Carbon-14
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Carbon-14
Carbon-14, C-14, or radiocarbon, is a radioactive isotope of carbon with an atomic nucleus containing 6 protons and 8 neutrons. Its presence in organic materials is the basis of the radiocarbon dating method pioneered by Willard Libby and colleagues (1949) to date archaeological, geological and hydrogeological samples. Carbon-14 was discovered on February 27, 1940, by Martin Kamen and Sam Ruben at the University of California Radiation Laboratory in Berkeley, California. Its existence had been suggested by Franz Kurie in 1934. There are three naturally occurring isotopes of carbon on Earth: carbon-12 (), which makes up 99% of all carbon on Earth; carbon-13 (), which makes up 1%; and carbon-14 (), which occurs in trace amounts, making up about 1 or 1.5 atoms per 1012 atoms of carbon in the atmosphere. Carbon-12 and carbon-13 are both stable, while carbon-14 is unstable and has a half-life of 5,730 ± 40 years. Carbon-14 decays into nitrogen-14 () through beta decay. A gra ...
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Radiometric Dating
Radiometric dating, radioactive dating or radioisotope dating is a technique which is used to date materials such as rocks or carbon, in which trace radioactive impurities were selectively incorporated when they were formed. The method compares the abundance of a naturally occurring radioactive isotope within the material to the abundance of its decay products, which form at a known constant rate of decay. The use of radiometric dating was first published in 1907 by Bertram Boltwood and is now the principal source of information about the absolute age of rocks and other geological features, including the age of fossilized life forms or the age of Earth itself, and can also be used to date a wide range of natural and man-made materials. Together with stratigraphic principles, radiometric dating methods are used in geochronology to establish the geologic time scale. Among the best-known techniques are radiocarbon dating, potassium–argon dating and uranium–lead dating. ...
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Martin Kamen
Martin David Kamen (August 27, 1913, Toronto – August 31, 2002, Montecito, California) was an American chemist who, together with Sam Ruben, co-discovered the synthesis of the isotope carbon-14 on February 27, 1940, at the University of California Radiation Laboratory, Berkeley. He also confirmed that all of the oxygen released in photosynthesis comes from water, not carbon dioxide, in 1941. Kamen was the first to use carbon-14 to study a biochemical system, and his work revolutionized biochemistry and molecular biology, enabling scientists to trace a wide variety of biological reactions and processes. Despite being blacklisted for nearly a decade on suspicion of being a security risk, Kamen went on to receive the Albert Einstein World Award of Science in 1989, and the U.S. Department of Energy's 1995 Enrico Fermi award for lifetime scientific achievement. Early life and education Kamen was born on August 27, 1913, in Toronto, the son of Russian Jewish immigrants. ...
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Willard Libby
Willard Frank Libby (December 17, 1908 – September 8, 1980) was an American physical chemist noted for his role in the 1949 development of radiocarbon dating, a process which revolutionized archaeology and palaeontology. For his contributions to the team that developed this process, Libby was awarded the Nobel Prize in Chemistry in 1960. A 1931 chemistry graduate of the University of California, Berkeley, from which he received his doctorate in 1933, he studied radioactive elements and developed sensitive Geiger counters to measure weak natural and artificial radioactivity. During World War II he worked in the Manhattan Project's Substitute Alloy Materials (SAM) Laboratories at Columbia University, developing the gaseous diffusion process for uranium enrichment. After the war, Libby accepted professorship at the University of Chicago's Institute for Nuclear Studies, where he developed the technique for dating organic compounds using carbon-14. He also discovered that trit ...
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Sam Ruben
Samuel Ruben (born Charles Rubenstein; November 5, 1913 – September 28, 1943) was an American chemist who with Martin Kamen co-discovered the synthesis of the isotope carbon-14 in 1940. Early life Ruben was the son of Herschel and Frieda Penn Rubenstein – the name was officially shortened to Ruben in 1930. Young Sam developed a friendship with neighbor Jack Dempsey and became involved with a local boys' boxing club and later, when the family moved across the Bay to Berkeley, he was a successful basketball player at Berkeley High School (Berkeley, California). After achieving his B.S. in Chemistry at the University of California, Berkeley, he continued his studies there and was awarded a Ph.D. in physical chemistry in May 1938. He was immediately appointed instructor in the Chemistry Department, and became an assistant professor in 1941. Research Ruben and colleague Martin Kamen, a University of Chicago Ph.D. and researcher in chemistry and nuclear physics working under ...
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Radiocarbon Dating
Radiocarbon dating (also referred to as carbon dating or carbon-14 dating) is a method for determining the age of an object containing organic material by using the properties of radiocarbon, a radioactive isotope of carbon. The method was developed in the late 1940s at the University of Chicago by Willard Libby. It is based on the fact that radiocarbon () is constantly being created in the Earth's atmosphere by the interaction of cosmic rays with atmospheric nitrogen. The resulting combines with atmospheric oxygen to form radioactive carbon dioxide, which is incorporated into plants by photosynthesis; animals then acquire by eating the plants. When the animal or plant dies, it stops exchanging carbon with its environment, and thereafter the amount of it contains begins to decrease as the undergoes radioactive decay. Measuring the amount of in a sample from a dead plant or animal, such as a piece of wood or a fragment of bone, provides information that can be used to ca ...
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Cosmic Ray
Cosmic rays are high-energy particles or clusters of particles (primarily represented by protons or atomic nuclei) that move through space at nearly the speed of light. They originate from the Sun, from outside of the Solar System in our own galaxy, and from distant galaxies. Upon impact with Earth's atmosphere, cosmic rays produce showers of secondary particles, some of which reach the surface, although the bulk is deflected off into space by the magnetosphere or the heliosphere. Cosmic rays were discovered by Victor Hess in 1912 in balloon experiments, for which he was awarded the 1936 Nobel Prize in Physics. Direct measurement of cosmic rays, especially at lower energies, has been possible since the launch of the first satellites in the late 1950s. Particle detectors similar to those used in nuclear and high-energy physics are used on satellites and space probes for research into cosmic rays. Data from the Fermi Space Telescope (2013) have been interpreted as evidence ...
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Isotope
Isotopes are two or more types of atoms that have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), and that differ in nucleon numbers (mass numbers) due to different numbers of neutrons in their nuclei. While all isotopes of a given element have almost the same chemical properties, they have different atomic masses and physical properties. The term isotope is formed from the Greek roots isos ( ἴσος "equal") and topos ( τόπος "place"), meaning "the same place"; thus, the meaning behind the name is that different isotopes of a single element occupy the same position on the periodic table. It was coined by Scottish doctor and writer Margaret Todd in 1913 in a suggestion to the British chemist Frederick Soddy. The number of protons within the atom's nucleus is called its atomic number and is equal to the number of electrons in the neutral (non-ionized) atom. Each atom ...
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Nitrogen-14
Natural nitrogen (7N) consists of two stable isotopes: the vast majority (99.6%) of naturally occurring nitrogen is nitrogen-14, with the remainder being nitrogen-15. Fourteen radioisotopes are also known, with atomic masses ranging from 10 to 25, along with one nuclear isomer, 11mN. All of these radioisotopes are short-lived, the longest-lived being nitrogen-13 with a half-life of . All of the others have half-lives below 7.15 seconds, with most of these being below 620 milliseconds. Most of the isotopes with atomic mass numbers below 14 decay to isotopes of carbon, while most of the isotopes with masses above 15 decay to isotopes of oxygen. The shortest-lived known isotope is nitrogen-10, with a half-life of . List of isotopes , - , , style="text-align:right" , 7 , style="text-align:right" , 3 , , , p ?Decay mode shown is energetically allowed, but has not been experimentally observed to occur in this nuclide. , ? , 1−, 2− , , , - , , style="text-align: ...
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Carbon-13
Carbon-13 (13C) is a natural, stable isotope of carbon with a nucleus containing six protons and seven neutrons. As one of the environmental isotopes, it makes up about 1.1% of all natural carbon on Earth. Detection by mass spectrometry A mass spectrum of an organic compound will usually contain a small peak of one mass unit greater than the apparent molecular ion peak (M) of the whole molecule. This is known as the M+1 peak and comes from the few molecules that contain a 13C atom in place of a 12C. A molecule containing one carbon atom will be expected to have an M+1 peak of approximately 1.1% of the size of the M peak, as 1.1% of the molecules will have a 13C rather than a 12C. Similarly, a molecule containing two carbon atoms will be expected to have an M+1 peak of approximately 2.2% of the size of the M peak, as there is double the previous likelihood that any molecule will contain a 13C atom. In the above, the mathematics and chemistry have been simplified, however it ca ...
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Carbon
Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent—its atom making four electrons available to form covalent chemical bonds. It belongs to group 14 of the periodic table. Carbon makes up only about 0.025 percent of Earth's crust. Three isotopes occur naturally, C and C being stable, while C is a radionuclide, decaying with a half-life of about 5,730 years. Carbon is one of the few elements known since antiquity. Carbon is the 15th most abundant element in the Earth's crust, and the fourth most abundant element in the universe by mass after hydrogen, helium, and oxygen. Carbon's abundance, its unique diversity of organic compounds, and its unusual ability to form polymers at the temperatures commonly encountered on Earth, enables this element to serve as a common element of all known life. It is the second most abundant element in the human body by mass (about 18.5%) after oxygen. The atoms of carbo ...
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Carbon Label
Carbon label is a form of isotopic labeling where a carbon-12 atom has been replaced with either a carbon-13 atom or a carbon-14 atom in a chemical compound so as to 'tag' (i.e. label) that position of the compound to assist in determining the way a chemical reaction proceeds i.e. the reaction mechanism. See also *Radiocarbon dating Radiocarbon dating (also referred to as carbon dating or carbon-14 dating) is a method for determining the age of an object containing organic material by using the properties of radiocarbon, a radioactive isotope of carbon. The method was de ... Isotopes {{isotope-stub ...
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Cosmogenic Nuclide
Cosmogenic nuclides (or cosmogenic isotopes) are rare nuclides (isotopes) created when a high-energy cosmic ray interacts with the nucleus of an '' in situ'' Solar System atom, causing nucleons (protons and neutrons) to be expelled from the atom (see cosmic ray spallation). These nuclides are produced within Earth materials such as rocks or soil, in Earth's atmosphere, and in extraterrestrial items such as meteoroids. By measuring cosmogenic nuclides, scientists are able to gain insight into a range of geological and astronomical processes. There are both radioactive and stable cosmogenic nuclides. Some of these radionuclides are tritium, carbon-14 and phosphorus-32. Certain light (low atomic number) primordial nuclides (isotopes of lithium, beryllium and boron) are thought to have been created not only during the Big Bang, but also (and perhaps primarily) to have been made after the Big Bang, but before the condensation of the Solar System, by the process of cosmic ra ...
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