of new fuels. After major accidents the core (or what is left of it) is normally subject to PIE to find out what happened. One site where PIE is done is the ITU which is the EU centre for the study of highly radioactive materials.
Materials in a high-radiation environment (such as a reactor) can undergo unique behaviors such as swelling and non-thermal creep. If there are nuclear reactions within the material (such as what happens in the fuel), the stoichiometry will also change slowly over time. These behaviors can lead to new material properties, cracking, and fission gas release.
The thermal conductivity of uranium dioxide is low; it is affected by porosity and burn-up. The burn-up results in fission products being dissolved in the lattice (such as lanthanides ), the precipitation of fission products such as palladium , the formation of fission gas bubbles due to fission products such as xenon and krypton and radiation damage of the lattice. The low thermal conductivity can lead to overheating of the center part of the pellets during use. The porosity results in a decrease in both the thermal conductivity of the fuel and the swelling which occurs during use.
According to the International Nuclear Safety Center the thermal conductivity of uranium dioxide can be predicted under different conditions by a series of equations.
The bulk density of the fuel can be related to the thermal conductivity
Where ρ is the bulk density of the fuel and ρtd is the theoretical density of the uranium dioxide .
Then the thermal conductivity of the porous phase (Kf) is related to the conductivity of the perfect phase (Ko, no porosity) by the following equation. Note that s is a term for the shape factor of the holes. Kf = Ko(1 − p/1 + (s − 1)p)
Rather than measuring the thermal conductivity using the traditional methods such as Lees\' disk , the Forbes\' method , or Searle\'s bar , it is common to use Laser Flash Analysis where a small disc of fuel is placed in a furnace. After being heated to the required temperature one side of the disc is illuminated with a laser pulse, the time required for the heat wave to flow through the disc, the density of the disc, and the thickness of the disk can then be used to calculate and determine the thermal conductivity. λ = ρCpα
* λ thermal conductivity * ρ density * Cp heat capacity * α thermal diffusivity
If t1/2 is defined as the time required for the non illuminated surface to experience half its final temperature rise then. α = 0.1388 L2/t1/2
* L is the thickness of the disc
For details see
RADIOISOTOPE DECAY FUELS
Main article: atomic battery
The terms atomic battery , nuclear battery and radioisotope battery
are used interchangeably to describe a device which uses the
radioactive decay to generate electricity. These systems use
radioisotopes that produce low energy beta particles or sometimes
alpha particles of varying energies. Low energy beta particles are
needed to prevent the production of high energy penetrating
bremsstrahlung radiation that would require heavy shielding.
Radioisotopes such as plutonium-238 , curium-242 , curium-244 and
strontium-90 have been used.
There are two main categories of atomic batteries: thermal and non-thermal. The non-thermal atomic batteries, which have many different designs, exploit charged alpha and beta particles . These designs include the direct charging generators , betavoltaics , the optoelectric nuclear battery , and the radioisotope piezoelectric generator . The thermal atomic batteries on the other hand, convert the heat from the radioactive decay to electricity. These designs include thermionic converter, thermophotovoltaic cells, alkali-metal thermal to electric converter, and the most common design, the radioisotope thermoelectric generator.
RADIOISOTOPE THERMOELECTRIC GENERATORS
Inspection of Cassini spacecraft RTGs before launch
A radioisotope thermoelectric generator (RTG) is a simple electrical generator which converts heat into electricity from a radioisotope using an array of thermocouples .
238 Pu has become the most widely used fuel for RTGs, in the form of plutonium dioxide . It has a half-life of 87.7 years, reasonable energy density, and exceptionally low gamma and neutron radiation levels. Some Russian terrestrial RTGs have used 90 Sr ; this isotope has a shorter half-life and a much lower energy density, but is cheaper. Early RTGs, first built in 1958 by the U.S. Atomic Energy Commission , have used 210 Po . This fuel provides phenomenally huge energy density, (a single gram of polonium-210 generates 140 watts thermal) but has limited use because of its very short half-life and gamma production, and has been phased out of use for this application. Photo of a disassembled RHU
RADIOISOTOPE HEATER UNITS (RHU)
Radioisotope heater units normally provide about 1 watt of heat each, derived from the decay of a few grams of plutonium-238. This heat is given off continuously for several decades.
Their function is to provide highly localised heating of sensitive
equipment (such as electronics in outer space ). The Cassini–Huygens
Fusion fuels include deuterium (2H) and tritium (3H) as well as helium-3 (3He). Many other elements can be fused together, but the larger electrical charge of their nuclei means that much higher temperatures are required. Only the fusion of the lightest elements is seriously considered as a future energy source. Fusion of the lightest atom, 1H hydrogen , as is done in the Sun and stars, has also not been considered practical on Earth. Although the energy density of fusion fuel is even higher than fission fuel, and fusion reactions sustained for a few minutes have been achieved, utilizing fusion fuel as a net energy source remains only a theoretical possibility.
FIRST-GENERATION FUSION FUEL
SECOND-GENERATION FUSION FUEL
Second-generation fuels require either higher confinement temperatures or longer confinement time than those required of first-generation fusion fuels, but generate fewer neutrons. Neutrons are an unwanted byproduct of fusion reactions in an energy generation context, because they are absorbed by the walls of a fusion chamber, making them radioactive. They cannot be confined by magnetic fields, because they are not electrically charged. This group consists of deuterium and helium-3. The products are all charged particles, but there may be significant side reactions leading to the production of neutrons. 2H + 3He → p (14.68 MeV) + 4He (3.67 MeV)
THIRD-GENERATION FUSION FUEL
Main article: Aneutronic fusion
Third-generation fusion fuels produce only charged particles in the primary reactions, and side reactions are relatively unimportant. Since a very small amount of neutrons is produced, there would be little induced radioactivity in the walls of the fusion chamber. This is often seen as the end goal of fusion research. 3He has the highest Maxwellian reactivity of any 3rd generation fusion fuel. However, there are no significant natural sources of this substance on Earth. 3He + 3He → 2p + 4He (12.86 MeV)
Another potential aneutronic fusion reaction is the proton-boron reaction: p + 11B → 34He (8.7 MeV)
Under reasonable assumptions, side reactions will result in about 0.1% of the fusion power being carried by neutrons. With 123 keV, the optimum temperature for this reaction is nearly ten times higher than that for the pure hydrogen reactions, the energy confinement must be 500 times better than that required for the D-T reaction, and the power density will be 2500 times lower than for D-T.